Minimum Autoignition Temperature Behavior(MAITB) of the Flammable Binary Systems

가연성 이성분계의 최소자연발화온도 거동(MAITB)

  • Ha, Dong-Myeong (Department of Occupational Health and Safety Engineering, Semyung University) ;
  • Lee, Sung-Jin (Department of Clinical Laboratory Science, Semyung University)
  • 하동명 (세명대학교 보건안전공학과) ;
  • 이성진 (세명대학교 임상병리학과)
  • Published : 2008.12.31

Abstract

The values of the AIT(Autoignition temperature) for fire and explosion protection are normally the lowest reported. The minimum autoignition temperature behavior(MAITB) of flammable liquid mixtures is exhibited when the AIT of mixture is below the AIT of the individual components. The MAITB is an interesting experimental features, which can be significant from the perspective of industrial safety. In this study, the AITs of m-xylene+n-butyric acid and ethylbenzene+n-butanol systems were measured using ASTM E659-78 apparatus. The AITs of m-xylene, n-butyric acid, ethylbenzene and n-butanol which constituted two binary systems were $587^{\circ}C$, $510^{\circ}C$, $475^{\circ}C$ and $340^{\circ}C$ respectively. The m-xylene+n-butyric acid system is exhibited MAITB at 0.3 mole fraction of m-xylene, and its minimum autoignition temperature was $460^{\circ}C$.

Keywords

References

  1. V. Babrauskas, "Ignition : A Century of Research and an Assessment of Our Current Status", J. of Fire Protection Engineering, Vol. 17, August, pp. 165-183, 2007 https://doi.org/10.1177/1042391507059434
  2. M.G. Zabetakis, A.L. Furno and G.W. Jones, "Minimum Spontaneous Ignition Temperature of Combustibles in Air", Industrial and Engineering Chemistry, Vol. 46, No. 10, pp.2173-2178, 1954 https://doi.org/10.1021/ie50538a047
  3. C.F. Cullis and C.D. Foster, "Studies of the Spontaneous Ignition in the Air of Binary Hydrocarbon Mixtures", Combustion and Flame, Vol. 23, pp. 347-356, 1974 https://doi.org/10.1016/0010-2180(74)90117-5
  4. D.M. Ha and S.J. Lee, "Measurement of Autoignition Temperature of o-Xylene+n-pentanol System", J. of the Korean Society of Safety, Vol. 21, No. 4, pp. 66-72, 2006
  5. D.M. Ha and S.J. Lee, "Measurement of Autoignition Temperature of Ethylbenzene+n-hexanol and Ethylbenzene+n-propionic acid Systems", T. of the Korean Institute of Fire Sci. & Eng., Vol. 21, No. 3, pp. 33-40, 2007
  6. D. Drysdale, "An Introduction to Fire Dynamics", 2nd ed., Jone Wiley & Sons, 1998
  7. ASTM, "Test Method E659-78(2000) Standard Test Method for Autoignition Temperature of Liquid Chemicals", American Society for Testing Materials, Philadelphia, PA(1994)
  8. F-Y. Hshieh, D.B. Hirsh and J.H. Willams, "Autoignition Temperature of Trichlorosilanes", Fire and Materials, Vol. 26, pp.289-290, 2002 https://doi.org/10.1002/fam.804
  9. D.M. Ha, "Measurement and Prediction of Autoignition Temperature(AIT) of Flammable Substances - Methanol and Ethanol -", J. of the Korean Society of Safety, Vol. 19, No. 2, pp.54-60, 2004
  10. NFPA, "Fire Hazard Properties of Flammable Liquid, Gases, and Volatile solids", NFPA 325M, NFPA, 1991
  11. R.E. Lenga and K.L. Votoupal, "The Sigma Aldrich Library of Regulatory and Safety Data, Volume I-III", Sigma Chemical Company and Aldrich Chemical Company Inc., 1993
  12. C.J. Hilado and S.W. Clark, "Autoignition Temperature of Organic Chemicals", Chemical Engineering, Vol. 4, pp. 75-80, 1972
  13. J.L. Jackson, "Spontaneous Ignition Temperature", Industrial and Engineering Chemistry, Vol. 43, No. 12, pp. 2869-2870, 1951 https://doi.org/10.1021/ie50504a058
  14. A.M. Kanury, "SFPE Handbook of Fire Protection Engineering ; Ignition of Liquid Fuels", 2nd ed., SFPE, 1995
  15. G.S. Scott, G.W. Jones and F.E. Scott, "Determination of Ignition Temperature of Combustible Liquids and Gases", Analytical Chemistry, Vol. 20, No. 3, pp. 238-241, 1948 https://doi.org/10.1021/ac60015a015
  16. KOSHA, http://www.kosha.net/members/login.jsp