Soluble Manganese Removal Using Manganese Oxide Coated Media (MOCM)

산화망간피복여재를 이용한 용존망간 제거

  • 김진근 (한국수자원공사 수자원교육원) ;
  • 정세채 (한국수자원공사 자원관리팀) ;
  • 고수현 (한국수자원공사 전북지역본부)
  • Received : 2006.06.27
  • Accepted : 2006.09.27
  • Published : 2006.12.15

Abstract

Soluble manganese removal was analyzed as a function of filter media, filter depth, presence or absence of chlorination, and surface manganese oxide concentration in water treatment processes. Sand, manganese oxide coated sand (MOCS), sand+MOCS, and granular activated carbon(GAC) were used as filter media. Manganese removal, surface manganese oxide concentration, turbidity removal, and regeneration of MOCS in various filter media were investigated. Results indicated that soluble manganese removal in MOCS was rapid and efficient, and most of the removal happened at the top of the filter. When filter influent (residual chlorine 1.0mg/L) with an average manganese concentration of 0.204mg/L was fed through a filter column, the sand+MOCS and MOCS columns can remove 98.9% and 99.2% of manganese respectively on an annual basis. On the other hand, manganese removal in sand and the GAC column was minimal during the initial stage of filtration, but after 8 months of filter run they removed 99% and 35% of manganese, respectively. Sand turned into MOCS after a certain period of filtration, while GAC did not. In MOCS, the manganese adsorption rate on the filter media was inversely proportional to the filter depth, while the density of media was proportional to the filter depth.

Keywords

References

  1. 김진근, 정상기, 김좀숙, 박세진 (2005) 상수처리에서 망간제거, 상하수도학회지, 19(5), pp, 595-604
  2. 김진근, 정상기 (2006), 수돗물에서 흑수발생 저감방안, 상하수도, 13, pp. 116-121
  3. 정세채 , 고수현, 김진근, 유정희 (2006), 망간사화된 모래여과지 운영에 대한 연구, 대한환경공학회지, 26(10), pp. 1131-1136
  4. 환경부 홈페이지 http://www.me.go.kr.(2005)
  5. AWWA (1999) Water Quality and Treatment 5th Ed. AWWA, Denver, pp. 12.24-12.25
  6. Bajpai, S. and Chaudhuri, M. (1999) Removal of Arsenic from Ground Water by Manganese Dioxide-Coated Sand, J. Environmental Engineering, 125(8), pp. 782-784 https://doi.org/10.1061/(ASCE)0733-9372(1999)125:8(782)
  7. Gouzinis, A., Kosmidis, N., Vayenas, D.V., and Lyberatos, G. (1998) Removal of Mn and Simultaneous Removal of $NH_3$, Fe and Mn from Potable Water Using A Trickling Filter, Wat. Res. 32(8), pp. 2442-2450 https://doi.org/10.1016/S0043-1354(97)00471-5
  8. Hu, P.Y., Hsieh, Y.H., Chen, J.C, and Chang, C.Y. (2004) Characteristics of manganese-coated sand using SEM and EDAX analysis, J. Colloid and Interface Sci. 272, pp. 308-313 https://doi.org/10.1016/j.jcis.2003.12.058
  9. Jusoh, A., Cheng, W.H., Low, W.M. Nora'aini, A., and Noor, M.J. (2005) Study on the removal of iron and manganese in groundwater by granular activated carbon, Desalination, 182, pp. 347-353 https://doi.org/10.1016/j.desal.2005.03.022
  10. Kawamura, S. (2000) Integrated Design and Operation of Water Treatment Facilities, 2nd Ed. John 'Wiley & Sons, Inc. New York, pp. 523-527
  11. Kim, J.K. Nason, J.A. and Lawler, D.F. (2006) Zeta Potential Distributions in Particle Treatment, J. of Water Supply: Research and Technology-AQUA, 55(7-8), pp. 461-470 https://doi.org/10.2166/aqua.2006.056
  12. Knocke, W.R., Occiano, S.C., and Hungate, R. (1991) Removal of Soluble Manganese by Oxide-coated Filter Media: Sorption Rate and Removal Mechanism Issues, J. AWWA, 83(8), pp. 64-69
  13. Knocke, W.R., Hamon, J.R., and Thompson, C.P. (1988) Soluble Manganese Removal on Oxide-Coated Filter Media, J. AWWA, 80(12), pp. 65-70
  14. Morgan, J.J. and Stumm W. 1964. Colloid-Chemical Properties of Manganese Dioxide, J. Colloid Sci. 19, pp. 347-359 https://doi.org/10.1016/0095-8522(64)90036-4
  15. Sommerfeld, E.O. (1999) Iron and Manganese Removal Handbook, AWWA, pp. 13-92
  16. Weng, C., Hoven, D.L., and Schwartz, B.J. (1986) Ozonation: An Economic Choice for Water Treatment, J. AWWA, 78(11), pp. 83-89
  17. Williams, R.B. and Culp, G.L. (1986) Handbook of Public Water System, Van Nostrand Reinhold Company, New York, pp. 633-644
  18. Zaw, M., and Chiswell, B. (1999) Iron and Manganese Dynamics in Lake Water, Wat. Res. 33(8), pp. 1900-1910 https://doi.org/10.1016/S0043-1354(98)00360-1
  19. 日本水道協會 (2000) 水道施設設計指針. pp. 332-334
  20. 水道技術硏究セソタ- (2000) 淨水技術ガイドライン pp. 87-89