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Estimation of Fugitive Emission of Organic Hazardous Air Pollutants from Oil Refinery Industry

석유정제산업에서의 유기성 유해대기오염물질의 비산배출량 산정

  • Yang, Sung-Bong (Department of Chemistry, University of Ulsan) ;
  • Yu, Mee-Seon (Department of Chemistry, University of Ulsan) ;
  • Lee, Young-Joon (Environmental Measurement Standards Department, National Institute of Environmental Research) ;
  • Yoo, Eun-Jin (Environmental Measurement Standards Department, National Institute of Environmental Research) ;
  • Choi, Sung-Hyun (Environmental Measurement Standards Department, National Institute of Environmental Research)
  • Published : 2008.04.30

Abstract

Hazardous air pollutants emitted from the oil refinery plant were surveyed from 1993 US and 2005 Korean TRI data. Toluene, xylene, methanol, MTBE and n-hexane, relatively large in amount of fugitive emission, are considered as candidates of newly designated HAPs in Korea. The sealed oil pump, one of equipments among fugitive sources in the crude oil distillation tower was examined for the estimation of amounts of annual HAPs emissions according to several calculation methods using registered emission factors. Emission rates showed to be decreased with following calculation factors; average emission factor>pegged emission factor>concentration emission factor>correlation equation. Annual emission amounts of benzene, toluene, xylene. ethyl benzene and nhexane from the distillation tower were estimated and amounts of these HAPs calculated with TVOC concentrations obtained from LDAR program and correlation equations showed only 6% of those from using concentration factors.

Keywords

References

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