한국염색가공학회지 (Textile Coloration and Finishing)

  • 제18권4호
  • /
  • Pages.28-36
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  • 2006
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  • 1229-0033(pISSN)
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  • 2234-036X(eISSN)
한국염색가공학회 (The Korean Society of Dyers and Finishers)
권호 표지

인조스웨드의 견뢰도 향상에 관한 연구(2)

Enhancement of Dyeing Fastness of Artificial Studies

  • Kim, Hea-In (Department of Textile Engineering, Pusan National University) ;
  • Park, Soo-Min (Department of Textile Engineering, Pusan National University)
  • 발행 : 2006.08.27
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초록

The polyurethane prepolymers, which were previously synthesized from 2,4-toluene disocyanate(2,4-TDI) and polypropylene glycol(PPG), were chain extended by ethylene diamine or hydroxyl terminated polydimethylsiloxane(HTPMS) having hydroxy group at both ends of the chain, giving polyurethaneurea(PU) and polyurethane containing HTPMS segment(SiPU), respectively. In thermal gravimetric analysis, PU was almost completely degraded at $500^{circ}$ but SiPU showed about 11% residue at the same temperature. Suspension of SiPU and pigment showed more good compatibility than that of PU and pigment. The crocking fastness, migration fastness and solvent wicking were enhanced to 4.5 grades, 4 grades and 4 grades, respectively.

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참고문헌

  1. F. Tsunekatsu, M. Hideki, S. Mutsuo, Jp. Pat. 051877(1993)
  2. N. Hitoshi, Y. Hisao, Jp. Pat. 241980(1997)
  3. Y. Yoshiaki, T. Yoshishiro, Jp. Pat. 315986(2004)
  4. M. Meiji, S. Sei, Jp. Pat. 268680(2003)
  5. N. HIitoshi, Y. Hisao, Jp. Pat. 241980(1997)
  6. Y. Yoshiaki, T. Yoshihiro, Jp. Pat. 2004-315986(2004)
  7. S. Ioan, G. Grigorescu, and A. Stanciu, Dynamic-mechanical and differential scanning calorimetry measurements on crosslinked poly(ester-siloxane)-urethanes, Polymer, 42, 3633-3639(2001) https://doi.org/10.1016/S0032-3861(00)00747-3
  8. S. Ioan, G. Grigorescu, and A. Stanciu, poly(ester-siloxan)urethanes compositional parameters on differential scanning calorimetry and dynamic-mechanical measurements, European Polymer Journal, 38, 2295-2303(2002)
  9. J. P. Sheth, A. Aneja, G. L. Wilkes, E. Yilgor, G. E. Atilla, I. Yilgor, and F. L. Beyer, Influence of system variables on the morphological and dynamic mechanical behavior of polydimethylsiloxane based segmented polyurethane and polyurea copolymers: a comparative perspective, Polymer, 45, 6919-6932(2004) https://doi.org/10.1016/j.polymer.2004.06.057
  10. S. J. Hinder, C. Lowe, J. T. Maxted, and John F. Watts, Migration and segregation phenomena of a silicone additive in a multilayer organic coating, Progress in Organic Coatings, 54, 104-112(2005) https://doi.org/10.1016/j.porgcoat.2005.04.007
  11. I. Yilgor, and J. E. McGrath, 1,3-bis(${\gamma}$-aminopropyl)tetramethyldisiloxane modified epoxy resins: curing and characterization, Advanced Polymer Science, 86, 1-17(1988) https://doi.org/10.1007/BFb0025274
  12. F. Garbassi, M. Morra, and E. Occhiello, 'Polymer Surface', John Wiley & Sons, New York, pp.84-97, 1994
  13. P. F. Bruins, 'Silicone Technology', Wiley & New York, pp.105-123, 1970
  14. N. Asahi, K. Sakai, N. Kumagai, T. Nakanishi, K. Hata, S. Katoh, and T. Moriyoshi, Methaolysis investgation of commercially available polyurethane foam, Polymer Degradation and Stability, 86, 147-151(2004) https://doi.org/10.1016/j.polymdegradstab.2004.04.002
  15. M. F. Lin, W. C. Tsen, Y. C. Shu, and F. S. Chuang, Effect of silicone and phosphorus on the degradation of polyurethanes, Journal of Applied Polymer Science, 79, 881-889(2001) https://doi.org/10.1002/1097-4628(20010131)79:5<881::AID-APP130>3.0.CO;2-I
  16. O. Mengual, G. Meunier, I. Cayre, K. Puech, and P. Snabre, TURBISCAN MA 2000: Multiple light scattering measurement for concentrated emulsion and suspension instability analysis, Talanta, 50, 443-456(1999)
  17. I. K. Kang, Y. Ito, M. Sisido, and Y. Imanishi, Adsorption of plasma proteins and platelet adhesion on to polydimethylsiloxane/poly($\gamma$-benzyl L-glutamate) block copolymer films, Biomaterials, 9, 138-144(1988) https://doi.org/10.1016/0142-9612(88)90112-3
  18. S. D. Park, I. K. Kang, Y. M. Lee, and Y. K. Sung, Synthesis and Physical Properties of Biocompatible and Biodegradable Polyetherurethaneurea :I. Synthesis and Physical Properties of Polyetherurethaneurea Containing Polydimethylsiloxane Segament, Polymer(Korea), 17, 580-587(1993)
  19. Y. W. Chang, S. S. Im, Y. S. Choi, and D. K. Kim, J. Korean Ind. Eng. Chem., Swelling Behavior of Polyurethane Hydrogels Based on Poly(ethylene oxide) glycol(PEG) or Poly(ethylene oxide-co-propylene oxide) glycol(PEPG), 11, 19-23(2000)
  20. S. Y. Lee and K. G. Hong, Effect of Silicone/Polyurethane Treatment on Physical Properties of Suede-like PET/cotton Fabrics, J. Korean Fiber Soc., 36, 624-631(1999)