• The Journal of Engineering Geology
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• v.23 no.4
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• pp.341-352
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• 2013

The physical and mechanical properties of red shale and black shale exposed in the Daegu area were investigated in tests conducted to determine unit weight, absorption ratio, porosity, ultrasonic velocity, unconfined compressive strength, point load strength, slake durability index, and deterioration characteristics. XRD, XRF, and SEM analyses were also performed on the shale specimens. While the unit weights of the two shales were similar, the absorption ratio and porosity were higher in the red shale than in the black shale. Despite the higher porosity of the red shale, the ultrasonic velocity, compressive strength, and point load strength were higher in the red shale, which is an unexpected result that may be due to the presence of fine laminations in the black shale. The deterioration rate, as determined from the point load strength and the slake durability index, increased with increasing immersion time and with the acidity of the immersion liquid. The deterioration rate was higher for the red shale than for the black shale because of the higher porosity of the former.

• Economic and Environmental Geology
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• v.37 no.6 s.169
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• pp.585-601
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• 2004

A general study of domestic black sandstone and black shale quarries has not been made. For this reason it is difficult to know how the matter really stands. The objectives of this study are to achieve systematical and scientific study of the distribution, occurrences and rock quality of black sandstone and black shale resources exploited in existing quarries in the Boryeong area. The black sandstone bed survey was made from 54 mine claims on 4 sheets. In the area, 140 black sandstone and 22 black shale quarries were ascertained in 37 mine claims. The general development information data from that existing quarries were collected and synthesized. Among these black sandstone quarries for gravestones, monuments and black shale quarries for inkstone are in operation. Most of the black sandstone quarries were closed throughout the Gaewhari, Suburi, Seongjuri district in the investigated area even though these quarries had played a prominent part in the production of black sandstone. In view of commercial dimension stones, raw materials from black sandstone are classified as corestone and fresh rock body according to the characteristics of their occurrences and shape. Black sandstone beds are characteristically well-jointed and are particularly subdivided into cubic or quadrangular blocks in 3 joint sets. The colors of these black sandstones show medium dark $gray\~grayish$ black judging from the Rock Color Chart. The black sandstone beds which are intercalated in the Amisan, Jogeri, Baegunsa, Seongjuri Formations of the Daedong Supergroup are about $1\~10\;m$ in thickness.

• Proceedings of the KSEEG Conference
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• 2002.04a
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• pp.19-21
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• 2002

• Proceedings of the KSEEG Conference
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• 2001.04a
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• pp.393-395
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• 2001

• Economic and Environmental Geology
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• v.36 no.4
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• pp.295-304
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• 2003

The Dukpyung and the Chubu areas were selected to investigate the migration and enrichment of arsenic and other toxic elements in soils and crop plants in areas covered with black shales. Rock and soil samples digested in 4-acid solution (HCI+HNO$_3$+HF+HC1O$_4$) were analyzed fer arsenic and other heavy metals by ICP-AES and ICP-MS, and plant samples by INAA. Mean concentration of As in Okchon black shale is higher than those of both world average values of shale and black shale. Especially high concentration of 23.2 mg/kg As is found in black shale from the Dukpyung area. Mean concentration of As is highly elevated in agricultural soils from the Duk-pyung (28.2 mg/kg) and the Chubu areas (32.6 mg/kg). Arsenic is highly elevated in rice stalks and leaves from the Dukpyung (1.14 mg/kg) and the Chubu areas (1.35 mg/kg). The biological absorption coefficient (BAC) of As in plant species decreases in the order of rice leaves>com leaves>red pepper>soybean leaves=sesame leaves>corn stalks>corn grains.

• 한국해양학회지
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• v.22 no.2
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• pp.87-104
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• 1987

The middle Cretaceous stratigraphec section of Deep Sea Drilling Project (DSDP) Site 530 in the Angola Basin is characterized by cyclic interbeds of organic-carbon-rich black shales and organic-carbon-poor red and green claystones, namely the black shale sequence. A number of samples from the black shale sequence were analyzed for the typesand distribution of insoluble sedimentary organic matter(kerogen) in order to give more information on the depositional conditions of the black shales in the Angola Basin. The dominant type of kerogen in the black shale sequence at Site 530 is amorphous organic matter mainly of marine planktonic algal origin. It probably consists of remains of some unfossiliqed dinoflagellates. The cyclic preservation of organic-carbon-rich black shales in the Angola Basin during the mid-Cretaceous could be explained by the low dissolved-oxygen concentration in the warm, saline deep and bottom waters combined with the sluggish circulation within the highly restricted basin, and the periodic high productivity in the surface waters.

