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Electrochemical Properties of Ultrathin Film Prepared Functional Polyimide by Langmuir-Blodgett Method

Langmuir-Blodgett법으로 제조한 기능성 폴리이미드 초박막의 전기화학적 특성

  • Park, Keun-Ho (Dept. of Chemical Engineering, Changwon National University) ;
  • Min, Chang-Hun (Dept. of Chemical Engineering, Changwon National University) ;
  • Son, Tae-Chul (Dept. of Chemical Engineering, Changwon National University)
  • 박근호 (창원대학교 화공시스템공학과) ;
  • 민창훈 (창원대학교 화공시스템공학과) ;
  • 손태철 (창원대학교 화공시스템공학과)
  • Published : 2009.12.31

Abstract

We investigated the electrochemical properties for Langmuir-Blodgett (LB) films of functionalized polyimide. LB films of polyimide monolayer were deposited by the Langmuir-Blodgett method on the indium tin oxide(ITO) glass. The electrochemical properties measured by cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) at various concentrations(0.5, 1.0, and 1.5 N) of $NaClO_4$ solution. The current of reduction and oxidation range was measured from 1650 mV to -1350 mV, continuously. The scan rates were 50, 100 and 150 mV/s, respectively. As a result, monolayer and multilayer LB films of polyimide are appeared on irreversible process caused by the oxidation current from the cyclic voltammogram.

Keywords

References

  1. N. S Lee, H. K. Shin, J. S. Chang, and Y. S. Kwon, A study on the current-voltage properies of dipyridinium molecule using scanning tunneling microscopy, J. KIEEME, 18(7), 622 (2005) https://doi.org/10.4313/JKEM.2005.18.7.622
  2. M. H. Bae, K. H. Song, T. G. Park, and K. H. Park, Dynamic behaviors of externally-stimulated monolayers on the water surface, J. KIEEME, 13(4), 318, 2000
  3. X. Zhai, and J. M. Kleijn, Molecular structure of dipalmitoyl phosphatidyl choline Langmuir-Blodgett monolayer s studied by atomic force microscopy, Thin Solid Films, 304, 327 (1997) https://doi.org/10.1016/S0040-6090(97)00185-5
  4. J. Y. Lee, G. C. Sung, C. H. Yang, D. S. Shin, C. K. Kim, and Y. S. Kwon, Investigation of the monolayer LB film properties of a silsesquioxane hybrid containing phenyl groups using SPM, Thin Solid Films, (2009), doi:10.1016/j.tsf. 2009.07.095
  5. S. H. Choi and T. C. Son, J. Y. Song, K. H. Park, Electrochemical Properties of Organic Ultra Thin Films of Fatty Acid and Phospholipid Mixture, J. Kor. Oil Chem. Soc., 19(3), 75 (2006)
  6. T. C. Son, N. S. Kim, and K. H. Park, The Electrochemical Characterization of Mixture LB Films of Fatty Acid and Phospholipids, J. Kor. Oil Chem. Soc., 19(3), 75 (2003)
  7. K. H. Park and T. G. Park, A Study on the Photoisomerization of Fatty Acid and Polyamic Acid Mixture, J. Kor. Oil Chem. Soc., 19(3), 75 (2003)
  8. J. M. Ouyang, Z. M. Zhang, C. X. Huang, X. Q. Yao, H, Y, Liu, and X. M. Hu, Properties of mixed monolayer and LB films of chiral amino acid porphyrin, Colloids and Surfaces, 175, 99 (2000) https://doi.org/10.1016/S0927-7757(00)00525-2
  9. Rakesh K. Pandey, K. A. Suresh, and V. Lakshminarayanan, Electron transfer studies on cholesterol LB films assembled on thiophenol and 2-naphthalenethiol self-assembled monolayers, J. Coll. Inter. Sci. 315, 528 (2007) https://doi.org/10.1016/j.jcis.2007.07.044
  10. R. Li, Q. B. Chen, D. Z. Zhang, H. L. Liu, and Y. Hu, Mixed monolayers of Gemini surfactants and stearic acid at the air/water interface, J. Coll. Inter. Sci., 327, 162 (2008) https://doi.org/10.1016/j.jcis.2008.07.038
  11. J. M. Ko and H. C. Park, Principles and Applications of Cyclic Voltammetry, Poly. Sci. Tech., 10 519 (1999)
  12. D. S. Park, Study for Electrode Reaction Characteristics by Cyclic Voltammetry, Poly. Sci. Tech., 14, 356 (2003)
  13. P. T. Kissinger, Laboratory Techniques in Electroanalytical Chemistry, p.86, Marcel Dkker (1984)
  14. R. S. Nicholson and I. Shain, Theory of Stationary Electrode Polarography, Anal. Chem., 36, 706 (1964) https://doi.org/10.1021/ac60210a007
  15. H. S. Kim Y. I. Yun, E. J. Cho, Y. H. Choi, and M. Y. Oh, Analysis of Electrocoagulation Process using Faraday's Law, J. Indus. Tech., 21, 351 (2001)