Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Surface-Enhanced Raman Scattering of Benzenethiol Adsorbed on Silver-Exchanged Copper Powders

  • Shin, Kuan-Soo (Department of Chemistry, Soongsil University) ;
  • Ryoo, Hyun-Woo (Department of Chemistry, Seoul National University) ;
  • Lee, Yoon-Mi (Department of Chemistry, Seoul National University) ;
  • Kim, Kwan (Department of Chemistry, Seoul National University)
  • Published : 2008.02.20
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Abstract

Micrometer-sized copper (mCu) powders are weakly surface-enhanced Raman scattering (SERS) active by the excitation at 632.8 nm, but nearly ineffective as a SERS substrate at 514.5 nm excitation. The SERS activity of mCu powders at both excitation wavelengths can be increased dramatically by a simple method of the galvanic exchange reaction with AgNO3 in aqueous medium. In this work, the SERS activity of the Ag-exchanged Cu powders (mCu@Ag) has been evaluated by taking a series of Raman spectra using benzenethiol (BT) as the probe molecule. It is clearly confirmed by field emission scanning electron microscopy and X-ray diffractometry that the SERS activity of mCu@Ag powders is, in fact, highly dependent on the extent of galvanic reaction.

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