DOI QR코드

DOI QR Code

Effects of the Sputtering Thickness and the Incident Angle of Pt Film Deposition as a Counter Electrode for Dye-sensitized Solar Cells

염료감응형 태양전지의 상대전극 Pt 필름 두께와 증착 각도가 효율에 미치는 영향에 관한 연구

  • 김희제 (부산대학 전자전기공학과) ;
  • 여태빈 (부산대학 전자전기공학과) ;
  • 박성준 (한국 수력원자력 연구원) ;
  • 김휘영 (동주대학 의료기공학과) ;
  • 서현웅 (부산대학 전자전기공학과) ;
  • 손민규 (부산대학 전자전기공학과) ;
  • 채원용 (부산대학 전자전기공학과) ;
  • 이경준 (부산대학 전자전기공학과)
  • Published : 2010.03.01

Abstract

Sputter deposition on a Pt counter electrode was studied using radio frequency (RF) plasma as the improvement of incident photon to current conversion efficiency (IPCE) for dye-sensitized solar cells (DSCs). Effects of the sputtering thickness and the incident angle on a Pt counter electrode for DSCs were investigated. Experiments to get the optimal sputtering time for the performance of the DSCs were carried out. And it is found that the optimized sputtering time was 120 seconds, in addition, the incident angles of the substrate was adjusted from $0^{\circ}$ to $60^{\circ}$. The maximum efficiency of 5.37% was obtained at the incident angle of $40^{\circ}$ with an active cell area of $1cm^2$.

Keywords

References

  1. B. O'Regan, M. Gratzel, "Optical electrochemistry I: steady-state spectroscopy of conduction band electrons in a metal oxide semiconductor electrode", Chemical Physics Letters, Vol.353, pp.737-739, 1991
  2. A. Hagfeldt and M. Grätzel, "Molecular Photovoltaics", Acc. Chem. Res. 33, pp. 269–277, 2000
  3. John B. Asbury, Encai Hao, Yongqiang Wang, Hirendra N. Ghosh, and Tianquan Lian, "Ultrafast electron transfer dynamics from molecular adsorbates to semiconductor nanocrystalline thin films", Journal of Physical Chemistry B, Vol. 105, Iss. 20, pp. 4545-4557, 2001 https://doi.org/10.1021/jp003485m
  4. Joachim Schnadt, Paul A. Bruhwiler, Luc Patthey, James N. O'Shea, Sven Sodergren, Michael Odelius, Rajeev Ahuja, Olof Karis, Margit Bassler, Petter Persson, Hans Siegbahn, S. Lunell and Nils Märtensson, "Experimental evidence for sub-3-fs charge transfer from an aromatic adsorbate to a semiconductor", Nature, Vol. 418, pp. 620-623, AUG, 2002 https://doi.org/10.1038/nature00952
  5. Michael Gratzel, "Perspectives for dye-sensitized nanocrystalline solar cells", Progress in Photovoltaics : Research and Applications, Vol. 8, Iss. 1, pp. 171-185, FEB, 2000 https://doi.org/10.1002/(SICI)1099-159X(200001/02)8:1<171::AID-PIP300>3.0.CO;2-U
  6. Hee-Je Kim, Yong-Chul Kim, Jin-Young Choi, Ho-Sung Kim, Dong-Gil Lee, Ji-Tae Hong, "A Study of Photo-electric Efficiency Improvement using Ultrasonic and Thermal Treatment on Photo-electrode of DSC", Trans. KIEE. Vol. 57, No. 5, pp. 803-807, MAY, 2008
  7. Hee-Je Kim, Sung-Joon Park, Min-Kyu Son, Dong-Kil Lee, Kyoung-Jun Lee, "A Study on the Scribing of FTO using Pulsed Nd:YAG Laser", Trans. KIEE. Vol. 57, No. 8, pp. 1407-1411, AUG, 2008
  8. Hee-Je Kim, Sung-Joon Park, Jin-Young Choi, Hyun-Woong Seo, Mi-Jeong Kim, Kyoung-Jun Lee, Min-Kyu Son, "The Deduction of the Optimal Length to Width Ratio of Dye-sensitized Solar Cell and the Fabrication of a Module", Trans. KIEE. Vol. 58, No. 1, pp. 100-106, JAN, 2009
  9. N. Papageorgiou, W. F. Maier, and M. Grätzel, "An iodine/triiodide reduction electrocatalyst for aqueous and organic media", Journal of the Electrochemical Society, Vol. 144, Iss. 3, pp. 876-884, MAR, 1997 https://doi.org/10.1149/1.1837502
  10. Kazuharu Suzuki, Makoto Yamaguchi, Mikio Kumagai and Shozo Yanagida, "Application of carbon nanotubes to counter electrodes of dye-sensitized solar cells", Chemistry Letters, Vol. 32, No. 1, pp. 28-29, 2003. https://doi.org/10.1246/cl.2003.28
  11. X.Fang et al., "Effect of the thickness of the Pt film coated on a counter electrode on the performance of a dye-sensitized solar cell", Journal of Electroanalytical Chemistry 570, pp. 257-263, 2004 https://doi.org/10.1016/j.jelechem.2004.04.004
  12. A.I. Popov, D.H. Geske, "Studies on the Chemistry of Halogen and of Polyhalides. XIII. Voltammetry of Iodine Species in Acetonitrile", J. Am. Chem. Soc. 80, pp.1340-1352, 1958 https://doi.org/10.1021/ja01539a018
  13. Choi, J. Hong, J. Seo, H. Kim, M. Son, M. Lee, K. Lee, D. Kim, H, "Optimal series-parallel connection method of dye-sensitized solar cell for Pt thin film deposition using a radio frequency sputter system", Thin Solid Films, vol. 517, issue 2, pp. 963-966, 2008 https://doi.org/10.1016/j.tsf.2008.08.159
  14. L. Han, N. Koide, Y. Chiba, A. Islam, R. Komiya, N. Fuke, A. Fukui, R. Yamanaka, "Improvement of efficiency of dye-sensitized solar cells by reduction of internal resistance", Appl. Phys. Lett. 86, pp. 213501, 2005 https://doi.org/10.1063/1.1925773