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한반도 동남해와 남동해 표층수에서 알케논 수온계산식의 비교

Comparison of Alkenone Equations for Surface Water Temperature Estimation in the Eastern South Sea and Southern East Sea, Korea

  • 신경훈 (한양대학교 과학기술대학 해양환경과학과) ;
  • 윤숙희 (한양대학교 과학기술대학 해양환경과학과)
  • Shin, Kyung-Hoon (Department of Environmental Marine Science, College of Science & Technology Hanyang University) ;
  • Yoon, Suk-Hee (Department of Environmental Marine Science, College of Science & Technology Hanyang University)
  • 발행 : 2007.03.31

초록

A series of long chain unsaturated ketone (alkenone) was identified in the particulate organic matter sampled from surface water of the eastern South Sea, Korea. The seawater temperature based on the $C_{37}$ alkenone was calculated by using several different equations of unsaturation index(${U^{K'}}_{37}$), compared with in situ CTD temperature. Among the previously reported equations, the equation(0.044T-0.204) which was proposed by Sawada et al.(1996) seems to be the most useful for the calculation of $C_{37}$ alkenone temperature, showing average $0.51^{\circ}C$ difference between ${U^{K'}}_{37}$ temperature and in situ CTD temperature. This result suggest that alkenone should be a useful molecular biomarker for reconstructing paleo-environmental change in the South and East Sea, Korea. However, it is required to establish more reliable equation for the calculation of $C_{37}$ alkenone temperature.

