Effects of Additives for Glyoxal/Aluminium Ammonium Sulfate in Durable Press Finish of Cotton Fabrics

Glyoxal/Aluminium Ammonium Sulfate를 이용한 면직물의 DP가공에서 첨가제의 영향

  • Cho, Hang-Sung (Textile Materials Division, Korea Institute of Industrial Technology) ;
  • Lee, Beom-Soo (Department of Fiber & Polymer Engineering, Hanyang University) ;
  • Jeong, Seong-Hoon (Department of Fiber & Polymer Engineering, Hanyang University) ;
  • Lee, Eui-So (Department of Textile Engineering, Inha University)
  • 조항성 (한국생산기술연구원 섬유소재본부) ;
  • 이범수 (한양대학교 섬유고분자공학과) ;
  • 정성훈 (한양대학교 섬유고분자공학과) ;
  • 이의소 (인하대학교 섬유공학과)
  • Published : 2006.08.01

Abstract

When glyoxal was used as a crosslinking agent and aluminium ammonium sulfate as a catalyst for durable-press finishing, coreactants and additives to minimize the decrease of physical properties of durable-press finished cotton fabrics were studied. Also, optimum conditions such as coreactant/glyoxal mole ratio, the concentration of additives and the effects of one-bath and two-bath were investigated. Under the optimum concentration of DEG, the whiteness and strength retention of the fabrics treated with glyoxal/DEG/additive mixtures were increased while wrinkle recovery angles were decreased significantly. Under the optimum concentration of each additive, cotton fabrics were treated with various impregnation time in order to find the effect of two-bath method. The whiteness of cotton fabrics was increased by two-bath method, and wrinkle recovery angles were decreased either slightly or unchanged while the strength retention was not affected.

Keywords

References

  1. C. Schramm and B. Rinderer, 'Nonformaldehyde Durable Press Finishing of Cotton Fabric : Quantitative Evaluation of Cellulose-bound Glyoxal', Text Res J, 2002, 72, 357-360 https://doi.org/10.1177/004051750207200413
  2. C. Q. Yang and W. Wei, 'Evaluating Glutaraldehyde as a Nonformaldehyde Durable Press Finishing Agent for Cotton Fabrics', Text Res J, 2000, 70, 230-236 https://doi.org/10.1177/004051750007000309
  3. X. Gu and C. Q. Yang, 'FTIR Spectroscopy Study of the Formation of Cyclic Anhydride Intermediates of Polycarboxylic Acids Catalyzed by Sodium Hypophosphite', Text Res J, 2000, 70, 64-70 https://doi.org/10.1177/004051750007000110
  4. S. B. Vukusic, 'DP Finishing with Polycarboxylic Acid and Phosphono-Based Catalyst', AATCC Review, 2002, 10, 14-16
  5. C. M. Welch and G. F. Danna, 'Glyoxal as a Non-Nitrogenous Formaldehyde-Free Durable-Press Reagent for Cotton', Text Res J, 1982, 52, 149-157 https://doi.org/10.1177/004051758205200209
  6. C. M. Welch and G. F. Danna, 'Glyoxal as a Formaldehyde-Free Durable Press Reagent for Mild Curing Applications', Text Res J, 1983, 53, 181-186 https://doi.org/10.1177/004051758305300307
  7. E. Barbara(Ed.), 'Encyclopedia of Industrial Chemical', 5th Ed., Weinheim VCH, 1989, p. 491
  8. 유영하, '글리옥살 처리에 의한 면직물의 DP 가공시 새로운 촉매', 인하대학교 공학석사 학위논문, 2004
  9. 김승일, '글리옥살을 이용한 면직물의 DP 가공', 인하대학교 공학석사 학위논문, 1999
  10. 김용태, '글리옥살에 의한 면직물의 DP 가공에서 첨가제에 따른 백도 증진', 인하대학교 공학석사 학위논문, 2000
  11. Y. C. Park and J. W. Kim, 'Color Change of Durable Press Finished Cellulosic Fabric by Catalyst(I) - Effect Catalytic Activity on Color Change of Finished Fabric', J Korean Fiber Soc, 1997, 34, 629-634
  12. B. A. K. Adrews and R. M. Rheinhardt, 'How Mixed Catalysts Differ', Text Res J, 1982, 52, 123-132 https://doi.org/10.1177/004051758205200206
  13. U. Meyer, K. Muller, H. K. Routte, and H. Zollinger, 'Comparison of Catalytic Activities and Textile Mechanical Properties Observed in the Crosslinking of Cotton with Highly Active Catalysts', Text Res J, 1976, 46, 691-700 https://doi.org/10.1177/004051757604600913
  14. K. C. Gupta and P. C. Metha, 'Highly Active Catalysts for Wrinkle-Resistance Finishing of Cellulosic Textiles', Text Res J, 1971, 41, 75-76 https://doi.org/10.1177/004051757104100113