구형 철-알루미나 입자 제조 및 피셔-트롭시 반응을 위안 전처리 조건 확립

Development of Fe/$Al_2O_3$ Composite Granules and Activation Conditions for Fischer-Tropsch Synthesis

  • 유계상 (서울산업대학교 화학공학과) ;
  • 이동준 (고려대학교 화공생명공학과) ;
  • 정광덕 (한국과학기술연구원 청정에너지연구센터)
  • Yoo, Kye-Sang (Department of Chemical Engineering, Seoul National Univ. of Technology) ;
  • Lee, Dong-Joon (Department of Chemical & Biological Engineering, Korea Univ.) ;
  • Jung, Kwang-Deog (Clean Energy Research Center, Korea Institute of Science & Technology)
  • 발행 : 2008.12.30

초록

Fe/$Al_2O_3$ composite granules were prepared by combining sol-gel/oil drop method. The shape of granules were mainly determined by composition and concentration of aluminum precursor. The composite granule with the lowest aluminum concentration was synthesized with 0.75M boehmite solution. The prepared granules were tested as a catalyst in the plug-flow reactor for Fischer-Tropsch synthesis. Before the reaction, catalysts were activated by hydrogen reduction and synthesis gas treatment. The activation conditions and aluminum concentration have affected catalytic performance significantly.