• Geophysics and Geophysical Exploration
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• v.10 no.4
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• pp.393-398
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• 2007

Seismic traveltime tomography technique was conducted at a site composed of black shale. It is well known that black shale has strong anisotropic property. Therefore, the anisotropic property of black shale has to be considered to obtain the appropriate subsurface velocity model by an inversion process. To estimate the anisotropic constant of the velocity of the black shale in the survey area, the relation between the velocity, which is calculated by the straight ray path and the first arrival time, and the angle of the ray propagation was examined. The elliptically shaped relation was found and it reveals that the black shale contains the anisotropic property of velocity. It was also noticed that the horizontal velocity is faster than the vertical velocity. When the estimated anisotropic constant was applied in the process of the velocity inversion for three sets of field data, we could obtain the appropriate velocity structures of the site that is consistent with the result of the geological survey.

• Korean Journal of Environment and Ecology
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• v.12 no.1
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• pp.22-29
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• 1998

This study is investigated for the trace element concentration in the soils derived from different parent rocks, which are serpentinites, metamorphic rocks and black shales, and the absorption of the trace element by Pinus rigida in Hongseong and Keumsan, Chungnam, respectively. The concentrations of nickel, chrominium and cobalt are high in the serpentinites, whereas the concentrations of zinc, molybdenium and iron are high in the metamorphic rocks. These elements in black shale are lower than those in serpentinites and metamorphic rocks. The serpentine soils show high nickel, chrominium and cobalt content, while zinc and iron content are high in the mixed soils(serpentinites + metamorphic rocks) and black shales. Comparing with parent rocks, all of trace elements in their weathered soils are low. The pH of serpentine soil is high, 7.73~9.55 and that of black shale soil in 5.61. In serpentine area, the absorptions of chrominium by P. rigida is lower than its in the soils. The absorption of zinc by P. rigida is high relative to zinc concentration in soils. The Co/Ni and Fe/Ni quotient in P. rigida over serpentine soils are considerably lower than those growing over other soils tpes.

• 한국지구과학회:학술대회논문집
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• 2005.09a
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• pp.32-39
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• 2005

최근 들어 북한 서해안 일대의 원유매장 가능성에 대한 보도가 국내외 언론에 자주 오르내리고 있다. 실제 북한의 서한만 분지는 일일 생산량 450 배럴의 원유가 생산되고 있어 석유부존 가능성이 확인되었고, 중국에서 큰 유전중 하나인 발해만 유전지대와 지리적으로 근접해 있어 대규모 매장 가능성도 있다. 지금까지 밝혀진 북한 서한만의 지질은 중국의 발해만과 유사하다. 후기 원생대와 초기 고생대에 생성된 기반암 위에는 최대 6 ${\sim}$ 10 km 두께의 탄산염암 및 중생대 퇴적암과 4 ${\sim}$ 5 km 두께의 퇴적암이 집적되어 있다. 근원암은 3 km 이상 되는 쥐라기 흑색 셰일과 1 ${\sim}$ 2 km 두께의 백악기 흑색 셰일 그리고 수 km 두께의 중생대 이전의 탄산염암으로 구성되어 있다. 저류층은 높은 공극률을 가진 중생대부터 신생대에 퇴적된 사암과 중생대전에 균열된 탄산염암이다. 원유 트랩은 배사구조, 단층구조, 파묻혀 있는 언덕 그리고 층서형 트랩 형태다. 따라서 서한만에서의 퇴적층들은 다양한 형태의 근원암을 가지며 또한 공극률과 투수율이 높고, 많은 단층에 의한 이동경로를 가지게 되므로, 사암으로 이루어진 석유 저장지만 발견하면 석유를 생산할 수 있을 것으로 추정된다.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2000.05a
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• pp.98-98
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• 2000