Characterization of Volatile Organic Compounds Emission from Interior Materials of Railway Passenger Cabin

철도차량용 내장재의 휘발성유기화합물 방출특성 분석

  • 조영민 (한국철도기술연구원 철도환경연구실) ;
  • 박덕신 (한국철도기술연구원 철도환경연구실) ;
  • 권순박 (한국철도기술연구원 철도환경연구실) ;
  • 박은영 (과학기술연합대학원대학교)
  • Published : 2008.04.30

Abstract

The environmental significance of indoor air quality is gaining more attention. Especially, the contamination of indoor air by volatile organic chemicals (VOCs) has become a serious environmental concern. We investigated the VOCs emissions from some interior materials used in the conventional railway passenger cabin. The seat cover and the flooring of cabins were used as testing materials, and they were put in a clean environmental chamber. The temperature and relative humidity was kept at $25{\pm}1^{\circ}C$ and $50{\pm}5%$, respectively. It was found that these interior materials emitted significant amount of VOCs under constantly ventilated condition. The flooring emitted more halogenated VOCs than the seat cover, because it is made of PVC, which contains many chlorine atoms. However, the emission gradually decreased over time. Because the VOCs emission from interior materials may threaten the health of passengers in the cabin, interior materials emitting less VOCs should be used.

실내공기질의 중요성이 날로 부각되고 있다. 특히 휘발성유기화합물(VOCs)에 의한 실내공기의 오염은 매우 심각한 환경문제가 되고 있다. 이에 본 연구에서는 철도차량 객실용 시트커버와 바닥재를 대상으로 청정한 챔버 안에 넣고, 고정 환기 조건에서 VOCs 방출특성을 조사하였다. 챔버는 온도 $25{\pm}1^{\circ}C$, 상대습도 $50{\pm}5%$를 유지하면서 방출량을 조사하였다. 실험결과 바닥재가 시트커버보다 많이 양의 VOCs를 방출하는 것으로 나타났는데, 이는 바닥재가 PVC 재질이기 때문인 것으로 보인다. 방출량은 시간에 따라 점차 감소하였다.내장재에서 방출되는 VOCs는 객실 승객의 건강을 위협할 수 있으므로, VOCs를 덜 방출하는 내장재가 사용되어야 한다.

