Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Sr2+ Ion Selective p-tert-Butylthiacalix[4]arene Bearing Two Distal Amide Units

  • Published : 2008.03.20
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Abstract

A new thiacalix[4]arene diamide (TCAm) has been prepared and its electrochemical property and complexation behavior toward various metal ions have been investigated by voltammetry. p-tert-Butylthiacalix[4]arene diamide (TCAm) exhibited selectivity toward Sr2+ ion over alkali, alkaline earth and transition metal ions while conventional calix[4]arene diamides showed selective binding property with Ca2+ ion. This is probably due to the bigger size of thiacalix[4]arene than those of calix[4]arene.

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References

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