Polymer(Korea) (폴리머)

The Polymer Society of Korea (한국고분자학회)
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Behaviour of Acidic Gases(SOx, NOx) Adsorption on Aminated PP-g-AAc Ultrafine Fibrous Ion Exchanger

아민화 PP-g-AAc 초극세 이온교환섬유의 산성가스(SOx, NOx) 흡착거동

  • Choi, Yong-Jae (Department of Chemical Engineering, Chungnam National University) ;
  • Choi, Kuk-Jong (Department of Chemical Engineering, Chungnam National University) ;
  • Lee, Chang-Soo (Department of Chemical Engineering, Chungnam National University) ;
  • Hwang, Taek-Sung (Department of Chemical Engineering, Chungnam National University)
  • 최용재 (충남대학교 바이오응용화학부) ;
  • 최국종 (충남대학교 바이오응용화학부) ;
  • 이창수 (충남대학교 바이오응용화학부) ;
  • 황택성 (충남대학교 바이오응용화학부)
  • Published : 2009.01.25
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Abstract

In this study, the behaviour of $SO_2$ and $NO_2$ adsorption on aminated ultrafine fibrous PP-g-AAc ion exchanger was investigated, The amount of adsorbed $SO_2$ increased with increasing the initial concentration of $SO_2$. The adsorption breakthrough time in the low concentration of $SO_2$ was faster than high concentration. The adsorption breakthrough occurred within 60 min. Approximately 80% of $SO_2$ was adsorbed below 100 ppm $SO_2$ and 90% of $SO_2$ over 100 ppm $SO_2$ respectively. The selective adsorption rate for $NO_2$ was lower than that of $SO_2$. The adsorption rate for $SO_2$ was decreased with increasing flow rate and that of $NO_2$ was 60%. The breakthrough occurred within 60 min. The adsorption rate for $SO_2$ was 92% in the 250 mL/g water content. Isotherm adsorption model for $SO_2$ was close to the Langmuir rather than Freundlich model.

본 연구는 아민화 polypropylene grafted acrylic acid(이하 PF-g-AAc로 표기) 초극세 이온교환섬유의 $SO_2$, $NO_2$에 대한 흡착거동을 고찰하였다. $SO_2$에 대한 흡착량은 초기농도가 높을수록 증가하였으며 농도가 낮을수록 흡착파과 시간이 짧아졌다. 흡착파과 평형은 60분 이내에 일어났으며 초기농도 100 ppm 이하에서는 약 80%정도 흡착이 이루어졌고, $SO_2$ 농도 100 ppm 이상에서 90% 이상 흡착되었다. $NO_2$의 흡착량은 $SO_2$에 비해 낮은 선택흡착성을 나타내었다. 한편, 유속이 증가함에 따라 $SO_2$의 흡착률은 낮아졌으며 60분 이내에 흡착파과 평형에 도달하였고, $NO_2$의 흡착량은 60%로 $SO_2$에 비해 낮았다. 함수율 250 mL/g에서 $SO_2$의 흡착량은 92%이었다. 아민화 PP-g-AAc 초극세 이온교환섬유의 $SO_2$등온흡착모델은 Freundlich 모델보다 Langmuir 모델에 근접하였다.

Keywords

References

  1. A. M. Rubel and J. M. Stencel, Fuel, 76, 521 (1997) https://doi.org/10.1016/S0016-2361(96)00221-9
  2. J. K. Yoon, K. H. Lee, J. H. Park, S. I. Yoon, B. K. Ha, and Y. S. Mok, Trends in Metals & Materials Engineering, 13, 35 (2000)
  3. A. Chakrabarti, A. Mizqauno, K. Shimizu, T. Matsuoka, and S. Furuta, IEEE T. Ind. Appl., 31, 500 (1994) https://doi.org/10.1109/28.382109
  4. Y. L. M. Creyghton, E. M. van Veldhuizen, and W. R. Rutgers, Electrical and optical study of pulsed positive corona, Springer-Verlag Pub. Co., Berlin Heidelberg, p.205 (1993)
  5. S. J. Scott, A long life, high repetition rate electron beam source, Springer-Verlag Pub. Co., Berlin Heidelberg, p.339 (1993)
  6. S. Pekarek, J. Rosenkranz, and H. Lonekova, Generation of electron beam for technological processes, Springer-Verlag Pub. Co., Berlin Heidelberg, p.345 (1993)
  7. T. Hori, K Saito, S. Frusaki, T. Sugo, and J. Okamoto, Chem Soc. Japan, 12, 1792(1986)
  8. J. Okamoto, T. Sugo, A Katakai, and H. Omichi, J. Appl. Polym. Sci., 30, 2967 (1985) https://doi.org/10.1002/app.1985.070300720
  9. K. Sugasaka, S. Katoh, N. Taki, A. Takahashi, and Y. Umezawa, Sep. Sci. Technol., 18, 307 (1983) https://doi.org/10.1080/01496398308068568
  10. K. A. Kun and R. Kunin, Union of South Africa Patent 2689 (1968)
  11. K. A. Kun and R. Kunin, J. Polym. Sci., B2, 587 (1964)
  12. H. Egawa, Polym. Proc. Jpn, 32, 38 (1983)
  13. V. S. Soldatov, G. I. Sergeev, and R. V. Martsinkevich, Dock. Akad. Nauk USSR, 28, 1009 (1984)
  14. V. S. Soldatov, Izvest. Acad. Nauk BSSR, Chem. Ser., 6, 39 (1982)
  15. H. H. Park, H. D. Jo, I. W. Kim, and H. K. Lee, Korean Chem. Eng. Res., 46, 521 (2008)
  16. Y. C. Nho, J. L. Garnett, and P. A. Dworganyn, J. Polym. Sci., 31, 163 (1993)
  17. J. S. Park, Y. C. Nho, and T. S. Hwang, Polymer(Korea), 21, 701 (1997)
  18. J. S. Park, Y. C. Nho, and J. H. Jin, Polymer(Korea), 22, 39 (1998)
  19. C. S. Shin and T. H. Lee, J. Kor. Inst. Chem. Eng., 27, 588 (1989)
  20. J. Chen, L. Yang, M. Wu, Q. Xi, S. He, Y. Li, and Y. C. Nho, Radiat. Phys. Chem., 59, 313 (2000) https://doi.org/10.1016/S0969-806X(00)00274-7
  21. El-Sayed A. Hegazy, H. Kamal, N. Maziad and A. M. Dessouki, Nucl. Instrum. Meth. B, 151, 386 (1999) https://doi.org/10.1016/S0168-583X(99)00125-1
  22. K. Tani, T. Ohta, S. Nii, and K. Takashi, J. Chem. Eng. Jpn, 31, 393 (1998)
  23. K. J. Choi, C. H. Lee, and T. S. Hwang, Polymer(Korea), 32, 5 (2008)
  24. T. S. Hwang and M. K. Park, Polymer(Korea), 27, 1 (2003)