Journal of Korean Society of Environmental Engineers (대한환경공학회지)

Korean Society of Environmental Engineers (대한환경공학회)
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Sorption of Dissolved Inorganic Phosphorus to Zero Valent Iron and Black Shale as Reactive Materials

반응매질로서의 영가철 및 블랙셰일에 용존무기 인산염 흡착

  • Min, Jee-Eun (Department of Civil Engineering, Hanyang University) ;
  • Park, In-Sun (Department of Civil Engineering, Hanyang University) ;
  • Ko, Seok-Oh (Department of Civil Engineering, Kyunghee University) ;
  • Shin, Won-Sik (Department of Environmental Engineering, Kyungpook National University) ;
  • Park, Jae-Woo (Department of Civil Engineering, Hanyang University)
  • Published : 2008.09.30
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Abstract

In order to reduce the availability of dissolved inorganic phosphorus in surface water, lakes, and estuaries, black shale and zero valent iron can be used as reacitve materials. Sorption of phosphate to sampled sediment, black shale, and zero valent iron was quantitatively evaluated in this research. Effect of coexistence of calcium was also tested, since coexisting ions can enhance the precipitation of phosphate. An empirical kinetic model with fast sorption(k$_t$), slow sorption(k$_s$), and precipitation(k$_p$) was well fitted to experiment data from this research. Langmuir and Freundlich sorption isotherms were also used to evaluated phosphate maximum sorption capacity. Calcium ions at 0, 1 and 5 mM affected the precipitation kinetic coefficient in empirical kinetic model but did not have impact on the maximum sorbed concentration.

본 연구는 지표수나 호소수 등에서 유기 및 무기오염물질의 저감을 위해 반응매질로서 사용되는 black shale 및 영가철의 수중의 무기인산염을 흡착제거하는 데 있어서의 정량적 특성을 알아보았다. 무기인산염의 회분식 흡착실험에는 갯벌에서 마련한 퇴적토, black shale, 영가철이 흡착제로 사용되었으며 인산염의 흡착에 미치는 영향을 공존 칼슘이온의 농도를 0, 1, 5 mM로 변화시켜 실험하였다. 칼슘이온의 공존과 함께 세 흡착제에 대한 인산염 농도감소를 빠른 흡착계수(k$_f$), 느린 흡착계수(k$_s$)과 침전계수(k$_p$)로 구성된 kinetic model을 이용하여 해석하였다. 등온흡착의 결과는 Langmuir와 Freundlich 모델을 적용하였으며 퇴적토, black shale, 영가철에 대한 Freundlich 모델의 K$_f$값은 각각 1.141, 7.721, 그리고 4.873였다. 공존하는 칼슘이온과의 침전가능성으로 인하여 kinetic model에서는 칼슘농도와 침전제거간의 상관관계가 있었으나 등온흡착식에서 인산염의 최대흡착량에는 칼슘농도가 영향을 미치지 않았다.

Keywords

References

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