Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Selective Oxidation of Olefins Catalyzed by Polymer-anchored Nickel(II) Complex in Water Medium

  • Received : 2010.06.24
  • Accepted : 2010.10.19
  • Published : 2010.12.20
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Abstract

Selective oxidation of olefins has been carried out in water medium with tert-butylhydroperoxide (TBHP, 70% aqueous) as an oxidant using polymer-anchored Ni(II) complex as a catalyst. Several parameters were varied to optimize the reaction conditions. Under the optimized reaction conditions olefins gave selectively allylic oxidation products. The present polymer anchored Ni(II) complex can be recycled five times without any appreciable loss in catalytic activity.

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References

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