환경위생공학 (Journal of environmental and Sanitary engineering)

대한환경위생공학회 (Korean Society for Environmental Sanitary Engineers)
권호 표지

DNPH cartridge/LC-MS 방법에 의한 반월.시화산업단지의 폼알데하이드 분석에 관한 연구

Analysis of formaldehyde using DNPH cartridge/LC-MS in the Ban-Woll.Shi-Hwa Industrial Complex

  • 조덕희 (경기도보건환경연구원 악취분석팀) ;
  • 송일석 (경기도보건환경연구원 악취분석팀) ;
  • 김인구 (경기도보건환경연구원 악취분석팀) ;
  • 김웅수 (경기도보건환경연구원 악취분석팀) ;
  • 김종보 (경기도보건환경연구원 악취분석팀) ;
  • 김태현 (경기도보건환경연구원 악취분석팀) ;
  • 황선민 (경기도보건환경연구원 악취분석팀) ;
  • 남우경 (경기도보건환경연구원 악취분석팀)
  • Cho Deok-Hee (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment) ;
  • Song Il-Seok (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment) ;
  • Kim In-Gu (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment) ;
  • Kim Woong-Soo (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment) ;
  • Kim Jong-Bo (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment) ;
  • Kim Tae-Hyun (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment) ;
  • Hwang Sun-Min (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment) ;
  • Nam Woo-Kyong (Odor Analysis Team, Gyeonggi-do Institute of Health and Environment)
  • 발행 : 2006.03.01
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초록

Formaldehyde is important because of their irritant and toxic properties, mutagenicity and carcinogenicity. In this study, liquid chromatography-mass spectrometry (LC-MS) is used for the analysis of formaldehyde after derivatization with 2,4-dinitrophenylhydrazine (DNPH) cartridge. Analytical parameters such as linearity, repeatability and minimum detection limit were evaluated. The linearity ($r^2$) was 0.9997 when analyte concentration ranges from 25 to $200{\mu}g/l$. The relative standard deviation (%RSD) was 1.25 % for concentration of $200{\mu}g/l$. The minimum detection limit (MDL) was 0.73 ppbv. It was shown that LC-MS method has a great potential for formaldehyde analysis. The results of formaldehyde from the survey of Ban-Woll and Shi-Hwa Industrial Complex samples, the highest level was 6.20, 3.93 ppb, respectively. The highest emission level of formaldehyde at chemical plants in the Ban-Woll' Shi-Hwa Industrial Complex was 5421.25 ppb.

키워드

참고문헌

  1. Zhang J., Q. He, and P.J. Lioy, Characteristics of aldehydes : Concentrations, sources, and exposures for indoor and outdoor residential microenvironments, Environmental Science Technology, 28(1), 146-152, 1994 https://doi.org/10.1021/es00050a020
  2. WHO, Air quality guidelines for Europe, WHO European Series No 23, Copenhagen, Denmark, 1987
  3. Williams E.L. and Grogiean D., Removal of atmospheric oxidants with annular denuders, Environmental Science Technology, 24, 811-814, 1990 https://doi.org/10.1021/es00076a002
  4. Grosjean, E., E.L. Williams II, and D. Grosjean, Ambient levels of formaldehyde and acetaldehyde in Atlanta, Georgia, J. Air Waste Management Association, 43, 469-474, 1993
  5. Chang M.B. and C.C. Lee, Destruction of formaldehyde with dielectric barrier discharge plasmas, Environmental Science Technology, 29(1), 1428-1430, 1995
  6. Carlier P., H. Hannachi, and G. Mouvir, The chemistry of carbonyl compounds in the atmosphere: A review, Atmospheric Environment, 20(11), 2079-2099, 1986 https://doi.org/10.1016/0004-6981(86)90304-5
  7. Vairavamrthy A., J.M. Roberts and L. Newman, Sampling of atmospheric carbonyl compounds for the determination by liquid chromatography after 2,4-dinitrophenylhydrazine labeling, sampling and analysis of airborne pollutants, Edited by E.D. Winegar, and Keith, L.H., Lewis Publishers, 150-151, 1993
  8. 황윤정, 박상곤, 백성옥, DNPH 카트리지와 HPLC를 이용한 대기 중 카르보닐 화합물의 농도측정-분석방법의 평가와 실제에의 적용, 한국대기보전학회지, 12(2), 199-209, 1996
  9. Smith R.G., G.j. Bryan, M. Feldstein, B. Levadie, F.A. Miller, E.R. Stephens, and N.G. White, Methods of Air Sampling and Analysis, Edited by Jr., J.P. Lodge, Lewis Publishers Inc., Michigan, 274-278, 1988
  10. 황윤정, 박상곤, 백성옥, 공기 중 포름알데히드 측정을 위한 크로모트로핀산법과 DNPH/HPLC 방법간의 비교.평가, 한국대기환경학회지, 14(5), 519-524, 1998
  11. Sirju A.P. and P.B. Shepson, Laboratory and field investigation of the DNPH cartridge for the measurement of atmospheric carbonyl compounds, Environmental Science Technology, 29(2), 384-392, 1995 https://doi.org/10.1021/es00002a014
  12. Slemer J., Determination of volatile carbonyl compounds in clean air, Fresenius J. Analytic Chemistry, 340, 672-677, 1991 https://doi.org/10.1007/BF00321533
  13. Suze M. van Leeuwen, Laurens Hendriksen, Uwe Karst, Determination of aldehydes and ketones using derivatization with 2,4-dinitrophenylhydrazine and liquid hromatography-atmospheric pressure photoionization-mass spectrometry, Journal of Chromatography A, 1058, 107-112, 2004 https://doi.org/10.1016/j.chroma.2004.08.149
  14. 조덕희, 송일석, DNPH cartridge/LC-MS 방법에 의한 카르보닐화합물 분석에 관한 연구, 한국대기환경학회지, 22(2), 201-208, 2006
  15. 김기현, 최여진, 홍윤정, 사재환, 박종호, 전의찬, 최정렬, 구윤서, 반월공산 내 주요 산업시설물들의 대기배출시설을 중심으로한 주요 악취성분의 배출특성 및 배출원별 악취인자 선별방식에 대한 예비연구, 한국대기환경학회지, 21(2), 15-226, 2005
  16. 김진용, 이효송, 유재근, 길인섭, 김덕현, 여영우, 시화지구에서 발생되는 VOCs 농도분포 특성 연구, 한국대기환경학회지, 21(6), 613-624, 2005
  17. 여현구, 조기철, 엄철수, 최민규, 선우영, 수도권지역에서 포름알데하이드와 아세트알데하이드의 계절별 발생원 특성, 국대기환경학회지, 18(1), 11-23, 2002
  18. Altshuller, A.P., Estimating product yields of carbon-containing products from the atmospheric photooxidation of ambient air alkenes, J. atmos. Chem., 13, 131-154, 1991 https://doi.org/10.1007/BF00115970