Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Characterization of Graphene Sheets Formed by the Reaction of Carbon Monoxide with Aluminum Sulfide

  • Yoon, Il-Sun (Department of Chemistry, KAIST) ;
  • Kim, Chang-Duk (Faculty of Liberal Education, Sangju Campus, Kyungpook National University) ;
  • Min, Bong-Ki (Instrumental Analysis Center, Yeungnam University) ;
  • Kim, Young-Ki (Center for Research Facilities, Ulsan National Institute of Science and Technology) ;
  • Kim, Bong-Soo (Department of Chemistry, KAIST) ;
  • Jung, Woo-Sik (School of Display and Chemical Engineering, College of Engineering, Yeungnam University)
  • Published : 2009.12.20
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Abstract

Graphene sheets formed by the reaction of carbon monoxide (CO) with aluminum sulfide ($Al_2S_3$) at reaction temperatures ${\leq}$ 800 $^{\circ}$ were characterized by X-ray diffraction (XRD), Raman spectroscopy, and high-resolution transmission electron microscopy (HRTEM). The graphene sheets, formed as CO was reduced to gaseous carbon by the reaction with $Al_2S_3$, in the temperature range 800 - 1100 $^{circ}C$, did not exhibit their characteristic XRD peaks because of the small number of graphene layers and/or low crystallinity of graphene sheets. Raman spectra of graphene sheets showed that the intensity ratio of the D band to the G band decreased and the 2D band was shifted to higher frequencies with increasing reaction temperature, indicating that the number of graphene layers increased with increasing reaction temperature.

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References

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