Bulletin of the Korean Chemical Society

  • 제28권12호
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  • Pages.2253-2260
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  • 2007
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Polarity Probing Two-Photon Fluorophores Based on [2.2]Paracyclophane

  • Woo, Han-Young (Department of Nanomaterials Engineering (BK21), Pusan National University) ;
  • Korystov, Dmitry (Institute for Polymers and Organic Solids, University of California) ;
  • Jin, Young-Eup (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University) ;
  • Suh, Hong-Suk (Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University)
  • 발행 : 2007.12.20
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초록

A series of tetra donor substituted [2.2]paracyclophane-based two-photon absorption (TPA) fluorophores were synthesized in neutral and cationic forms. The imaging activity of overall set of fluorophores was studied by the two-photon induced fluorescence (TPIF) method in a range of solvents. We also measured a clear progression toward a longer photoluminescence lifetime with increasing solvent polarity (intrinsic photoluminescence lifetime, τi: ~2 ns in toluene → 12-16 ns in water). The paracyclophane fluorophores with this unique property can be utilized as an optical polarity probe for the biomolecular substrates. The combined measurement of the two-photon fluorescence microscopy (TPM) cell image and TPIF lifetime can give us a better understanding of the biological processes and local environments in the cells.

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피인용 문헌

  1. A Two-Photon Dye with Favorable Photophysical Properties and Ultrahigh Polarity Sensitivity Designed by Utilizing the Tautomerism of β-Diketone vol.5, pp.2, 2016, https://doi.org/10.1002/adom.201600696