DOI QR코드

DOI QR Code

Physical Properties of High-Solid Coatings with 80% Solid Contents Acrylic Resins Containing Caprolactone Group and HMDI-Trimer

카프로락톤기 함유 80% 고형분인 아크릴수지와 HMDI-Trimer에 의한 하이솔리드 도료의 도막물성

  • 박홍수 (명지대학교 공과대학 화학공학과) ;
  • 정충호 (요업기술원) ;
  • 조혜진 (명지대학교 공과대학 화학공학과) ;
  • 심일우 (명지대학교 공과대학 화학공학과) ;
  • 김승진 (한국건자재시험연구원) ;
  • 김성길 ((주)알엔씨 기술연구소)
  • Published : 2006.06.30

Abstract

The high-solid coatings were prepared by blending the synthesized acrylic resin in the previous paper, and hexamethylene diisocyanate-trimer and curing it at room temperature. The characterization of the films of the prepared coatings was performed. The $60^{\circ}$ specular gloss, impact resistance, cross-hatch adhesion, and heat resistance of the films proved to be good, and the pencil hardness, drying time, and pot-life proved to be slightly poor. From a viscoelastic measurement using a rigid-body pendulum, curing was accelerated with the Tg value.

Keywords

References

  1. K. Bay, H. Wanko, and J. Ulrich, Absorption of Volatile Organic Compounds in Biodiesel : Determination of Infinite Dilution Activity Coefficients by Headspace Gas Chromatography, Chem. Eng. Research Design, 84(A1), 22-28 (2006) https://doi.org/10.1205/cherd.05050
  2. M. Hirasawa, T. Seto, and S. B. Kwon, Decomposition of Volatile Oraganic Compounds Using Surface-Discharge Microplasma Devices, Jpn. J. Applied Physics, Part 1. Regular Paper, Brief Communications & Review Papers, 45(3A), 1801-1804 (2006)
  3. H. P. Rink and B. Lettmann, Water-Based 3-Pack Paint Systems for High-End Coatings, Euro. Coatings J., 6, 32-33 (2002)
  4. W. Goeblmeier, Loco Environmental Impact and Heat Resistant : Silicone -Based Powder Coatings Capture New Applications, Coatings, 39(1), 25-2:7 (2006)
  5. K. Willard, UV/EB Curings for Automotive Coatings, RadTech Report, 14(6), 22-27 (2000)
  6. R. Narayan, D. K. Chattopadhyay, K. V. S. N. Raju, N. N. Mallikarjuna, S. S. Jawalkar, and T. M. Aminabhavi, Viscosity Behavior of Hydroxylated and Acetoacetylated Polyesters, J. Appl. Polym. Sci., 100(3), 2422-2435 (2006) https://doi.org/10.1002/app.23341
  7. H. J. Jo., I. W. Shim, H. S. Park, C. H. Jung, and Y. G. Kim, Synthesis of Acrylic Resins Containing Caprolactone Group and 80% Solid Contents for High-Solid Coatings, J. Kor. Oil Chem. Soc., 23(1), 85-91 (2006)
  8. P. A. Janmey, A Torsion Pendulum for Measurements of the Viscoelasticity of Biopolyrners and Its Application to Action Networks, J. Biochemical and Biophysical Methods, 22(1), 41-53 (1991) https://doi.org/10.1016/0165-022X(91)90080-G
  9. B. Cao, P. Luo, H. Li, and Y. Zhang, Viscoelasticity and Rheological Behaviors of Hydrophobic Association Polymer Solution, Shiyou Xuebao, 27(1), 85-88 (2006)