Keywords

References

  1. Stadler, J.C., Kennedy, Jr G.L. (1996), 'Evaluation of sensory irritation potential of volatile organic chemicals from carpets-alone and in combination', Food Chem. Toxicol. Vol. 34, pp.1125-1130 https://doi.org/10.1016/S0278-6915(97)00098-7
  2. Anderson, R.C. (1992), Press release. Anderson Laboratories, Inc.; 18 August
  3. Lim, G.-G. (2005), 'A study on the reduction process of VOCs Emission from Paint Booth - A hybrid process of biotrickling filter and activated sludge reactor', J. KOSAE. Vol. 21, pp.41-48
  4. Wolkoff, P. (1998), 'Impact of air velocity, temperature, humidity, and air on long-term VOC emissions from building products', Atmos. Environ. Vol. 32, pp.2659-2668 https://doi.org/10.1016/S1352-2310(97)00402-0
  5. Jo, W.-K., Kim, K.-Y., Park, K.-H., Kim, Y.-K., Lee, H.-W., Park, J.-K. (2003), 'Comparison of outdoor and indoor mobile sourcerelated volatile organic compounds between low- and high-floor apartments', Environ. Res. Vol. 92, pp.166-171 https://doi.org/10.1016/S0013-9351(03)00013-6
  6. Yu, C., Crump, D. (1998), 'A review of the emission of VOCs from polymeric materials used in buildings', Build and Environment Vol. 33, pp.357-374 https://doi.org/10.1016/S0360-1323(97)00055-3
  7. Little, J.C., Hodgson, A.T., Gadgil, A.J. (1994). 'Modeling emissions of volatile organic compounds from new carpets', Atmos.Environ. Vol. 28, pp.227-234 https://doi.org/10.1016/1352-2310(94)90097-3
  8. Schaeffer, V.H., Bhooshan, B., Chen, S.-B., Sonenthal, J.S., Hodgson, A.T. (1996), 'Characterization of volatile organic chemical emissions from carpet cushions', J. Air Waste Manage. Assoc. Vol. 46, pp.813-820 https://doi.org/10.1080/10473289.1996.10467516
  9. Guo, H., Murray, F., Lee, S.C., Wilkinson, S. (2004), 'Evaluation of emissions of total volatile organic compounds from an environmental chamber', Building and Environment, Vol. 39, pp.179-187 https://doi.org/10.1016/j.buildenv.2003.08.015
  10. Elkilani, A.S., Baker, C.G.J., Al-Shammari, Q.H., Bouhamra, W.S. (2003), 'Sorption of volatile organic compounds on typical carpet fibers', Environ. Int. Vol. 29, pp.575-585 https://doi.org/10.1016/S0160-4120(03)00014-X
  11. Jo, W.-K., Park, K.-H. (1999), 'Commuter exposure to volatile organic compounds under different driving conditions', Atmos. Environ. Vol. 33, pp.409-417 https://doi.org/10.1016/S1352-2310(98)00201-5
  12. Jo, W.-K., Yu, C.H. (2001), 'Public bus and taxicab drivers' exposure to aromatic work-time volatile organic compounds', Environ. Res. A, Vol. 86, pp.66-72 https://doi.org/10.1006/enrs.2001.4257
  13. 환경부 (2006), '지하철 등 대중운송수단의 실내공기질 실태조사 및 관리방안'
  14. Chan, L.Y., Lau, W.L., Wang, X.M., Tang, J.H. (2003), 'Preliminary measurements of aromatic VOCs in public transportation modes in Guangzhou, China', Environment International, Vol. 29, pp.429-435 https://doi.org/10.1016/S0160-4120(02)00189-7
  15. Lau, W.-L., Chan, L.-Y. (2003), 'Commuter exposure to aromatic VOCs in public transportation modes in Hong Kong', Sci. Total Environ. Vol. 308, pp.143-155 https://doi.org/10.1016/S0048-9697(02)00647-2
  16. Sakakibara, K., Kaitani, K., Hamada, C., Sato, S., Matsuo, M. (1999). 'Analysis of odor in car cabin', JSAE Rev. Vol. 20, pp.237-241 https://doi.org/10.1016/S0389-4304(98)00073-3
  17. Leung, P.-L., Harrison, R.M. (1999). 'Roadside and in-vehicle concentrations of monoaromatic hydrocarbons', Atmos. Environ. Vol. 33, pp.191-204 https://doi.org/10.1016/S1352-2310(98)00147-2
  18. 한국철도기술연구원 (2002), '실내 쾌적성 향상기술 개발', 연차보고서
  19. 한국철도기술연구원 (2007). '차세대 객차용 청정시스템 개발', 연차보고서
  20. Wolkoff, P. (1999), 'How to measure and evaluate volatile organic compound emissions from buildings. A perspective', Sci. Total Environ. Vol. 227, pp.197-213 https://doi.org/10.1016/S0048-9697(99)00019-4
  21. Black, M.S., Work, L.M., Worthan, A.G., Pearson, W.J. (1993), 'Measuring the TVOC contributions of carpet using environmental chambers'. In: Saarela, K., Kalliokoski, P., Seppnen, O., editors. Indoor Air 93, Sixth International Conference on Indoor Air Quality and Climate. Helsinki, Vol. 2, pp.401-405
  22. Wolkoff, P., Clausen, P.A., Nielsen, P.A., Gunnarsen, L. (1993), 'Documentation of field laboratory emission cell FLEC-identification of emission processes from carpet, linoleum, paint and sealant by modeling'. In: Saarela, K., Kalliokoski, P., Seppnen, O., editors. Indoor Air Indoor 93, Sixth International Conference on Indoor Air Quality and Climate. Helsinki, Vol. 2, pp.349-554
  23. Sollinger, S., Levsen, K., Wunsch, G. (1993), 'Indoor air pollution by organic emissions from textile floor coverings: climate chamber studies under dynamic conditions', Atmos. Environ. Vol. 27B, pp.183-192
  24. Duffy, B.L., Nelson, P.F. (1997), 'Exposure to emissions of 1,3- butadiene and benzene in the cabins of moving motor vehicles and buses in Sydney, Australia', Atmos. Environ. Vol. 31, pp.3877-3885 https://doi.org/10.1016/S1352-2310(97)00255-0
  25. Korhonen, H., Lintunen, M. (2004), 'The good indoor air' Like Publishing Ltd. Helsinki, Finland
  26. 환경부 (2003), '다중이용시설 등의 실내공기질 관리법'
  27. Environmental Protection Agency (1999), 'Compendium of Methods for the determination of toxic organic compounds in ambient air'