한국표면공학회지 (Journal of the Korean institute of surface engineering)

  • 제41권5호
  • /
  • Pages.194-198
  • /
  • 2008
  • /
  • 1225-8024(pISSN)
  • /
  • 2288-8403(eISSN)
한국표면공학회 (The Korean Institute of Surface Engineering)
권호 표지
DOI QR코드

DOI QR Code

Surface Modification of Multi-walled Carbon Nanotubes for Enhancement of Dispersion and Electrochemical Properties

  • Kim, Young-Ja (Department of Applied Materials Engineering, Chungnam National University) ;
  • Zhang, Wentao (Department of Applied Materials Engineering, Chungnam National University) ;
  • Lee, Hong-Ro (Department of Applied Materials Engineering, Chungnam National University) ;
  • Kim, Jong-Hyee (Div. of Future Fundamental Technology Research, Korea Institute of Energy Research)
  • 발행 : 2008.10.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Several methods for improving dispersion of carbon nanotubes (CNTs) have been investigated. CNTs modified by acids and hydrogen peroxide ($H_2O_2$) showed improved dispersion. From SEM micrographs and photos of dispersion, CNTs modified with nitric acid and $H_2O_2$, showed no agglomeration in solution even standing for 4 months, which means successfully improved dispersion property. TEM micrographs of surface modified single CNT treated with 69% $HNO_3$ in boiling acid solution as the optimum method were obtained. For confirmation of CNTs' application to EDLC electrode materials, characteristics of EDLC have been analyzed by cyclic voltammetry curve, specific capacitance of unit cell, electrode discharge curves and AC impedance curve. From the results, it could be confirmed that electrochemical properties of CNTs were enhanced after surface modification with 69% $HNO_3$ acid treatment.

키워드

참고문헌

  1. S. Iijima, Nature, 354 (1991) 56 https://doi.org/10.1038/354056a0
  2. T. W. Ebbessen, Ann. Rev. Mater. Sci. 24 (1994) 235 https://doi.org/10.1146/annurev.ms.24.080194.001315
  3. Christopher A, Dyke, M. James. , 10 (2004) 11
  4. C. Dekker, Physics Today, 52 (1999) 22
  5. V. Skakalova, U. Dettlaff-Weglikowska, S. Roth, Diamond and Related Materials, 13 (2004) 296 https://doi.org/10.1016/j.diamond.2003.11.003
  6. H. W. C. Postma, T. Teepen, Z. Yao, M. Grifoni, C. Dekker, Science, 293 (2001) 76 https://doi.org/10.1126/science.1061797
  7. C. Niu, E. K. Sichel, R. Hoch, D. Moy, H. Tennent, Appl. Phys. Lett., 70 (1997) 1480 https://doi.org/10.1063/1.118568
  8. R. Z. Ma, J. Liang, B. Q. Wei, B. Zhang, C. L. Xu, J. Power Sources, 84 (1999) 126 https://doi.org/10.1016/S0378-7753(99)00252-9
  9. S. Wei, W. P. Kang, J. L. Davidson, J. H. Huang, Diam. Relat. Mater., 17 (2008) 906 https://doi.org/10.1016/j.diamond.2007.12.063
  10. J. Y. Lee, K. Liang, K. H. An, Y. H. Lee, Synthet. Met., 150 (2005) 153 https://doi.org/10.1016/j.synthmet.2005.01.016
  11. P. X. Hou, S. Bai, Q. H. Yang, C. Liu, H. M. Cheng, Carbon, 40 (2002) 81 https://doi.org/10.1016/S0008-6223(01)00075-6
  12. J. Li, T. Tang, X. Zhang, S. Li, M. Li, Mater. Lett., 61 (2007) 4351 https://doi.org/10.1016/j.matlet.2007.01.103
  13. N. Pierard, A. Fonseca, I. Willems, G. Van Tendeloo, J. B.Nagy, Chem. Phys. Lett. 335 (2001) 1 https://doi.org/10.1016/S0009-2614(01)00004-5
  14. P. M. Ajayan, T. W. Ebbesen, T. Ichihashi, S. Iijima, K. Tanigaki, Nature, 362 (1993) 522 https://doi.org/10.1038/362522a0
  15. Y. P. Sun, K. Fu, Y. Lin, W. Huang, Accounts Chem. Res. 35 (2002) 1096 https://doi.org/10.1021/ar010160v
  16. S. Niyogl, M. A. Hamon, H. Hu, B. Zhao, P. Bhowmik, R. Sen, M. E. Itkis, R. C. Haddon, Accounts Chem. Res. 35 (2002) 1105 https://doi.org/10.1021/ar010155r
  17. D. M. Guldi, G. M. A. Rahman, V. Sgobba, C. Ehli, Chem. Soc. Rev. 35 (2006) 471 https://doi.org/10.1039/b511541h
  18. M. Yang, J. Jiang, Y. Yang, X. Chen, G. Shen, Biosens. and Bioelectron. 21 (2006) 1791 https://doi.org/10.1016/j.bios.2005.09.004
  19. J. L. Lyon, K. J. Stevenson, Electrochim. Acta, 53 (2008) 6714 https://doi.org/10.1016/j.electacta.2007.11.079
  20. G. Wang, M. Qu, Z. Yu, R. Yuan, Mater. Chem. Phys. 105 (2007) 169 https://doi.org/10.1016/j.matchemphys.2007.04.034
  21. L. Li, G. Wu, B. Q. Xu, Carbon, 44 (2006) 2973 https://doi.org/10.1016/j.carbon.2006.05.027
  22. S. M. Lipka, IEEE AES Systems Magazine, July 1997
  23. T. Momma, X. Liu, T. Osaka, Y. Ushio, Y. Sawada, J. Power Sources, 60 (1996) 249 https://doi.org/10.1016/S0378-7753(96)80018-8
  24. F. Pico, C. Pecharroman, A. Anson, M. T. Martinez, J. M. Rojo, J. Electrochem. Soc. 154 (2007) A579 https://doi.org/10.1149/1.2728037

피인용 문헌

  1. Electrical and morphological characterization of multiwalled carbon nanotubes functionalized via the Bingel reaction vol.83, 2015, https://doi.org/10.1016/j.jpcs.2015.04.004
  2. Preparation of Graphene-Perfluoroalkoxy Composite and Thermal and Mechanical Properties vol.10, pp.7, 2018, https://doi.org/10.3390/polym10070700