Bulletin of the Korean Chemical Society

  • 제29권10호
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  • Pages.1983-1987
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  • 2008
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Monitoring of the Transfer of Tetrachloroaurate(III) Ions by Thin-layer Electrochemistry and Electrochemical Deposition of Metallic Gold over a Graphite Electrode

  • Song, Ji-Seon (Department of Chemistry, Research Institute of Physics and Chemistry, Chonbuk National University) ;
  • Shin, Hyo-Sul (Department of Chemistry, Research Institute of Physics and Chemistry, Chonbuk National University) ;
  • Kang, Chan (Department of Chemistry, Research Institute of Physics and Chemistry, Chonbuk National University)
  • 발행 : 2008.10.20
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초록

This study demonstrates the electrochemical conversion of the synthetic procedure of monolayer-protected clusters using a thin toluene layer over an edge plane pyrolytic graphite electrode. A thin toluene layer with a thickness of 0.31 mm was coated over the electrode and an immiscible liquid/liquid water/toluene interface was introduced. The transfer of the tetrachloroaurate ($AuCl_4^-$) ions into the toluene layer interposed between the aqueous solution and the electrode surface was electrochemically monitored. The $AuCl_4^-$ ions initially could not move through into the toluene layer, showing no reduction wave, but, in the presence of the phase transfer reagent, tetraoctylammonium bromide (TOABr), a cathodic wave at 0.23 V vs. Ag/AgCl was observed, indicating the reduction of the transferred $AuCl_4^-$ ions in the toluene layer. In the presence of dodecanethiol together with TOABr, a self-assembled monolayer was formed over the electro-deposited metallic gold surface. The E-SEM image of the surface indicates the formation of a highly porous metallic gold surface, rather than individual nanoparticles, over the EPG electrode.

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피인용 문헌

  1. Electrochemical deposition of gold at liquid–liquid interfaces studied by thin organic film-modified electrodes vol.16, pp.7, 2012, https://doi.org/10.1007/s10008-011-1613-3