Residue Distribution of Chlorothalonil, Kresoxim-methyl and Procymidone among Different Parts of Hot Pepper Plants

고추 부위별 chlorothalonil, kresoxim-methyl 및 procymidone 농약성분의 잔류 분포

  • 이미경 (안동대학교 자연과학대학 생명자원과학부) ;
  • 황재문 (안동대학교 자연과학대학 생명자원과학부)
  • Published : 2009.12.31

Abstract

The residue distribution ratio of pesticides among the flesh, stem and leaves of hot peppers were investigated to assure the safety of pepper powder and pepper leaves. Mixed solutions of chlorothalonil (wettable powder), kresoximmethyl (water dispersible granules) and procymidone (wettable powder) were applied once onto pepper plants in a plastic film house. After 7 days, the fruits and leaves were harvested and the fruits were divided into the flesh and stems. Pesticide residues in each pepper part were then analyzed by gas chromatography. The results showed that the concentration ratios of the chemicals in the flesh:stem and flesh:leaf ranged from 1:2-5 and 1:11-39, respectively, depending on the chemical evaluated. The observed flesh:stem ratio indicates that the pesticide content of the pepper powder product can increase by 20% if pepper stems are included in the powder product. The Korea Food and Drug Administration does not set a pesticide maximum residue level (MRL) for pepper leaves if a residue ratio in leaves over flesh is more than ten times. Results from this study support non-MRL status on the pepper leaves for the studied pesticides. Additionally, we recommend that the chlorothalonil product of a wettable powder type include the phrase "prohibition of distribution or sale for pepper leaves as food" because chlorothalonil highly resided in pepper leaves as more than twenty-four times that is a criterion level to determine an inclusion of the phrase in the label of pesticide product.

Chlorothalonil, kresoxim-methyl 및 procymidone 농약성분은 고추 과육 대 꼭지에서의 잔류농도의 비율이 농약성분에 따라 1:2-5로서 고춧가루에 꼭지가 혼입될 경우 고춧가루 중 농약 잔류량이 약 20%만큼 상승할 수 있는 것으로 나타났다. 그러므로 고춧가루의 안전성 확보를 위해서는 고춧가루 제조 시 꼭지가 혼입되지 않도록 해야 할 것이다. 고추 과육 대 고춧잎에서는 실험 농약성분 3종의 잔류농도 비율이 농약성분에 따라 1:11-39로 나타났다. 이것은 현재 실험 농약 3종의 고춧잎에 대한 잔류허용기준의 비설정 조치가 기준 설정 여부의 판단기준에 부합되는 것임을 말한다. 그러나 chlorothalonil 수화제의 경우 고춧잎 식용금지 문구가 부재한데 이것은 식용금지 문구 포함 여부의 판단기준에 부합되지 않으므로 이에 대한 재검토가 필요하다.

Keywords

References

  1. Lee SR. Food Safety. The Korean Academy of Science and Technology. Freedom Academy Pub. Co., Paju, Gyeonggi, Korea. p. 95 (2008)
  2. Kim KI, Kim HT, Kyung KS, Jin CW, Jeong CH, Ahn MS, Sim SW, Yun SS, Kim YJ, Lee KG, Lee KD, Lee WJ, Lim JB. Monitoring of pesticide residues in peppers from farmgate and pepper powder from wholesale market in Chungbuk area and their risk assessment. Korean J. Pest. Sci. 10: 15-21 (2006)
  3. Lee MG, Lee JH, Chung KM. Determination of pesticide residues in red-pepper powder by GC-ECD. Food Sci. Biotechnol. 11: 220-225 (2002)
  4. Kim HY, Yoon SH, Park HJ, Lee JH, Gwak IS, Moon HS, Song MH, Jang YM, Lee MS, Park JS, Lee KH. Monitoring of residual pesticides in commercial agricultural products in Korea. Korean J. Food Sci. Technol. 39: 237-245 (2007)
  5. Jeon JS, Kwon MJ, O SH, Nam HJ, Kim HY, Go JM, Kim YH. A Survey on the pesticide residues on agricultural products on the markets in Incheon area from 2003-2005. Korean J. Environ. Agr. 25: 180-189 (2006) https://doi.org/10.5338/KJEA.2006.25.2.180
  6. Hwang JM, Choi YW, Park H, Park CM, Kim JH, Jung EJ, Lee MH. The present status and solutions for pesticide residues in the parts of dried hot pepper. pp. 2-22. In: 2008 Report of the Industry & Academy Collaboration Foundation for Hot Pepper. Rural Development Administration, Suwon, Gyeonggi, Korea (2008)
  7. KFDA. Food Standards Code. Korea Food & Drug Administration, Seoul, Korea. p. 5-21-6 (2008)
  8. Lee MG, Lee SR. Studies to Improve the Tolerance Setting System of Pesticide Residues in Foods. Korea Food & Drug Administration, Seoul, Korea. pp. 61-66 (2004)
  9. KCPA. Agrochemicals Use Guide Book. Korea Crop Protection Association. Seoul, Korea. pp. 230-292 (2006)
  10. KFDA. Food Standards Code. Korea Food & Drug Administration, Soul, Korea. p. 10-9-1-1 (2008)
  11. KFDA. MRLs for Pesticides in Foods. Korea Food & Drug Administration, Seoul, Korea. pp. 243-244 (2008)
  12. Park H. Residual amount variation of carbendazim and chlorpyrifos on the parts of red pepper according to a cultivation type. MS thesis, Andong National University, Andong, Gyeongbuk, Korea (2008)
  13. RDA. Agenda of the 19th Pesticide Safety Advisory Committee. Rural Development Administration, Suwon, Gyeonggi, Korea. p. 8 (2008)
  14. Lee MG, Kim JH. Re-evaluation of Maximum Residue Limits of Pesticides. Korea Food and Drug Administration, Seoul, Korea. p. 64 (2004)