Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
권호 표지
DOI QR코드

DOI QR Code

Investigation of the Interactions between Anionic Polymer and Nonionic Surfactant with Rheological and Surface Tension Measurements

유변학적 특성과 표면장력측정을 통한 음이온성 폴리머와 비이온성 계면활성제의 상호작용에 대한 연구

  • Lee, Jung-No (Dept. of Bio Quality Control, Korea Bio Polytechnic) ;
  • Kim, Dong-Joo (Cosmetics R&D Center, LG Household & Health Care Ltd.) ;
  • Koh, Ha-Young (Dept. of Bio Quality Control, Korea Bio Polytechnic)
  • 이정노 (한국폴리텍바이오대학 바이오품질관리과) ;
  • 김동주 ((주) LG 생활건강 화장품연구소) ;
  • 고하영 (한국폴리텍바이오대학 바이오품질관리과)
  • Published : 2007.06.30
Download PDF
⟨ Previous Next ⟩

Abstract

The rheological properties and surface tensions of polymer solutions and polymer-surfactant mixed solutions were investigated. The polymers used in this study were a homopolymer of acrylic acid crosslinked with an allyl ether of pentaerythritol, an allyl ether of sucrose, or an allyl ether of propylene (CARBOMER), acylate/C10-30 alkyl acylate crosspolymer (AAAC), and ammonium acryloydimethyltaurate/VP copolymer (ADTV). A solubilizing agent PEG-40 hydrogenated castor oil (HCO-40) and an emulsifying agent polyoxyethylene (20) sorbitan monostearate (POLYSORBATE 60) made the micelles intervening between AAAC polymers, resulting in the increase of viscosity. However, HCO-40 made this behavior over the wider range of surfactant concentration than POLYSORBATE 60. From the view point of surface tensions in the same range of surfactant concentration, AAAC/HCO-40 solution showed the area of increasing surface tension with surfactant concentration in contrast to the AAAC/POLYSORBATE 60 solution showing no increasing area.

Keywords

References

  1. R. Zana, Polymer-Surfactant Systems, Kwak, J C. T., Marcel Dekker, New York, pp. 409-454 (1998)
  2. E. D. Goddard, Principles of Polymer Science and Technology in Cosmetics and Personal Care, E. D. Goddard and J. Gruber, Marcel Dekker, New York, Chapter 4, pp.1l3-180 (1999)
  3. J. Lee and Y. Moroi, Solubilization Study for Aggregates of Sodium dodecyl Sulfate and Cationic Polymer of High Charge Density, J. Colloid Interface Sci., 273, 645 (2004) https://doi.org/10.1016/j.jcis.2004.01.079
  4. J. Lee and Y. Moroi, Solubilization of n-Alkylbenzenes in Aggregates of Sodium Dodecyl Sulfate and a Cationic Polymer of High Charge Density (II), Langmuir, 20, 6116 (2004) https://doi.org/10.1021/la030443r
  5. S. Sallustio, L.Galantini, G. Gente, G. Masci, and C. La Mesa, Hydrophobically Modified Pullulans : Characterization and Physicochemical Properties, J. Phys. Chem B., 108, 18876 (2004) https://doi.org/10.1021/jp048068e
  6. S. Nilsson, K. Thuresson, P. Hansson and B. Lindman, Mixed Solutions of Surfactant and Hydrophobically Modified Polymer. Controlling Viscosity with Micellar Size, J. Phys. Chem. B, 102, 7099 (1998) https://doi.org/10.1021/jp9812379
  7. S. Panmai, R. Prud'hornrne, D. Peiffer, S. Jochusch and N. Turro, Interactions between Hydrophobically Modified Polymers and Surfactants: A Fluorescence Study, Langmuir, 18, 3860 (2002) https://doi.org/10.1021/la020165g
  8. T. Noda, A. Hashidzume and Y. Morishima, Rheological Properties of Transient Networks Formed from Copolymers of Sodium Acrylate and Methacrylates Substituted with Arnphiphiles: Comparison with Sodium 2-(Aerylamido)-2-methylpropanesulfonate Copolymers, Langmuir, 17, 5984 (2001)
  9. B. Magny, F. Lafuma and I. Iliopoulos, Determination of Microstructure of Hydrophobically Modified Water-soluble Polymers by 13C N.M.R., Polymer, 33, 3151 (1992) https://doi.org/10.1016/0032-3861(92)90227-N
  10. J. Lee and Y. Moroi, Binding of Sodium Dodecyl Sulfate to a Cationic Polymer of High Charge Density, Bull. Chem Soc. Jpn., 76, 2099 (2003) https://doi.org/10.1246/bcsj.76.2099
  11. C. J. Davidson, P. Meares and D. G. Hall, A Polymeric Electrode for Ionic Surfactants, J. Membr. Sci., 36, 511 (1988) https://doi.org/10.1016/0376-7388(88)80040-1
  12. K. Hayakawa and J. C. T. Kwak, Cationic Surfactants: Physical Chemistry, D. N. Rubingh and P. M. Holland, Marcel Dekker, New York, Chapter 5, (1990)
  13. K. Hayakawa, J. P. Santerre and J. C. T. Kwak, Study of Surfactant-Polyelectrolyte Interactions. Binding of Dodecyl- and Tetradecyltrimethylammonium Bromide by Some Carboxylic Polyelectrolytes, Macromolecules, 16, 1642 (1983) https://doi.org/10.1021/ma00244a017
  14. K. Shirahama, S. Sato, N. Niino and N. Takisawa, Interaction of Surfactant with Polymer Gel Binding Isotherm and Swelling Ratio, Colloids surf A, 112, 233 (1996) https://doi.org/10.1016/0927-7757(96)03671-0
  15. J. Liu, M. Nakama, N. Takisawa and K. Shirahama, Binding of Dodecyloxyethylpyridiniurn Bromide to Polymer: the Effect of Molecular Geometry of Surfactant, Colloids surf A, 150, 275(1999) https://doi.org/10.1016/S0927-7757(98)00819-X
  16. C. W. Macosko, Rheology: Principles, Measurements and Applications, John Wiley & Sons, New York (1994)