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γ-Al2O3로부터 가역과정을 경유한 AlO(OH) 나노콜로이드의 합성

Synthesis of AlO(OH) Nano Colloids from γ-Al2O3 via Reversible Process

  • 조현란 (한국화학연구원 에너지소재연구센터) ;
  • 김숙현 (한국화학연구원 에너지소재연구센터) ;
  • 박병기 (한국화학연구원 에너지소재연구센터)
  • Cho, Hyun-Ran (Energy Materials Research Center, Korea Research Institute of Chemical Technology) ;
  • Kim, Sook-Hyun (Energy Materials Research Center, Korea Research Institute of Chemical Technology) ;
  • Park, Byung-Ki (Energy Materials Research Center, Korea Research Institute of Chemical Technology)
  • 발행 : 2009.05.31

초록

The platelet AlO(OH) nano colloids were prepared by hydrothermal reaction of the $\gamma-Al_2O_3$ obtained with dehydration of $\gamma$-AlO(OH) and dilute $CH_3COOH$ solution. In hydrothermal reaction process, reversible reaction was accompanied between $\gamma-Al_2O_3$ and AlO(OH), and hydrothermal reaction temperature, hydrothermal reaction time and $CH_3COOH$ concentration had an effect on the crystal structure, surface chemical property, surface area, pore characteristics and crystal morphology of the AlO(OH) nano colloid particles. In this study, it was investigated to the hydrothermal reaction condition of the AlO(OH) nano colloid for using catalyst support, heat resisting agent, adsorbents, binder, polishing agent and coating agent. The crystal structure, surface area, pore volume and pore size of the platelet AlO(OH) nano colloids were investigated by XRD, TEM, TG/DTA, FT-IR and $N_2$ BET method in liquid nitrogen temperature.

