DOI QR코드

DOI QR Code

Effect of Water State in Electroactive Chitosan/Poly (Diallyldimethylammonium Chloride) Hydrogels on Bending Behavior at Various pH Conditions

키토산/폴리디아릴디메틸암모늄클로라이드 전기감응성 고분바 하이드로겔의 굽힘 거동에서 물 상태에 따른 영향 분석

  • Yoon, Seong-Gil (Creative Research Center for Bio-artificial Muscle, Hanyang University) ;
  • Kim, Seon-Jeong (Creative Research Center for Bio-artificial Muscle, Hanyang University) ;
  • Kim, In-Young (Division of Electrical, control, biomedical engineering, Hanyang University) ;
  • Kim, Sun-I. (Division of Electrical, control, biomedical engineering, Hanyang University)
  • 윤성길 (한양대학교 생체인공근육 창의연구단) ;
  • 김선정 (한양대학교 생체인공근육 창의연구단) ;
  • 김인영 (한양대학교 공과대학 전기제어생체공학부) ;
  • 김선일 (한양대학교 공과대학 전기제어생체공학부)
  • Published : 2007.06.30

Abstract

A interpenetrating polymer network (IPN) hydrogel, composed of chitosan (CS) and poly(diallydimethylammonium chloride) (PDADMAC) was prepared, which exhibited electrical sensitive behavior. The swelling behavior of the CS/PDADMAC SIPN hydrogel was studied by immersion of the gel into various pH buffer solutions, and their stimuli response in electric fields also investigated. In order to clarify the relationship between the equilibrium swelling ratio and bending behavior of the SIPN hydrogels, the state of water in the SIPN hydrogel was also investigated using differential scanning calorimetry (DSC).

Keywords

References

  1. S. H. Yuk, H. B. Lee, 'Electric-current sensitive polymers. Reversible bending of rod-shaped acrylamide gel in NaCl solution,' J. Polym. Sci., PartB: Pol. Phys., vol. 31, pp. 487-489, 1993 https://doi.org/10.1002/polb.1993.090310415
  2. G. B. Park, Y. Kagami, J. P. Gong, D. C. Lee, Y. Osadr., 'Chemomechanical bending behaviors of ionizable thin films with gradient network-size,' Thin Solid Films, vol. 350, pp. 289-294, 1999 https://doi.org/10.1016/S0040-6090(99)00297-7
  3. Y. Yang, B. F. N. Engberts, 'Stimuli response of polysoao hydrogels in aqueous solution and DC electric fields,' Colloid Surface A, vol. 169, pp. 85-94, 2000 https://doi.org/10.1016/S0927-7757(00)00420-9
  4. J. Fei, Z. Zhang, L. Gu, 'Bending behaviour of electroresponsive poly(vinyl alcohol)/poly(acrylic acid) semi-interpenetrating network hydrogel fibres under an electric stimulus,' Polym. Int, vol. 51, pp. 502-509, 2002 https://doi.org/10.1002/pi.910
  5. W. F. Lee, Y. J. Chen, 'Studies of preparation and swelling properties of the N-isopropylacrylamide/chitosan semi-IPN and IPN hydrogels,' J. Appl. Polym. Sci., vol.82, pp. 2487-2496, 2001 https://doi.org/10.1002/app.2099
  6. C. Peniche, A. M. Waldo, N. Davidenko, R. Sastre, A. Gallarde, J. S. Roman, 'Self-curing membranes of chitosan/PAA IPNs obtained by radical polymerization: preparation, characterization and interpolymer complexation,' Biomaterials, vol. 20, pp. 1869-1878, 1999 https://doi.org/10.1016/S0142-9612(99)00048-4
  7. D. W. Kang, H. R. Choi,D. K. Kweon, 'Stability constants cf amidoximated chitosan-g-poly(acrylonitrile) copolymer for heavy metal ions,' J. Appl. Polym. Sci., vol. 73, pp. 469-476, 1999 https://doi.org/10.1002/(SICI)1097-4628(19990725)73:4<469::AID-APP2>3.0.CO;2-I
  8. J. Ren, Y. Zhang, J. Li, J. Ja, 'Radiation synthesis and characteristic of IPN hydrogel composed of poly(diallyldimethylammonium chloride) and Kappa-Carrageenan,' Radiat. Phys. Chem., vol.62, , pp. 277-281, 2001 https://doi.org/10.1016/S0969-806X(01)00186-4
  9. G. Albin, T. A. Horbett, B. D. Ratner, 'Glucose sensitive membranes for controlled delivery of insulin: Insulin transport studies,' J. Controlled Release, vol. 2, pp. 153-164, 1985 https://doi.org/10.1016/0168-3659(85)90041-0
  10. B. Park, J. O. You, H. Y. Park, S. J. Haam, W. S. Kim, 'A novel pH-sensitive membrane from chitosan TEOS IPN; preparation and its drug permeation characteristics,' Biomaterials, vol. 22, pp. 323-330, 2001 https://doi.org/10.1016/S0142-9612(00)00187-3
  11. S. Y. Kim, S. M. Cho, Y. M. Lee, S. J. Kim, 'Thermo-and pH-responsive behaviors of graft copolymer and blend based on chitosan and N-isopropylacrylamide,' J. Appl. Polym. Sci., vol. 78, pp. 1381-1391, 2000 https://doi.org/10.1002/1097-4628(20001114)78:7<1381::AID-APP90>3.0.CO;2-M
  12. M. Shahinpoor, 'Micro-electro-mechanics of ionic gels as electrically-controllable artificial muscles,' J. Intel. Mater. Syst , vol.6, pp. 307-314, 1995 https://doi.org/10.1177/1045389X9500600302
  13. T. Shiga, T. Kurauchi, 'Deformation of polyelectrolyte gels under the influence of electric field,' J. Appl. Polym. Sci., vol. 39 , pp. 2305-2320, 1990 https://doi.org/10.1002/app.1990.070391110
  14. M. Shahinpoor, Y. Bar-Cohen, J. O. Simpson, S. Smith, 'Ionic polymer metal composites (IPMCs) as biomimitic sensors, actuators and artificial muscles a review,' Smart Mater. Struct , vol. 7, pp. R15-R30, 1998 https://doi.org/10.1088/0964-1726/7/6/001