Electrochemical Corrosion Behaviors of Amorphous $Zr_{65}Al_8Ni_{15}Cu_{12}$ Alloy

비정질 $Zr_{65}Al_8Ni_{15}Cu_{12}$ 금속합금의 전기화학적 부식 특성

  • Kim, Hyun-Goo (Department of Physics Education, Chosun University)
  • 김현구 (조선대학교 사범대학 물리교육과)
  • Received : 2009.11.17
  • Accepted : 2009.12.28
  • Published : 2009.12.31

Abstract

This study was undertaken to measure the electrochemical corrosion of amorphous $Zr_{65}Al_8Ni_{15}Cu_{12}$ (at.%) alloy ribbon under various conditions, including 0.4 mM HCl solution, and for various values of the pH and the immersion time. The corrosion potentials($E_{corr}$) for the amorphous $Zr_{65}Al_8Ni_{15}Cu_{12}$ alloy in 0.4 mM HCl decreased with increasing temperature; the corrosion current density($I_{corr}$) increased with increasing temperature in general. The polarization resistance($R_p$) was inversely proportional to the corrosion rate. While pH=7, 9, 11 was not as sensitive as pH=3, 5, pH=3 was more sensitive for amorphous $Zr_{65}Al_8Ni_{15}Cu_{12}$ alloy than other pHs specially. The change of mass in the 70 mM $H_2SO_4$ solution with immersion time was the greatest in the first 100 h.

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