Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Silica Supported Ammonium Acetate: An Efficient and Recyclable Heterogeneous Catalyst for Knoevenagel Condensation between Adehydes or Ketones and Active Methylene Group in Liquid Phase

  • Gupta, Raman (Department of Engineering Chemistry, Modern Institute of Engineering and Technology (MIET)) ;
  • Gupta, Monika (Department of Chemistry, University of Jammu) ;
  • Paul, Satya (Department of Chemistry, University of Jammu) ;
  • Gupta, Rajive (Department of Chemistry, University of Jammu)
  • Published : 2009.10.20
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Abstract

A simple and efficient method has been developed for Knoevenagel condensation between aldehydes or ketones and active methylene group by stirring in methylene chloride at 60 ${^{\circ}C}$ under heterogeneous conditions using silica supported ammonium acetate. The products are obtained in excellent yields and are in a state of high purity. The structures of the products were confirmed by IR, $^1H$ NMR and mass spectral data and comparison with authentic samples available commercially.

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