Macromolecular Research

  • 제15권1호
  • /
  • Pages.17-21
  • /
  • 2007
  • /
  • 1598-5032(pISSN)
  • /
  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Preparation of Amine-Containing Poly(amide-sulfone)s Using Vinylsulfone Reactive Monomers and Their Properties

  • Jeon, Young-Min (Department of Chemistry and Institute of Basic Science, Dankook University) ;
  • Lim, Tai-Ho (Department of Chemistry and Institute of Basic Science, Dankook University) ;
  • Kim, Soo-Han (Department of Chemistry and Institute of Basic Science, Dankook University) ;
  • Kim, Jong-Gyu (Department of Chemistry and Institute of Basic Science, Dankook University) ;
  • Gong, Myoung-Seon (Department of Chemistry and Institute of Basic Science, Dankook University)
  • 발행 : 2007.02.28
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초록

A series of new, vinyl sulfone-containing monomers was prepared by p-aminophenyl vinyl sulfone (1) with various acid chlorides such as adipoly chloride, terephthaloyl chloride and isophthaloyl chloride. Finally, tertiary amine-containing poly(amide-sulfone)s were prepared by the Michael-type addition polymerization using N,N-dimethylethylenediamine (DMEDA), p-phenylenediamine and piperazin. To evaluate the relevant properties for permselective membranes and enzyme substrate, various physical properties such as molecular weight, solubility, quaternization behavior and thermal properties were examined.

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