고체상미량추출법을 이용한 BTEX와 MTBE의 경쟁적 추출효과 및 미량분석에 관한 연구

Competitive Extraction and Trace Analysis of BTEX and MTBE by Solid-Phase Microextraction (SPME)

  • 안상우 (한양대학교 건설환경공학과) ;
  • 천석영 (경기대학교 환경에너지시스템공학과) ;
  • 이시진 (경기대학교 환경에너지시스템공학과) ;
  • 박재우 (한양대학교 건설환경공학과) ;
  • 장순웅 (경기대학교 환경에너지시스템공학과)
  • An, Sang-Woo (Department of Civil and Environmental Engineering, Hanyang University) ;
  • Chun, Suk-Young (Department of Environmental Energy & System Engineering, Kyonggi University) ;
  • Lee, Si-Jin (Department of Environmental Energy & System Engineering, Kyonggi University) ;
  • Park, Jae-Woo (Department of Civil and Environmental Engineering, Hanyang University) ;
  • Chang, Soon-Woong (Department of Environmental Energy & System Engineering, Kyonggi University)
  • 투고 : 2010.02.11
  • 심사 : 2010.05.11
  • 발행 : 2010.07.30

초록

In this study, Solid-phase microextraction (SPME) with GC/FID was studied as a possible alternative to liquid-liquid extraction for the analysis of BTEX and MTBE. Experimental parameters affecting the SPME process (such as kind of fibers, adsorption time, desorption time, volume ratio of sample to headspace, salt addition, and magnetic stirring) were optimized. Experimental parameters such as CAR/PDMS, adsorption time of 20 min, desorption time of 5 min at $250^{\circ}C$, headspace volume of 50 mL, sodium chloride (NaCl) concentration of 25% combined with magnetic stirring were selected in optimal experimental conditions for analysis of BTEX and MTBE. The general affinity of analytes to CAR/PDMS fiber was high in the order p-Xylene>Toluene>Ethylbenzene>MTBE>Benzene. The linearity of $R^2$ for BTEX and MTBE was from 0.970 to 0.999 when analyte concentration ranges from $30{\mu}g/L$ to $500{\mu}g/L$, respectively. The relative standard deviation (% RSD) were from 2.5% to 3.2% for concentration of $100{\mu}g/L$ (n=5), respectively. Finally, the limited of detection (LOD) observed in our study for BTEX and MTBE were from $7.5{\mu}g/L$ to $15{\mu}g/L$, respectively.

키워드

참고문헌

  1. 김택제(2000). 고체상 미량추출법의 이론과 활용. 분석과학회지, 15(5), pp. 51-62.
  2. 박교범, 이석곤(2000). SPME를 이용한 수용액 중의 휘발성 유기화합물 분석. 분석과학회지, 13(3), pp. 277-281.
  3. 박용하, 조종수, 김미정, 공성호, 박정규, 정충섭(2002). 연료첨가제 MTBE의 위해성 및 관리필요성에 관한 연구. 한국환경정책.평가연구원.
  4. 안상우, 박재홍, 조일형,장순응(2006). 광촉매공정과 초음파를 접목시킨 광촉매공정에 의한 Benomyl의 분해 비교. 수질보전 한국물환경학회지. 21(4), pp. 585-589.
  5. 안상우, 장순응(2004). SPME-GC/FID를 이용한 MTBE 및 TBA 분석에 관한 연구. 한국환경분석학회지, 7(2), pp. 83-89.
  6. Alizadeh, N., Jafaria, M., and Mohammadi, A. (2009). Head-space-solid-phase microextraction using a dodecylsulfate-doped polypyrrole film coupled to ion mobility spectrometry for analysis methyl tert-butyl ether in water and gasoline. Journal of Hazardous Materials, 169, pp. 861-867. https://doi.org/10.1016/j.jhazmat.2009.04.029
  7. Black, L. and Fine, D. (2001). High Levels of Monoaromatic Compounds Limit the Use of Solid-Phase Microextraction of Methyl tert-Butyl Ether and tert-Butyl Alcohol. Environmental Science & Technology, 35(15), pp. 3190-3192. https://doi.org/10.1021/es010539c
  8. Cho, D. H., Kong, S. H., and Oh, S. G. (2003a). Anaysis of trihalomethanes in drinking water using headspace-SPME technique with gas chromatography. Water Research, 36, pp. 402-408.
  9. Cho, H. J., Baek, K. T., Lee, H. H., Lee, S. H., and Yang, J. W. (2003b). Competitive extraction of muti-component contaminants in water by Carboxen-polydimethylsiloxan fiber during solid-phase microextraction. Journal of Chromatography A, 988, pp. 177-184. https://doi.org/10.1016/S0021-9673(02)02083-6
  10. Guitarta, C., Bayonaa, J. M., and Readman, J. W. (2004). Sources, distribution and behaviour of methyl tert-buryl ether (MTBE) in the Tamar Estuary, UK. Chemosphere, 57(6), pp. 429-437. https://doi.org/10.1016/j.chemosphere.2004.07.003
  11. Kolb, A. and Puttmanna, W. (2006). Methyl tert-butyl ether (MTBE) in snow samples in Germany. Atmospheric Environment, 40(1), pp. 76-86. https://doi.org/10.1016/j.atmosenv.2005.09.016
  12. Lin, T. F., Liu, C. L., Yang, F. C., and Hung, H. W. (2003). Effect of residual chlorine on the analysis of geosmin, 2-MIB and MTBE in drinking water using the SPME technique. Water Research, 37, pp. 21-26. https://doi.org/10.1016/S0043-1354(02)00251-8
  13. Pawliszyn, J. (1997). Solid-Phase Microextraction. Theory and Practice, Wiley-VCH, New York.
  14. Povolo, M. and Contarini, G. (2003). Comparison of solidphase microextraction and purge-and-trap methods for the analysis of the volatile fraction of butter. Journal of Chromatography A, 985, pp. 117-125. https://doi.org/10.1016/S0021-9673(02)01395-X
  15. Rosella, M., Lacorte, S., and Barcelo, D. (2006). Analysis, occurrence and fate of MTBE in the aquatic environment over the past decade. Trends in Analytical Chemistry, 25(10), pp. 1016-1029. https://doi.org/10.1016/j.trac.2006.06.011