DOI QR코드

DOI QR Code

PCBs and PBDEs in Pine Needles of Seoul and Ansung

서울, 안성지역 소나무 잎 중 PCBs와 PBDEs

  • Lee, Sung-Hee (Division of Environmental Engineering, Chungju National University) ;
  • Yeo, Hyun-Gu (Technical Support Department, Gangwon Regional Small and Medium Business Administraion)
  • 이성희 (충주대학교 환경공학부) ;
  • 여현구 (강원지방중소기업청 기술지원과)
  • Published : 2007.09.30

Abstract

Polychlorinated biphenyls(PCBs) and polybrominated diphenyl ethers (PBDEs) were measured in pine needles of Seoul, and Ansung(GyeongGi-do) to investigate composition, source, and regional concentration of PBDEs. Concentration of total PCBs in Seoul and Ansung showed 608, 945 pg/g DW (mean: 777 pg/g DW), respectively, also concentration of total PBDEs(pg/g DW) in Seoul and Ansung showed 7944, 14,255 pg/g DW(mean 11,100 pg/g DW). Tetrachlorinated biphenyls(Tetra-CBs) and Decabromodiphenyl ethers (Deca-BDE) were detected in relatively high concentration compared to other PBDE congeners in Seoul and Ansung. Correlation coefficients(r) of between PCB congeners in pine needles detected of Seoul and Ansung were significant (r=0.85, p<0.01). It suggested that PCBs concentration in pine needles may originate from secondary sources such as air-plant partition. The similarity of between PBDE congeners profile to those of the technical mixture formulation (Bromkal 70-5DE) suggests a source of this product in these sites.

Keywords

References

  1. Marco M, Schreltmuller J., Reuter U, Ballschmiter K, 1993, Correlation between C-6/C-14 chlorinated hydrocarbons levels in the vegetation and in the boundary layer of the troposphere, Environ. Sci. Technol, 27, 1517-1523 https://doi.org/10.1021/es00045a005
  2. Zegers B. N., Wilma E. L., Booiji K, Smittenberg R. H., Boea W., Boon J. D., Boon J P., 2003, Levels of polybrominated diphenyl ether flame retardants in sediment cores from western Europe, Environ. Sci. Technol, 37, 3803-3807 https://doi.org/10.1021/es034226o
  3. Stefan V., Adrian C., Paul S., 2003, Polybrominated diphenyl ethers in marine species from the Belgian North Sea and the Western Scheidt estuary: Levels, profIle, and distribution, Environ.Sci. Technol, 37, 4338-4357
  4. Shin E. S., Yeo H. -G., Cho K -Ch., Chun M.-Y, 2006, Deposition characteristics of atmospheric PCBs by type of leaves in pine needles, Korea of Journal Environmental Health, 32, 46-52
  5. Shim ll. Y, Yeo H.-G., Choi M.-K, Kim T.-W, Chun M.- Y, 2002, Spatial distribution of PCBs using pine needles, J of KSEE, 24, 2227-2237
  6. Gareth T., Andrew J., Sweetman W A, Ockenden D. M., Jones K C., 1998, Air-pasture transfer of PCBs, Environ. Sci. Technol, 32, 936-942 https://doi.org/10.1021/es970761a
  7. Trapp S., Matthies M., 1997; Modelling volatilization of PCDD/F from soil and uptake into vegetation, Environ. Sci. Technol, 31, 71-74 https://doi.org/10.1021/es960133d
  8. Romney L. F., Hobbs P. V., Eltgorth M. W., 1963, Contamination of plant foliage with radioactive fallout, Ecology, 44, 343-349 https://doi.org/10.2307/1932181
  9. Bacci E., Cerejerira M. J., Gaggi c., Chemello G., Calamari D., Vighi M., 1990, Bioconcentration of organic chemical vapors in plant leaves: the azalea model, Chemosphere, 21, 525-535 https://doi.org/10.1016/0045-6535(90)90023-M
  10. Yeo H.-G., Cho K-C., Chun M.-Y, 2006, Composition, source, and regional concentration of PBDEs in pine needles, J of KSEE, 28, 829-835
  11. Chun M.- Y., 1998, A study on the deposition of PCBs in air on coniferous needles, J of KSEE, 20, 1377-1383
  12. Tremolada P., Burnett V., Calamari D., Kevin C. J., 1996, A study of the spatial distribution of PCBs in the UK atmosphere using pine needles, Chemosphere 32, 2189-2203 https://doi.org/10.1016/0045-6535(96)00127-0
  13. Chen L.-G., Mai B.-X., Bi X.-H., Chen S., Wang X.-M., Ran Y, Luo X.-J, Sheng G.-Y, Fu J.-M., Zeng E. Y, 2006, Concentration levels, compositional profiles and gas-particle partitioning of polybrominated diphenyl ethers in the atmosphere of an urban city in south China, Environ. Sci. Technol, 40, 1190-1196 https://doi.org/10.1021/es052123v
  14. Choi J.-W, Jun O., Kimiyoshi K, Shunji H., Hiroyasu I., Noriyuki S., Shin I. S., Masatoshi M., 2003, Modified clean-up for PBDD, PBDF and PBDE with an active carbon column- its application to sediments, Chemosphere, 53, 637-643 https://doi.org/10.1016/S0045-6535(03)00534-4
  15. Hassanin A, Knut B., Sandra N. M., Eiliv S., Gareth O. M., Kevin C. J., 2004, PBDEs in European background soil: Levels and factors controlling their distribution, Environ. Sci. Technol, 38, 738-745 https://doi.org/10.1021/es035008y

Cited by

  1. Concentration Distribution of PBDEs and PCBs in Soil vol.35, pp.6, 2009, https://doi.org/10.5668/JEHS.2009.35.6.510