국화과 허브류인 수입산 캐모마일차와 국내산 국화차의 향기성분 비교

Analysis of aroma components from flower tea of German chamomile and Chrysanthemum boreale Makino

  • 임성임 (동의대학교 생활과학연구소) ;
  • 배정은 (동의대학교 생활과학연구소) ;
  • 최성희 (동의대학교 식품영양학과)
  • Im, Sung-Im (Research Institute of Life Sciences, Dongeui University) ;
  • Bae, Jung-Eun (Research Institute of Life Sciences, Dongeui University) ;
  • Choi, Sung-Hee (Department of Food and Nutrition, Dongeui University)
  • 발행 : 2006.12.31

초록

유럽의 허브요법을 대표하는 캐모마일차와 국내산 국화차에 속하는 감국차의 휘발성성분을 동시증류추출법에 의해 추출하여 GC 및 GC-MS로 분석${\cdot}$동정하고 비교하였다. 캐모마일차의 휘발성성분으로는 cubebene(14.59%), ${\beta}$-elemene(4.88%), ${\delta}$-cadinol(1.54%)을 포함한 총 46종류의 화합물이 동정되었다. 반면, 국내산 국화차에서는 santalol(6.25%), bornyl acetate(3.47%), farnesene(3.37%), 1,8-nonadiene(2.80%), caryophyllene oxide(2.77%) 및 thymol(2.16%) 등 총 45종류의 화합물이 동정 또는 추정되었다. 동정 또는 추정된 화합물 중 22종은 두 시료에 공통적으로 포함되어 있었다. 캐모마일차와 국화차에 공통으로 함유된 화합물 중 비교적 함량적으로 많이 들어있는 화합물은 4-terpineol, ${\alpha}$-terpineol, thymol, phenylacetaldehyde들이 었다.

The aroma components of german chamomile tea in Europe and kukwha (Chrysanthemum boreale Makino) tea in Korea belonging to genus chrysanthemum were analyzed and compared. The volatile components of chamomile tea and kukwha tea were collected by a simultaneous steam distillation-solvent extraction method (SDE). The extracted components were analyzed gas chromatography (GC) and gas chromatography-mass spectrometry (GC-MS). Forty-six compounds, including cubebene(14.59%), ${\beta}$-elememe(4.88%) and ${\delta}$-cadinol(1.54%) were identified in chamomile tea. Forty-five compounds including santalol(6.25%), bomyl acetate(3.47%), farnesene(3.37%), 1,8-nonadiene (2.80%), caryophyllene oxide(2.77%) and thymol (2.16%) were identified in kukwha tea. Twenty-two compounds including 4-terpineol, ${\alpha}$-terpineol, thymol, phenylacetaldehyde, V-terpinene were found in both samples.

키워드

참고문헌

  1. 이유미. 2003. 한국의 야생화. 다른세상. 서울. pp.470-475
  2. Akahoshi G. 1983. Kouryonokagaku(in Japanese). Dainihontosyo. Tokyo, Japan. p. 315
  3. Choi KS, Choi BY, Park HK, Kim JH, Park JS, Yoon CN. 1988. Flavor components of Artemisia Lavandulaefolia DC. Kor. J. Food Sci. Technol. 20: 774-779
  4. Choi SH. 1991. Studies on flavor components of commercial korean green tea. Kor. J. Food Sci. Technol. 23: 98- 101
  5. Choi SH. 2001. Volatile aroma components of Korean semi- fermented teas. Kor. J. Food Sci. Technol. 33: 529-533
  6. Choi SH, Bae JE. 1996. The aroma components of green tea, the products of Mt. Chiri garden. J. Korean Soc. Food Nutr. 25: 478-483
  7. Choi SH, Kim HJ. 2000. Volatile flavor components of Angelica giga Nakai by the storage conditions. Kor. J. Food Sci. Technol. 32: 513-518
  8. Choi SH, Kim HJ. 2000. The flavor components of korean cnidium officinale Makino. J. Korean Soc. Food Sci. Nutr. 29:582- 585
  9. Choi SH, Im SI, Jang EY, Cho YS. 2004. Volatile components of flavor and seed of safflower. Kor. J. Food Sci. Technol. 36: 196-201
  10. Dewick PM. 2002. Medicinal Natural Products. Wiley. England. p.184
  11. Fujimaki M. 1982. Kouryounoziten (in Japanese). Asakurashoten, Tokyo, Japan. p. 368
  12. Hanafusa M. 1993. Fragrance materials of the cosmetica : Chrysanthemum. Kouryou(in Japanese) 177, pp. 107-110
  13. Isao K, Hisae M, Masaki H. 1992. Antimmicrobial activity of green tea flavor components and their combination effects. J Agric Food Chem 40: 245-250 https://doi.org/10.1021/jf00014a015
  14. Jang DS, Park KH, Yang MS. 1998. Germacranolides from flowers of chrysanthemum boreale Makino. Kor. J. pharmacogn 29: 67-70
  15. Kawakami M. 2000. Aroma Study of Tea. Koseikan. Tokyo, Japan. p. 214
  16. Kim JO, Kim YS, Lee JH, Kim MN, Rhee SH, Moon SH, Park KY. 1992. Antimutagentic effect of the major volatile compounds identified from Mugwort(Artemisia asictica nakai) leaves. J Korean Soc Food Nutrition 21: 231-239
  17. Kim YS, Lee JH, Kim MN, Lee WG, Kim JO. 1994. Volatile flavor compounds from raw mugwort leaves and parched mugwort tea. J. Korean Soc. Food Nutr. 23:261-267
  18. Ody P. 2000. Medicinal Herbal. Dorling Kindorsley, Australia
  19. Omori M. 1997. Characterization of tea flavor. Kouryou(in Japanese) 193. pp. 59-73
  20. Shin SH, Choi YI. 1982. Analysis of essential oil from chrysanthemum sibiricum and comparison with essential oils from seoul chrysanthemum spp. Kor. J. Pharmacog. 13:153-156
  21. Wassenhove FV, Dirinck DJ, Schamp NM, Vulsteke G A. 1990. Effect of nitrogen fertilizers on celery volatiles. J Agric Food Chem 38: 582-585
  22. Yamanishi T, Kosuge M, Tokitomo Y, Maeda R. 1980. Flavor constituent of pouchong tea and comparison of the aroma pattern with jasmine tea. Agric Biol Chem 44: 2139-2142 https://doi.org/10.1271/bbb1961.44.2139
  23. Yamanishi T. 1989. Tea. Kouryou(in Japanese) 161. pp. 57-72
  24. Yang MS, Park KH, Jang DS, Choi SU, Nam SH, Shiro M. 1996. Cumambrin A in Chrysanthemum boreale Makino preparation, X-ray Crystal Structure and $^{13}C-$ and $^1H-NMR$ Study of Cumambrin A. Kor. J. Pharmacogn. 27: 207-211