키워드

참고문헌

  1. Y. Yang, H. W. Xiang, Y. Y. Xu, L. Bai and Y. W. Li, "Effect of potassium promoter on precipitated iron-manganese catalyst for Fischer-Tropsch synthesis", Appl. Catal. A: Gen., Vol. 266, No. 2, 2004, pp. 181-194 https://doi.org/10.1016/j.apcata.2004.02.018
  2. C. H. Zhang, Y. Yang, Z. C.Tao, T. Z. Li, H. J. Wan, H. W. Xiang and Y. W. Li, "Effects of Cu and K on Co-precipitated $FeMn/SiO_2$ Catalysts for Fischer-Tropsch Synthesis", Acta Phys.-Chim. Sin., Vol. 22, No. 11, 2006, pp. 1310-1316 https://doi.org/10.1016/S1872-1508(06)60064-8
  3. M. E. Dry, "Practical and theoretical aspects of the catalytic Fischer-Tropsch process", Appl. Catal. A: Gen., Vol. 138, No. 2, 1996, pp. 319-344 https://doi.org/10.1016/0926-860X(95)00306-1
  4. H. Dlamini, T. Motjope, G. Joorst and M. Mdleleni, "Changes in Physico-Chemical Properties of Iron-Based Fischer-Tropsch Catalyst Induced by $SiO_2$ Addition", Catal. Lett., Vol. 78, No. 1-4, 2002, pp. 201-207 https://doi.org/10.1023/A:1014953201451
  5. Y. Yang, H. W. Xiang, L. Tian, H. Wang, C. H. Zhang, Z. C. Tao, Y. Y. Xu, B. Zhong and Y. W. Li, "Structure and Fischer Tropsch performance of iron manganese catalyst incorporated with $SiO_2$", Appl. Catal. A: Gen., Vol. 284, No. 1-2, 2005, pp. 105-122 https://doi.org/10.1016/j.apcata.2005.01.025
  6. D. G. Miller and M. Moskovits, "A study of the effects of potassium addition to supported iron catalysts in the Fischer-Tropsch reaction", J. Phys. Chem., Vol. 92, No. 21, 1988, pp. 6081-6085 https://doi.org/10.1021/j100332a047
  7. L. Bai, H. W. Xiang, Y. W. Li, Z. Y. Han and B. Zhong, "Slurry phase Fischer-Tropsch synthesis over manganese-promoted iron ultrafine particle catalyst", Fuel, Vol. 81, No. 11-12, 2002, pp. 1577-1581 https://doi.org/10.1016/S0016-2361(02)00089-3
  8. W. Ma, Y. Ding, V. H. Carreto, V. Guez and D. B. Bukur, "Study on catalytic performance nd attrition strength of Ruhrchmie catalyst for the Fischer-Tropsch synthesis in a stirred tank slurry reactor", Appl. Catal. A: Gen., Vol. 268, No. 1-2, 2004, pp. 99-106 https://doi.org/10.1016/j.apcata.2004.03.024
  9. D. S. Kalakkad, M. D. Shroff, S. Kohler, N. Jackson and A. K. Datye, "Attrition of precipitated iron Fischer-Tropsch catalysts", Appl. Catal. A: Gen., Vol. 133, No. 2, 1995, pp. 335-350 https://doi.org/10.1016/0926-860X(95)00200-6
  10. R. Zhao, J. G. Goodwin Jr., K. Jothimurugesan, S. K. Gangwal and J. J. Spivey, "Spray-dried iron Fischer-Tropsch catalysts. 1. Effect of structure on the attrition resistance of the catalysts in the calcined state", Ind. Eng. Chem. Res. Vol. 40, No. 4, 2001, pp. 1065-1075 https://doi.org/10.1021/ie000644f
  11. R. Zhao, K. Sudsakorn, J. G. Goodwin, K. Jothimurugesan, S. K. Gangwal and J. J. Spivey, "Attrition resistance of spray-dried iron F-T catalysts: effect of activation conditions", Catal. Today, Vol. 71, No. 3-4, 2002, pp. 319-326 https://doi.org/10.1016/S0920-5861(01)00458-8
  12. K. Sudsakorn, J. G. Goodwin Jr., K. Jothimurugesan and A. A. Adeyiga, "Preparation of attrition resistant spray dried Fe Fischer Tropsch catalysts using precipitated $SiO_2$", Ind. Eng. Chem. Res., Vol. 40, No. 22, 2001, pp. 4778-4784 https://doi.org/10.1021/ie0101442
  13. J. Choi, J. Kim and T. G. Lee, 'Synthesis of Biomodally porous $\gamma$-Alumina Granules by Sol-Gel/Oil-Drop Method', J. Korean Ind. Eng. Chem., Vol. 18, No. 2, 2007, p. 111-115
  14. H. Abimanyu, K. D. Jung, K. W. Jun, J. Kim and K. S. Yoo, "Preparation and Characterization of $Fe/Cu/Al_2O_3$ composite Granules for $SO_3$ Decomposition to Assist Hydrogen Production", Appl. Catal. A:Gen., Vol. 343, No. 1-2, 2008, p. 134-141 https://doi.org/10.1016/j.apcata.2008.03.033
  15. 유계상, 정광덕, "황-요오드 열화학 수소제조 공정에서 다양한 크기의 $Cu/Fe/Al_2O_3$ 구형촉매를 이용한 삼산화황 분해", 한국수소 및 신에너지 학회 논문집, 제 19권 3호, 2008, pp. 226-231
  16. G. Bian, A. Oounki, N. Koizumi, H. Nomoto and M. Yamada, "Studies with a precipitated iron Fischer-Tropsch catalyst reduced by $H_2$ or CO", J. Mol. Catal. A, Vol. 186, No. 1-2, 2002, pp. 203-213 https://doi.org/10.1016/S1381-1169(02)00186-3
  17. Q. Hao, F. Liu, H. Wang, J. Chang, C. Zhang, L. Bai, H. Xiang, Y, Li, F. Yi and B. Xu, "Effect of reduction temperature on a spray dried iron-based catalyst for slurry Fischer Tropsch synthesis", J. Mol. Catal. A, Vol. 261, No. 1, 2007, pp. 104-111 https://doi.org/10.1016/j.molcata.2006.07.056
  18. C. H. Zhang, Y. Yang, B. T. Tenga, T. Z. Li H. Y. Zheng, H. W. Xiang and Y. W. Li, "Study of an iron-manganese Fischer Tropsch synthesis catalyst promoted with copper", J. Catal., Vol. 237, No. 2, 2006, pp. 405-415 https://doi.org/10.1016/j.jcat.2005.11.004
  19. H. Wan, B. Wu, C. Zhang, H. Xiang and Y. Li, "Promotional effects of Cu and K on precipitated iron based catalysts for Fischer Tropsch synthesis", J. Mol. Catal. A, Vol. 283, No. 1, 2008, pp. 33-42 https://doi.org/10.1016/j.molcata.2007.12.013