키워드

참고문헌

  1. 강영실, 조영조, 고우진, 김성수, 전경암, 오현주. 2000. 한국 남해안에서 살파류(Tunicata: Thaliacea)의 대번식과 해양 생태계에 미치는 영향. J. Kor. Soc. Oceanogr., 5, 47-58
  2. 양동범. 1992. 1986년 하계 마산만의 각종 질소 화합물 분포와 산소 소비율에 대한 연구. 한국해양학회지, 27, 303-310
  3. Ahn, Y.H., P. Shanmugam, K.I. Chang, J.E. Moon, and J.H. Ryu. 2005. Spatial and temporal aspects of phytoplankton blooms in complex ecosystems off the Korean coast from satellite ocean color observations. Ocean Sci. J., 40, 67-78 https://doi.org/10.1007/BF03028587
  4. Bentaleb, I., J.O. Grimalt, F. Vidussi, J.C. Marty, V. Martin, M. Denis, C. Hatte, and M. Fontugne. 1999. The $C_{37}$ alkenone record of seawater temperature during seasonal thermocline stratification. Mar. Chem., 64, 301-313 https://doi.org/10.1016/S0304-4203(98)00079-6
  5. Brassell, S.G., G. Eglinton, I.T. Malowe, U. Pflaumann, and M. Sarnthein. 1986. Molecular stratigraphy: a new tool for climate assessment. Nature, 320, 129-133 https://doi.org/10.1038/320129a0
  6. Conte, M.H., T. Anthony, L. David, and P.H. Roger. 1998. Genetic and physiological influences on the alkenone/ alkenoate versus growth temperature relationship in Emiliania huxleyi and Gephyrocapsa Oceanica. Geochim. Cosmochim. Acta, 62, 51-68 https://doi.org/10.1016/S0016-7037(97)00327-X
  7. Epstein, B.L., S. D'Hondt, J.G. Quinn, J. Zhang, and P.E. Hargraves. 1998. An effect of dissolved nutrient concentrations on alkenone-based temperature estimates. Paleoceanography, 13, 122-126 https://doi.org/10.1029/97PA03358
  8. Furuya, K., M. Hayashi, Y. Yabushita, and A. Ishikawa. 2003. Phytoplankton dynamics in the East China Sea in spring and summer as revealed by HPLC-derived pigment signatures. Deep-Sea Res. II, 50, 367-387 https://doi.org/10.1016/S0967-0645(02)00460-5
  9. Harada, N., N. Handa, K. Harada, and H. Matsuoka. 2001. Alkenones and particulate fluxes in sediment traps from the central equatorial Pacific. Deep-Sea Res. I, 48, 891-907 https://doi.org/10.1016/S0967-0637(00)00077-7
  10. Harada, N., K.H. Shin, A. Murata, M. Uchida, and T. Nakatani. 2003. Characteristics of alkenones synthesized by a bloom of Emiliania huxleyi in the Bering Sea. Geochim. Cosmochim. Acta, 67, 1507-1519 https://doi.org/10.1016/S0016-7037(02)01318-2
  11. Hong, G.H., S.-M. Choe, M.-S. Suk, J.-Y. Na, I.C. Sin, C.S. Chung, and S.H. Kim. 1996. Annual biogenic particle fluxes to the interior of the East/Japan Sea, a large marginal sea of the Northwest Pacific. p. 300-321. In: Biogeochemical processes in the North Pacific. ed. by S. Tsunogai. Proceedings of the International Marine Science Symposium held on 12-14 November 1996 at Mutsu, Aomori, Japan
  12. Lee, K.E. and R. Schneider. 2005. Alkenone production in the upper 200 m of the Pacific Ocean. Deep-Sea Res. I, 52, 443-456 https://doi.org/10.1016/j.dsr.2004.11.006
  13. Lee, K.E. and K.R. Kim. 2002. Past sea surface temperature of the East Sea inferred from alkenone. J. Kor. Soc. Oceanogra., 37, 27-34
  14. Lee, T. and I.N. Kim. 2003. Chemical imprints of the upwelled waters off the Coast of the Southern East Sea of Korea. J. Kor. Soc. Oceanogr., 38, 101-110
  15. Park, M.O., C.H. Moon, H.S. Yang, and J.S. Park. 1999. Distribution of phytoplankton pigments in the Korea Strait. J. Kor. Soc. Oceanogr., 34, 95-112
  16. Popp, B.N. and F. Kenig. 1998. Does growth rate affect ketone unsaturation and intracellular carbon isotopic variability in Emiliania huxleyi?. Paleoceanography, 13, 35-41 https://doi.org/10.1029/97PA02594
  17. Prahl, F.G. and S.G. Wakeham. 1987. Calibration of unsaturation patterns in long-chain ketone compositions for paleotemperature assessment. Nature, 330, 367-369 https://doi.org/10.1038/330367a0
  18. Prahl, F.G., L.A. Muehlhausen, and D.L. Zahnle. 1988. Further evaluation of long-chain alkenones as indicators of paleoceanographic conditions. Geochim. Cosmochim. Acta, 52, 2303-2310 https://doi.org/10.1016/0016-7037(88)90132-9
  19. Prahl, F.G., G.J. DeLange, M. Lyle, and M.A. Sparrow. 1989. Post-depositional stability of long-chain alkenones under contrasting redox conditions. Nature, 341, 434-437 https://doi.org/10.1038/341434a0
  20. Prahl, F.G., G.V. Wolfe, and M.A. Sparrow. 2003. Physiological impacts on alkenone paleothermometry. Paleoceanography, 18, 2002PA000803 https://doi.org/10.1029/2002PA000803
  21. Sawada, K., N. Handa, Y. Shiraiwa, A. Danbara, and S. Monatni. 1996. Long-chain alkenones and alkyl alkenoates in the coastal and pelagic sediments of the northwest North Pacific with special reference to the reconstruction of Emiliania huxleyi and Gephyrocapsa oceanica ratios. Org. Geochem., 24, 751-764 https://doi.org/10.1016/S0146-6380(96)00087-3
  22. Sawada, K., N. Handa, and T. Nakatsula. 1998. Production and transport of long-chain alkenones and alkyl alkenoates in a sea water column in the northwestern Pacific off central Japan. Mar. Chem., 59, 219-234 https://doi.org/10.1016/S0304-4203(97)00074-1
  23. Shin, K.H., N. Tanaka, N. Harada, and J.C. Marty. 2002. Production and turnover rates of $C_{37}$ alkenones in the eastern Bering Sea: Implication for the mechanism of a long duration of Emiliania huxleyi bloom. Prog. Oceanogr., 55, 113-129 https://doi.org/10.1016/S0079-6611(02)00073-3
  24. Sike, E., J.K. Volkman, L.G. Robertson, and J.J. Pichon. 1997. Alkenones and alkenes in surface waters and sediments of the Southern Ocean: Implications for paleotemperature estimation in polar regions. Geochim. Cosmochim. Acta, 61, 1495-1505 https://doi.org/10.1016/S0016-7037(97)00017-3
  25. Ternois, Y., M.A. Sicre, A. Boireau, M.H. Conte, and G. Eglinton. 1997. Evaluation of long-chain alkenones as paleo-temperature indicators in the Mediterranean Sea. Deep-Sea Res. I, 44, 271-286 https://doi.org/10.1016/S0967-0637(97)89915-3
  26. Volkman, J.K., G. Eglinton, E.D.S. Corner, and J.R. Sargent. 1979. Novel unsaturated straight-chain $C_{37}-C_{39}$ methyl and ethyl ketones in marine sediments and a coccolithophorid Emiliania huxleyi. p. 219-227. In: Advances in Organic Geochemistry. ed. by A.G. Douglas and J.R. Maxwell. Pergamon Press, Oxford
  27. Volkman J.K., G. Eglinton, E.D.S. Corner, and T.E.V. Forsberg. 1980. Long-chain alkanes and alkenones in the marine coccolithophorid Emiliania huxleyi. Phytochemistry, 19, 2619-2622 https://doi.org/10.1016/S0031-9422(00)83930-8
  28. Volkman, J.K., M.B. Stephanie, I.B. Susan, and L.S. Elisabeth. 1995. Alkenones in Gephyrocapsa oceanica: Implications for studies of paleoclimate. Geochim. Cosmochim. Acta, 59, 513-520 https://doi.org/10.1016/0016-7037(95)00325-T