The Effect of Additive to Corrosion Resistance of Heavy Anti-Corrosive Paint

중방식 도료의 내식성에 미치는 첨가제의 영향

  • Moon, Kyung-Man (Dept. of Mechanical and Material Engineering, Korea Maritime Univ.) ;
  • Cho, Hwang-Rae (Dept. of Mechanical and Material Engineering, Korea Maritime Univ.) ;
  • Lee, Myung-Hoon (Dept. of Marine System Engineering, Korea Maritime Univ.) ;
  • Kim, Hyun-Myung (Byucksanpaint & Coatings co, ltd.) ;
  • Lee, In-Won (Dept. of Naval Architecture and Ocean Engineering, Pusan Nation Univ.) ;
  • Chun, Ho-Hwan (Dept. of Naval Architecture and Ocean Engineering, Pusan Nation Univ.)
  • 문경만 (한국해양대학교 기계소재공학부) ;
  • 조황래 (한국해양대학교 기계소재공학부) ;
  • 이명훈 (한국해양대학교 기관시스템공학부) ;
  • 김현명 (벽산페인트(주)) ;
  • 이인원 (부산대학교 조선해양공학과) ;
  • 전호환 (부산대학교 조선해양공학과)
  • Published : 2007.06.29

Abstract

There are many kinds of protection methods for marine structures, with varyingeconomical and environmental advantages. The coating protection method is being widely used in both continental and marine structures. In this study, by adding some additives, such as Zn powder(Zn), carbon black(CB) to epoxy anti-corrosive paint, the effect on the corrosion resistance was investigated throughan electrochemical method. The additive of Zn(20)+CB(10) showed the lowest passivity current density. Polarization resistance in both cyclic voltammogram and impedance measurement of an additive of Zn(20)+CB(10) was also the largest value, compared to other additives. Furthermore, rusting and bubbling was not observed on the surface of the test specimen with the additive of Zn(20)+CB(10), compared to other specimens. It is suggested that the corrosion resistance of the anti-corrosive paint can be improved by using some additives.

Keywords

References

  1. 김귀식, 한세웅, 현창해 (2005). '소형선박용 프로펠러의 부식녹 제거장치 개발', 한국해양공학회지, 제19권, 제6호, pp 72-77
  2. 문경만 (1999). '알기 쉬운 문답식 실용전기화학', 효성출판사, pp 106-148
  3. 부식손실조사보고서 (1977). 일본방식기술협회
  4. 성호진, 김진경, 이명훈, 김기준, 문경만 (2005). '중방식도료의 내식성에 관한 전기화학적 평가', 한국마린엔지니어링학회지, 제29권, 제5호, pp 519-525
  5. Cicognami, P. (1990). 'Application of the Boundary-Element Method to Offshore Cathodic Protection Modeling', J.Electrochem.Soc., Vol 137, No 6, pp 1689-1695 https://doi.org/10.1149/1.2086771
  6. Compton, K.G. (1961). 'Factor Involved in Corrosion of Lead Cable Sheath', CORROSION, Vol 17, pp 115-118
  7. Gartland, P.O., Bardel, E., Andresen, R.E. and Johnson, R. (1984). 'Effect of Flow on the Cathodic Protection of a Steel Cylinder in Sea Water', CORROSION' Vol 40, No 3, pp 127-133 https://doi.org/10.5006/1.3593927
  8. Hiramatsi, M., Hino, M. and Omi, T. (1996). 'Current Trend in Development of corrosion Protective Plating', Zairo-to-Kankyo, Vol 45, No 1, pp 33-41 https://doi.org/10.3323/jcorr1991.45.33
  9. Jones, D.A. and Nair, N.R. (1985). 'Electrochemical Corrosion Studies on Zinc- Coated Steel', CORROSION, Vol 41, No 6, pp 357-362 https://doi.org/10.5006/1.3582017
  10. Newman, J. (1991). 'Cathodic Protection with Parrel Cylinders', J. Electrochem. Soc., Vol 130, No 12, pp 3554-3559
  11. Steinsmo, U. and Bardal, E. (1989a). 'Factors Limiting the Cathodic Current on Painted Steel', J. Electrochem. Soc., Vol 136, No 12, pp 3588-3594 https://doi.org/10.1149/1.2096514
  12. Steinsmo, U., Ska, J.I., and Bardal, E. (1989b). 'The Effect of the Dry Film Thickness, Temperature, and Electrolyte on the Cathodic Current of Painted Steel', J. Electrochem. Soc., Vol 136, No 12, pp 3383-3587
  13. Talati, J.D., Patel, G.A. and Gandhi, D.K. (1984). 'Maximum Utilization Current Density', CORROSION, Vol 40, No 2, pp 88-91 https://doi.org/10.5006/1.3593921
  14. The Overseas Coastal Area Development Institute of Japan (1998). Corrosion Protection and Repair Manual for Port and Harbor Steel Structures, pp 27-96