Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Self-assembly of Dumbbell-shaped Rod Amphiphiles Based on Dodeca-p-phenylene

  • Huang, Zhegang (Center for Supramolecular Nano-Assembly and Department of Chemistry, Yonsei University) ;
  • Liu, Libin (Center for Supramolecular Nano-Assembly and Department of Chemistry, Yonsei University) ;
  • Lee, Eun-Ji (Center for Supramolecular Nano-Assembly and Department of Chemistry, Yonsei University) ;
  • Lee, Myong-Soo (Center for Supramolecular Nano-Assembly and Department of Chemistry, Yonsei University)
  • Published : 2008.08.20
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Abstract

Dumbbell-shaped aromatic amphiphilic molecules consisting of a dodeca-p-phenylene as a rigid segment and oligoether dendrons as a flexible chains were synthesized, characterized, and their aggregation behavior was investigated in the bulk and at the air-water interface. In contrast to the molecule 2 which shows a nematic liquid crystalline state, molecule 1 based on shorter dendritic chains was observed to self-assemble into a 3-D primitive orthorhombic supercrystal. And molecule 1 at the air-water interface was observed to reorganize from circular plates to ring structures by lateral compressions.

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References

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