키워드

참고문헌

  1. B.C. Lippins and J.H. Dcboer, 'Study of Phase Transformations during Calciantion of Aluminum Hydoxides by Selected Area Electron Diffraction,' Acta Crystallogr., 17 1312-21 (1964) https://doi.org/10.1107/S0365110X64003267
  2. B.E. Yoldas, 'Alumina Sol Preparation from Alkoxides,' Ceram. Bull., 54 289-90 (1975)
  3. Wells, A. F.: 'Structural Inorganic Chemistry,' 5th Ed., Oxford (1984)
  4. M. Bellotto, B. Rebours, and P. Euzen, 'Mechanism of Pseudo-boehmite Dehydration:Influence of Reagent Structure and Reaction Kinetics on the Transformation Sequence,' Materials Science Forum, 271 [2] 572-77 (1998) https://doi.org/10.4028/www.scientific.net/MSF.278-281.572
  5. K. H. Lee and B. H. Ha, 'Preparation and Characteristic for $\gamma$-Alumina,' J. Kor. Institute. Chem. Eng., 34 [1] 28-35 (1996)
  6. R. I. Zakharchenya, 'Influence of Peptization on the Properties of Alumina Produced from Boehmite Sols,' J. Sol-Gel Sci. Tech., 6 179-86(1996) https://doi.org/10.1007/BF00425975
  7. K. Okada and T. Nagashima, 'Relationship between Formation Conditions, Properties, and Crystalline Size of Boehmite,' J. Kor. Chem. Eng., 34 [1] 28-35 (1996)
  8. B. K. Park, J. K. Suh, J. M. Lee, and D. S. Suhr, 'The Rehydration Properties of Aphous Alumina Powder in Low Water/Alumina Ratio(in Korean),' J. Kor. Ceram. Soc., 35 [10] 1085-93 (1998)
  9. S. J. YOO, W. S. Baek, H. J. Park, J. W. Lee, S. G. Kim, U. Y. Hwang, H. S. Park, and H. S. Yoon, 'Synthesis of Alumina Sol from Al Metal and Effect of Surface Characterization by Aging in the Sol Preparation,' HWAHAKKONGHAK, 40 [3] 371-76 (2002)
  10. B. K. Park, J. K. Suh, J. M. Lee, and D. S. Suhr, 'Preparaton of High-capacity Ceramic Catalytic Support from Gibbsite (in Korean),' J. Kor. Ceram. Soc., 39 [3] 245-51 (2002) https://doi.org/10.4191/KCERS.2002.39.3.245
  11. R. Petrovic, S. Milonjic, V. Jokanvic, Lj. Kostic-Gvozdennovic, I. Petrovic-prelevic, and Dj. Janackovic, 'Influence of synthesis parameters on the structure of boehmite sol particles,' Powder Tech., 133 185-89 (2003) https://doi.org/10.1016/S0032-5910(03)00091-3
  12. B. K. Park, J. M. Lee, and D. S. Suhr, 'Preparation of $Fe_2O_3 Supported \gamma$-alumina Catalyst by Hydrothermal Method(in Korean),' J. Kor. Ceram. Soc., 40 [7] 683-89 (2003) https://doi.org/10.4191/KCERS.2003.40.7.683
  13. B. K. Park, J. M. Lee, and D. S. Suhr, 'Effect of $CH_3COOH Concentration on Characteristics of Fe_2O_3 Supported \gamma$-Alumina Catalyst by Hydrothermal Method(in Korean),' J. Kor. Ceram. Soc., 40 [8] 758-64 (2003) https://doi.org/10.4191/KCERS.2003.40.8.758
  14. B. K. Park, H. S. Lee, Y. H. Kim, and J. M. Lee, 'Prep-aration of Porous Boehmite Gel from Waste $AlCl_3$ Solution(in Korean),' J. Kor. Ceram. Soc., 40 [11] 864-71 (2004) https://doi.org/10.4191/KCERS.2004.41.11.864
  15. B. K. Park, J. M. Lee, D. S. Suhr, and K. S. Lim, 'Preparation of $\gamma-Al_2O_3$ Platelets from Aluminum Hydroxides Gel(in Korean),' J. Kor. Ceram. Soc., 41 [8] 610-17 (2004) https://doi.org/10.4191/KCERS.2004.41.8.610
  16. J. W. Lee, H. S. Yoon, U S. Chae, H. J. Park, U. Y. Hwang, H. S. Park, D. R. park, and S. J. Yoo, 'A Comparison of Structural Characterization of Composite Alumina Powder Prepared by Sol-Gel Method According to the Promoters,' Korean Chem. Eng. Res., 43 [4] 503-10 (2005) https://doi.org/10.1140/epjb/e2005-00083-9
  17. D. U. Choe, B. K. Park, J. K. Suh, and J. M. Lee, 'Effect of Aging Time of AlO(OH) Gel Precipitated by Hydrolysis of Aluminum Sulfate on Crystal Growth of the Flaky $\alpha-Al_2O_3$(in Korean),' J. Kor. Ceram. Soc., 43 [9] 575-81 (2006) https://doi.org/10.4191/KCERS.2006.43.9.575
  18. D. U. Choe, B. K. Park, and J. M. Lee, 'Effect of Water and Aluminum Sulfate Mole Ratio on Pore Characteristics in Synthesis of AlO(OH) Nano Gel by Homogeneous Precipitation(in Korean),' J. Kor. Ceram. Soc., 43 [9] 564-68 (2006) https://doi.org/10.4191/KCERS.2006.43.9.564
  19. B. K. Park, D. U. Choe, and J. R. Lee, 'Effect of pH on Pore Characteristics in Synthesis of High Porous AlO(OH) Gel by Hydrolysis of Al_2(SO_4)_3 and Na_2SO_4$ Mixed Solution,' J. Kor. Ceram. Soc., 44 [6] 325-30 (2007) https://doi.org/10.4191/KCERS.2007.44.6.325
  20. D. U. Choe, B. K. Park, J. K. Suh, and J. M. Lee, 'Effect of pH on Pore Characteristics in Synthesis of High Porous AlO(OH) Gel by Hydrolysis of $Al_2(SO_4)_3 and Na_2SO_44 Mixed Solution(in Korean),' J. Kor. Ceram. Soc., 44 [6] 325-30 (2007) https://doi.org/10.4191/KCERS.2007.44.6.325