Macromolecular Research

  • 제14권2호
  • /
  • Pages.220-229
  • /
  • 2006
  • /
  • 1598-5032(pISSN)
  • /
  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Equations of State for Hard-Sphere Chains: Effect of Attractive Contribution

  • Kim Jae-Jun (The College of Architecture, Department of Architectural Engineering, Hanyang University)
  • 발행 : 2006.04.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Several equations of state for hard-sphere chains with various perturbation terms are reviewed. For each model, three characteristic parameters are required to represent phase equilibria of normal fluids and obtained from thermodynamic properties of pure saturated liquids. The models are then compared with computer simulation data to show the effect of attractive contribution forms employed. Calculated values of vapor-liquid equilibria (VLE) of hydrocarbons that can be reproduced for each model are also compared with experimental results. An additional parameter, ${\zeta}_{KB}$, is required to represent the VLE of pure water, which is ascertained to have a strong influence on the theoretical coexistence curve.

키워드

참고문헌

  1. W. Wang, K. K. Mohammad, and J. H. Vera, Fluid Phase Equilibria, 115, 25 (1996) https://doi.org/10.1016/0378-3812(95)02837-4
  2. K. K. Mohammad and J. H. Vera, Fluid Phase Equilibria, 130, 189 (1997) https://doi.org/10.1016/S0378-3812(96)03189-5
  3. K. K. Mohammad and J. H. Vera, Fluid Phase Equilibria, 142, 131 (1998) https://doi.org/10.1016/S0378-3812(97)00230-6
  4. J. M. Prausnitz, R. N. Lichtenthaler, and E. G. D. Azevedo, Molecular Thermodynamics of Fluid Phase Equilibria, 3rd Edition, Prentice-Hall, Englewood Cliffs, NJ, 1999
  5. J. A. Barker and D. Henderson, J. Chem. Phys., 47, 4714 (1967) https://doi.org/10.1063/1.1701689
  6. C. P. Bokis, M. D. Donohue, and C. K. Hall, Ind. Eng. Chem. Res., 33 1290 (1994) https://doi.org/10.1021/ie00029a027
  7. A. Yethiraj and C. K. Hall, J. Chem. Phys., 95, 1999 (1991) https://doi.org/10.1063/1.460998
  8. R. L. Cotterman, B. J. Schwarz, and J. M. Prausnitz, AIChE J., 32, 1787 (1986) https://doi.org/10.1002/aic.690321104
  9. W. O. Morris, P. Vimalchand, and M. D. Donohue, Fluid Phase Equilibria, 32, 103 (1987) https://doi.org/10.1016/0378-3812(87)85031-8
  10. B. J. Alder, D. A. Young, and M. A. Mark, J. Chem. Phys., 56, 3013 (1972)
  11. S. S. Chen and A. Kreglewski, Ber. Bunsenges., 81, 1048 (1977) https://doi.org/10.1002/bbpc.19770811037
  12. D. A. Mc Quarrie, Statistical Mechanics, Harper Collins Publishers, NY, 1976
  13. M. Christoforakis and E. U. Franck, Ber. Bunsenges. Phys. Chem., 90, 780 (1986)
  14. Y. Song, S. M. Lambert, and J. M. Prausnitz, Macromolecules, 27, 441 (1994) https://doi.org/10.1021/ma00080a018
  15. Y. Song, S. M. Lambert, and J. M. Prausnitz, Ind. Eng. Chem. Res., 33, 1047 (1994) https://doi.org/10.1021/ie00028a037
  16. Y. Song, S. M. Lambert, and J. M. Prausnitz, Chem. Eng. Sci., 49, 2765 (1994) https://doi.org/10.1016/0009-2509(94)E0096-9
  17. R. O'Lenick and Y. C Chiew, Mol. Phys., 85, 257 (1995) https://doi.org/10.1080/00268979500101091
  18. W. G. Chapman, K. E. Gubbins, G. Jackson, and M. Radosz, Ind. Eng. Chem. Res., 29, 1709 (1990) https://doi.org/10.1021/ie00104a021
  19. M. Banaszak, Y. C. Chiew, and M. Radosz, Physical Review E, 48, 3760 (1993) https://doi.org/10.1103/PhysRevE.48.3760
  20. F. W. Travares, J. Chang, and S. I. Sandler, Fluid Phase Equilibria, 140, 129 (1997) https://doi.org/10.1016/S0378-3812(97)00097-6
  21. D. Ghonasgi and W. G. Chapman, AIChE J., 40, 878 (1994) https://doi.org/10.1002/aic.690400514
  22. M. Banaszak, Y C. Chiew, R. O'Lenick, and M. Radosz, J. Chem. Phys., 100, 3803 (1994) https://doi.org/10.1063/1.466368
  23. J. K. Johnson, E. A. Müller, and K. E. Gubbins, J. Chem. Phys., 98, 6413 (1994) https://doi.org/10.1021/j100076a028
  24. T. Kraska and K. E. Gubbins, Ind. Eng. Chem. Res., 35, 4727 (1996) https://doi.org/10.1021/ie9602320
  25. T. Kraska and K. E. Gubbins, Ind. Eng. Chem. Res., 35, 4738 (1996) https://doi.org/10.1021/ie960233s
  26. F. J. Blas and L. F. Vega, Ind. Eng. Chem. Res., 37, 660 (1998) https://doi.org/10.1021/ie970449+
  27. N. F. Carnahan and K. E. Starling, J. Chem. Phys., 51, 635 (1969) https://doi.org/10.1063/1.1672048
  28. I. H. Kim and Y. C. Bae, Fluid Phase Equilibria, 167, 187 (2000) https://doi.org/10.1016/S0378-3812(99)00325-8
  29. J. D. van der Waals, Doctoral Dissertion, Leiden, 1873
  30. G. Sadowski, Fluid Phase Equilibria, 149, 75 (1998) https://doi.org/10.1016/S0378-3812(98)00370-7
  31. Y. C. Chiew, Mol. Phys., 73, 359 (1991) https://doi.org/10.1080/00268979100101251
  32. J. A. Barker and D. Henderson, Mol. Phys., 21, 187 (1971) https://doi.org/10.1080/00268977100101331
  33. J. Gao and J. H. Weiner, J. Chem. Phys., 91, 3168 (1989) https://doi.org/10.1063/1.456937
  34. R. Dickman and C. K. Hall, J. Chem. Phys., 89, 3168 (1988) https://doi.org/10.1063/1.454973
  35. B. D. Smith and R. Srivastava, Thermodynamic Data for Pure Compounds, Elsevier Science Publishers, B. V., 1986
  36. L. Zeman, J. Biros, G. Delmas, and D. Patterson, J. Phys. Chem., 76, 1206 (1972) https://doi.org/10.1021/j100652a021