DOI QR코드

DOI QR Code

말론산 에스테르 합성 및 이를 이용한 알루미늄 가공용 절삭유의 제조

Preparation of Aluminum Metalworking Lubricant with Synthesized Malonic Diester

  • 이수 (창원대학교 공과대학 화공시스템공학과) ;
  • 박근호 (창원대학교 공과대학 화공시스템공학과) ;
  • 송주영 (창원대학교 공과대학 화공시스템공학과)
  • Lee, Soo (Dept. of Chemical Engineering, Changwon National University) ;
  • Park, Keun-Ho (Dept. of Chemical Engineering, Changwon National University) ;
  • Song, Ju-Yeong (Dept. of Chemical Engineering, Changwon National University)
  • 발행 : 2006.09.30

초록

To provide an aqueous rust inhibitor for metalworking lubricant having low toxicity and excellent rust resistance, we synthesized diester of malonic acid by three consecutive esterifications with over 98% of conversion. This substituted malonic diester could be used as an additive to mineral oil based metalworking lubricant. These metalworking lubricant compositions were showed excellent rust resistance and suitable for various metals and different metalworking processes including hot rolling and cold rolling of aluminum and aluminum alloys.

키워드

참고문헌

  1. A. W. Ackerman, The Properties and Classification of Metalworking fluids, Lubrication Eng., 25(7), 285 (1969)
  2. D. P. Hunsicker and J. S. McCoy, 'Compatibility: Metalworking Fluid, Machine Tool, and Lubricant', Lubrication Eng.,.-Illinois-, 52(5), 366 (1996)
  3. T. Mathiesen, Modified TMP Esters as Multifunctional Additives in Metalworking Fluids, J. Syn. Lubrication, 14(4), 381 (1998) https://doi.org/10.1002/jsl.3000140405
  4. C. Kajdas, Additives for Metalworking Lubricants-a Review, Lubrication Science, 1(4), 385 (1989) https://doi.org/10.1002/ls.3010010406
  5. W. Popendorf, E. R. Miller, N. L. Sprince, M. S. Selim, P. S. Thome, C. S. Davis, and M. L. Jones, The Utility of Preliminary Surveys to Detect the Cause of Acute Metalworking Fluid Hazards, Amer. J. Ind. Medicine, 30(6), 744 (1996) https://doi.org/10.1002/(SICI)1097-0274(199612)30:6<744::AID-AJIM11>3.0.CO;2-2
  6. R. Burgo and P. Kennedy, 'Alpha Branched Esters for Use in Metalworking Fluids and Metalworking Fluids Containing such Esters', U. S. Patent 7,008,909 (2006)
  7. C. K Cox, 'Metalworking Fluid', U. S. Patent 4,882,077 (1989)
  8. K. Fukutani, M. Tanaka, Y. Ueno, S. Fukushima, K. Wada, and S. Suzuki, 'Metal Working Fluid', U. S. Patent 6,448,207 (2002)
  9. S. Futahashi, Y. Fukutani, Y. Wada and E. Nakayama, 'Metal Working Water and Metal Working Composition', U. S. Patent 6,258,759 (2001)
  10. Y. Fukutani, K. Fukutani, Y. Wada, Y. Ueno, S. Fukushima and E. Nakayama, 'Rust Preventive', U. S. Patent 6,488,749 (2002)
  11. L. Meszaros, H. Schrimpf, and K. Pfitzner, 'Glycol Based Antifreeze Concentrates Inhibited with Monocarboxylic Acid Salts Together with Hydrocarbontriazoles and/or -Thiazoles', U. S. Patent 6,080,331 (2000)
  12. S. A. Rizvi and C. V. Luciani, 'Polyethoxylated Alcohol-Based Phosphonates for Metal Working Lubricants', U. S. Patent 5,985,803 (1999)
  13. N. Tanaka, A. Fukushima, K. Morita and A. Miyashita, 'Lubricating Composition', U. S. Patent 6,268,316 (2001)
  14. K. E. Davis, 'Homogeneous Compositions Prepared from Dimercaptothiadiazoles', U. S. Patent 4,136,043 (1979)
  15. J. T. Laemmle and J. Bohaychick, 'Metalworking Lubricant Composition Containing a Novel Substituted Malonic Acid Diester' U. S. Patent 4,517,105 (1985)