Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Control over [2+2+2] and Carbonylative [4+2] Cycloaddition by CO Pressure in Co-Catalyzed Cycloaddition between Internal Diynes and Cyclopentadiene

  • Kim, Do-Han (Intelligent Textile System Research Center, and Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Chung, Young-Keun (Intelligent Textile System Research Center, and Department of Chemistry, College of Natural Sciences, Seoul National University) ;
  • Han, Jin-Wook (Department of Chemistry, Hanyang University)
  • Published : 2008.06.20
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Abstract

The reaction of internal diynes and cyclopentadiene in the presence of 5 mol % of cobalt catalysts proceeded under 5 atm of carbon monoxide pressure to give a high yield of the corresponding [2+2+2] cycloaddition product. By lowering carbon monoxide pressure from 30 atm to 5atm, cyclopentadiene can be used as a dienophile in the cobalt carbonyl-catalyzed [2+2+2] cycloaddition reaction between internal diynes and cyclopentadiene.

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