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http://dx.doi.org/10.5012/bkcs.2008.29.6.1224

Control over [2+2+2] and Carbonylative [4+2] Cycloaddition by CO Pressure in Co-Catalyzed Cycloaddition between Internal Diynes and Cyclopentadiene  

Kim, Do-Han (Intelligent Textile System Research Center, and Department of Chemistry, College of Natural Sciences, Seoul National University)
Chung, Young-Keun (Intelligent Textile System Research Center, and Department of Chemistry, College of Natural Sciences, Seoul National University)
Han, Jin-Wook (Department of Chemistry, Hanyang University)
Publication Information
Bulletin of the Korean Chemical Society / v.29, no.6, 2008 , pp. 1224-1228 More about this Journal
Abstract
The reaction of internal diynes and cyclopentadiene in the presence of 5 mol % of cobalt catalysts proceeded under 5 atm of carbon monoxide pressure to give a high yield of the corresponding [2+2+2] cycloaddition product. By lowering carbon monoxide pressure from 30 atm to 5atm, cyclopentadiene can be used as a dienophile in the cobalt carbonyl-catalyzed [2+2+2] cycloaddition reaction between internal diynes and cyclopentadiene.
Keywords
[2+2+2] Cycloaddition; Diyne; Cobalt catalyst
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Times Cited By Web Of Science : 2  (Related Records In Web of Science)
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