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Synthesis and Characterization of Two New Fluoroplumbate(II) Complexes: Tetrabutylammonium Fluorodihaloplumbate, (But)4N[PbX2F] (X = Cl, I)

  • Published : 2008.08.20

Abstract

Tetrabutylammonium Fluorodichloroplumbate(II), N$(C_4H_9)_4$[$PbCl_2F$], TBAFDiCP and Tetrabutylammonium Fluorodiiodoplumbate(II), [$(C_4H_9)_4$N][$PbI_2F$], TBAFDiIP are the first examples of fluoroplumbate salts that have been prepared from the reaction of $(C_4H_9)_4$NF with $PbCl_2$ and $PbI_2$ respectively using either $CH_3CN$ solvent. These new compound characterized by elemental analysis, IR, UV/Visible, $^1H$ NMR, and $^{19}F$ NMR techniques.

Keywords

References

  1. Veltheer, J. E.; Burger, P.; Bergman, R. G. J. Am. Chem. Soc. 1995, 117, 12478 https://doi.org/10.1021/ja00155a012
  2. Grushin, V. V. Angew. Chem., Int. Ed. Engl. 1998, 37, 994 https://doi.org/10.1002/(SICI)1521-3773(19980420)37:7<994::AID-ANIE994>3.0.CO;2-H
  3. Archibald, S. J.; Braun, T.; Gaunt, J. A.; Hobson, J. E.; Perutz, R. N. J. Chem. Soc., Dalton Trans. 2000, 2013
  4. Pagenkopf, B. L.; Carreira, E. M. Chem. Eur. J. 1999, 5, 3437 https://doi.org/10.1002/(SICI)1521-3765(19991203)5:12<3437::AID-CHEM3437>3.0.CO;2-E
  5. Bartlett, N. Proc. Chem. Soc. 1962, 218
  6. Lein, M.; Frenking, G. J. Chem. 2004, 57, 1191
  7. Muetterties, E. L. J. Am. Chem. Soc. 1959, 81, 1084 https://doi.org/10.1021/ja01514a017
  8. Christe, K. O.; Wilson, W. W.; Bau, R. D. J. Am. Chem. Soc. 1990, 112, 7619 https://doi.org/10.1021/ja00177a025
  9. Christe, K. O.; Dixon, D. A.; Mercier, H. P. A.; Slnder, J. C. P.; Schrobilgen, G. J.; Wilson, W. W. J. Am. Chem. Soc. 1994, 116, 2850 https://doi.org/10.1021/ja00086a018
  10. Mahjoub, A. R.; Leopold, D.; Seppelt, K. Z. Anorg. Chem. 1992, 618, 83 https://doi.org/10.1002/zaac.19926180115
  11. Mahjoub, A. R.; Seppelt, K. Angew. Chem. Int. Ed. Engl. 1991, 30(7), 876 https://doi.org/10.1002/anie.199108761
  12. Mahjoub, A. R.; Ghammami, S.; Abbasi, A. R.; Hosseinian, A. J. Chem. Research 2000, S10, 486
  13. Mahjoub, A. R.; Ghammami, S.; Abbasi, A. R.; Hosseinian, A. Indian J. Chem. 2000, 39A, 434
  14. Giese, S.; Seppelt, K. Angew. Chem. Int. Ed. Engl. 1994, 33(4), 461 https://doi.org/10.1002/anie.199404611
  15. Ghammamy, S.; Rezaeibehbehani, G. R. Russian J. Inorg. Chem. 2005, 50, 1671
  16. Lehtonen, A.; Sillanpaa, R. Polyhedron 1994, 13, 2519 https://doi.org/10.1016/S0277-5387(00)83093-4
  17. Grubbs, R. H. Comprehensive Organometalic Chemistry; New York, 1982; Vol. 8, p 1193
  18. Berger, S.; Braun, S.; Kalinowski, H.-O. NMR Spectroscopy of the Non-metallic Elements; John Wiley & Sons Ltd.: 1997
  19. Schrock, R. R. Reaction of Coordinated Ligands; Plenum Press: New York, 1986

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