Microstructural Development of $Si_3N_4$ Ceramics Containing Aligned ${\beta}-Si_3N_4$ Whisker Seeds

배향된 질화규소 휘스커 종자를 함유한 질화규소 세라믹스의 미세구조에 관한 연구

  • Bae, Byoung-Chan (Division of Advanced Materials Science and Engineering, Pukyong National University) ;
  • Park, Dong-Soo (Functional Ceramic Materials Group, Korea Institute of Machinery and Materials) ;
  • Seo, Won-Chan (Division of Advanced Materials Science and Engineering, Pukyong National University) ;
  • Bang, Kook-Soo (Division of Advanced Materials Science and Engineering, Pukyong National University) ;
  • Park, Chan (Division of Advanced Materials Science and Engineering, Pukyong National University)
  • 배병찬 (부경대학교 신소재공학부) ;
  • 박동수 (한국기계연구원 기능세라믹스그룹) ;
  • 서원찬 (부경대학교 신소재공학부) ;
  • 방국수 (부경대학교 신소재공학부) ;
  • 박찬 (부경대학교 신소재공학부)
  • Published : 2009.10.31

Abstract

Silicon nitride samples with aligned whisker seeds were prepared with different amounts of yttria and alumina as the sintering additives. Their sintering behaviors and the microstructural developments between $1850^{\circ}C$ and $2050^{\circ}C$ were examined. The sample with larger amount of the sintering additives showed faster densification and grain growth. Even though addition of the aligned whisker seeds slightly retarded densification of silicon nitride, it improved the flexural strength and the fracture toughness. Both the flexural strength and the fracture toughness of silicon nitride with the aligned whisker seeds were increased as the amount of the sintering additives was increased.

Keywords

References

  1. Andou, M. and Sawaoka, A. (1994). "Sinterability and Fracture Toughness of β-Si3N4 Whisker-Added Silicon Nitride", J. Ceram. Soc. Jpn., Vol 102, No 9, pp 890-892 https://doi.org/10.2109/jcersj.102.890
  2. Buljan, S.T., Pasto, A.E. and Kim, H.J. (1989). "Ceramic Whisker and Particulate-Composites: Properties, Reliability, and Applications", J. Am. Ceram. Soc. Bull., Vol 68, No 2, pp 387-394
  3. Einarsrud, M.A. and Mitomo, M. (1993). "Mechanism of Grain Growth of β-SiAlON", J. Am. Ceram. Soc., Vol 76, No 6, pp 1624-26 https://doi.org/10.1111/j.1151-2916.1993.tb03953.x
  4. Hirao, K., Ohashi, M., Brito, M.E. and S. Kanzaki (1995). "Processing Strategy for Producing Highly Anisotropic Silicon Nitride", J. Am. Ceram. Soc., Vol 78, No 6, pp 1687-1690 https://doi.org/10.1111/j.1151-2916.1995.tb08871.x
  5. Hirosaki, N., Okada, A. and Matoba, K. (1988). "Sintering of Si3N4 with the Addition of Rare-Earth Oxides", J. Am. Ceram. Soc., Vol 71, No 3, C-144-C-147
  6. Hirosaki, N. and Okada, A. (1992). "Effect of Additive-Oxide Amount on Sintering of Si3N4 with Y2O3 and Nd2O3", J. Mat. Sci., Vol 27, pp 3743-3748 https://doi.org/10.1007/BF00545450
  7. Kawashima, T., Okamoto, H., Yamamoto, Y. and Kitamura, A. (1991). "Grain Size Dependence of the Fracture Toughness of Silicon Nitride Ceramics", J. Ceram. Soc. Jpn., Vol 99, No 4, pp 320-323 https://doi.org/10.2109/jcersj.99.320
  8. Kijima, K. and Shirasaki, S.-I. (1976). "Nitrogen Self Diffusion", J. Chem, Phys., Vol 65, pp 2668-71 https://doi.org/10.1063/1.433464
  9. Lange, F.F. (1982). "Volatilization Associated with the Sintering of Polyphase Si3N4 Materials", J. Am. Ceram. Soc., Vol 65, No 8, C-120-C-121 https://doi.org/10.1111/j.1151-2916.1982.tb10493.x
  10. Lee, D.D., Kang, S.J. and Yoon, D.N. (1998). "Mechanism of Grain Growth and α-β ' Transformation during Liquid-Phase Sintering of β-SiAlON", J. Am. Ceram. Soc., Vol 71, pp 803-806 https://doi.org/10.1111/j.1151-2916.1988.tb06417.x
  11. Loehman, R.E. and Rowcliffe, D.J. (1980). "Sintering of Si3N4-Y2O3-Al2O3", J. Am. Ceram. Soc., Vol 63, No 3-4, pp 144-148 https://doi.org/10.1111/j.1151-2916.1980.tb10679.x
  12. Matsuhiro, K. and Takahashi, T. (1989). "The Effect of Grain Size on the Toughness of Sintered Si3N4", Ceram. Eng. Sci. Proc., Vol 10, No 7-8, pp 807-816
  13. Mitomo, M. and Mizuno, K.I. (1986). "Sintering Behavior of Si3N4 with Y2O3 and Al2O3 Addition", Yogyo-Kyokai-Shi Vol 94, No 1, pp 106-111 https://doi.org/10.2109/jcersj1950.94.106
  14. Park, D.S., Lee, S.Y., Kim, H.D., Yoo, B.J. and Kim, B.A. (1998). "Extra-Large Grains in the Silicon Nitride Ceramics Doped with Yttria and Hafnia", J. Am. Ceram. Soc., Vol 81, No 7, pp 1876-1880
  15. Priest, H.F., Priest, G.L. and Gazza, G.E. (1977). "Sintering of Si3N4 under high Nitrogen Pressure", J. Am. Ceram. Soc., Vol 60, No 1-2, C-81
  16. Reed, J.S. (1988). Introduction to the Principles of Ceramic Processing, pp. 121-182, 395-399, John Wiley & Sons, Inc., Canada
  17. Ring, T.A. (1996). Fundamentals of Ceramic Powder Processing and Synthesis, San Diego, Academic Press, pp 620-629
  18. Wang, C.M., Pan, X., Hoffmann, M.J. and Cannon, R.M. and Ruhle, M. (1996). "Grain Boundary Films in Rare-Earth-Grass-Based Silicon Niteide", J. Am. Ceram. Soc., Vol 79 No 3, pp 788-792 https://doi.org/10.1111/j.1151-2916.1996.tb07946.x
  19. Wu, M. and Messing, G.I. (1994). "Fabrication of Oriented SiC-Whisker-Reinforced Mullite Matrix Composites by Tape Casting", J. Am. Ceram. Soc., Vol 77, No 10, pp 2586-2592 https://doi.org/10.1111/j.1151-2916.1994.tb04646.x