Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
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Synthesis and Characterization of Poly(fluorenylenevinylene-terphenylenevinylene) Containing Phenyl Pendant Group

  • Kim Yun-Hi (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University) ;
  • Jung Sung-Ouk (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University) ;
  • Lee Kwang-Hoi (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University) ;
  • Kwon Soon-Ki (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University)
  • Published : 2006.02.01
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Abstract

Poly(fluorenylenevinylene-terphenylenevinylene) containing phenyl pendant group was synthesized by Suzuki coupling reaction and characterized by ${1}^H$-NMR, ${13}^C$-NMR, and IR-spectrum. The weight average molecular weight ($M_{w}$) of the obtained polymer was 31,000 with a polydispersity index of 1.9. The polymer showed good solubility in common organic solvents, and the solution and film emitted blue emission ($\lambda_{max}$=460 nm) on irradiation with UV light. The ITO/PEDOT/polymer/Al device fabricated using the polymer as an emitting layer emitted blue light with a maximum peak around 460 nm. The maximum efficiency of the device was 0.011$\%$.

Keywords

References

  1. Y. Yang and A. J. Heeger, Nature, 372, 344 (1994) https://doi.org/10.1038/372344a0
  2. M. Strukelj, M. Papadimitrakopoulos, F. Miller, T. M. Miller, and L. J. Rotherberg, Science, 270, 1969 (1995)
  3. M. Andersson, G. Yu, and A. J. Heeger, Synth. Met., 85, 1275 (1997) https://doi.org/10.1016/S0379-6779(97)80238-X
  4. C. S. Choi, I. T. Kim, and S. W. Lee, Macromol. Res., 12, 322 (2004) https://doi.org/10.1007/BF03218407
  5. D. Y. Kim, H. N. Cho, and C. Y. Kim, Prog. Polym. Sci., 25, 1089 (2000)
  6. L. Dai, B. Winkler, L. Dong, L. Tong, and A. W. H. Mau, Adv. Mater., 13, 915 (2001) https://doi.org/10.1002/1521-4095(200107)13:12/13<915::AID-ADMA915>3.0.CO;2-N
  7. Q. Pei and Y. Yang, J. Am. Chem. Soc., 118, 7416 (1996) https://doi.org/10.1021/ja9615233
  8. Y. Yang and Q. Pei, J. Appl. Phys., 81, 3294 (1997) https://doi.org/10.1063/1.364313
  9. C. Klaerner and R. D. Miller, Macromolecules, 31, 2007 (1998) https://doi.org/10.1021/ma971073e
  10. M. Zheng, L. Ding, Z. Lin, and F. E. Karasz, Macromolecules, 35, 9939 (2002) https://doi.org/10.1021/ma020533n
  11. S. Janietz, D. D. C. Bradley, M. Grell, C. Giebeler, M. Inbasekaran, and E. P. Woo, Appl. Phys. Lett., 74, 3084 (1999) https://doi.org/10.1063/1.124069
  12. J. Roncali, J. Chem. Rev., 92, 71 (1992)
  13. G. Grem, G. Leditzky, B. Ullrich, and G. Leising, Adv. Mater., 4, 36 (1992) https://doi.org/10.1002/adma.19920040107
  14. B. K. An, Y. H. Kim, D. C. Shin, S. Y. Park, H. S. Yu, and S. K. Kwon, Macromolecules, 34, 3993 (2001) https://doi.org/10.1021/ma0016735
  15. Y. H. Kim, D. C. Shin, S. K. Kwon, and J. H. Lee, J. Mater. Chem., 12, 1280 (2002) https://doi.org/10.1039/b200496h
  16. Y. H. Kim, J. H. Ahn, D. C. Shin, H. S. Kim, and S. K. Kwon, Optical Materials, 21, 175 (2002)
  17. Y. H. Kim, J. H. Ahn, D. C. Shin, J. H. Kim,Y. W. Park, D. S. Choi, Y. K. Kim, and S. K. Kwon, Bull. Korean Chem. Soc., 22, 1181 (2001)
  18. Y. H. Kim, J. H. Ahn, D. C. Shin, and S. K. Kwon, Polymer, 45, 2525 (2004) https://doi.org/10.1016/j.polymer.2004.02.032
  19. Y. H. Kim, D. C. Shin, H. S. Kim, and S. K. Kwon, Polymer, (2005)
  20. Y. H. Kim, J. C. Park, H. J. Kang, J. W. Park, H. S. Kim, J. H. Kim, and S. K. Kwon, Marcomol. Res., 13, 403 (2005)
  21. Y. H. Kim, S. K. Kwon, D. S. Yoo, M. F. Rubner, and M. S. Wrighton, Chem. Mater., 9, 2699 (1997) https://doi.org/10.1021/cm970586x
  22. H. N. Cho, D. Y. Kim, Y. C. Kim, J. Y. Kim, J. Y. Lee, and C. Y. Kim, Adv. Mater., 9, 326 (1997) https://doi.org/10.1002/adma.19970090408
  23. S. Ng, H. Lu, H. S. O. Chan, A. Fujii, T. Laga, and K. Yoshino, Adv. Mater., 12, 1122 (2000) https://doi.org/10.1002/1521-4095(200008)12:15<1122::AID-ADMA1122>3.0.CO;2-F
  24. X. Tao, Y. Zhang, T. Wada, H. Sasabe, H. Suzuki, T. Watanabe, and S. Miyata, Adv. Mater., 10, 226 (1998) https://doi.org/10.1002/(SICI)1521-4095(199802)10:3<226::AID-ADMA226>3.0.CO;2-E
  25. V. Cimrova, D. Neher, M. Remmers, and I. Kimnek, Adv. Mater., 10, 676 (1998) https://doi.org/10.1002/(SICI)1521-4095(199806)10:9<676::AID-ADMA676>3.0.CO;2-Y