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Time Evolution of a High-temperature GaN Epilayer Grown on a Low-temperature GaN Buffer Layer using a Low-pressure MOCVD

  • Chang, Kyung-Hwa (Department of Chemical Engineering, University fo Seoul) ;
  • Cho, Sung-Il (Department of Chemical Engineering, University fo Seoul) ;
  • Kwon, Myoung-Seok (Department of Materials Science and Engineering, University of Seoul)
  • Published : 2006.02.01

Abstract

In this paper, the time evolution of undoped GaN epilayers on a low-temperature GaN buffer layer grown on c-plane sapphire at a low pressure of 300 Torr was studied via a two-step growth condition in a horizontal MOCVD reactor. As a function of the growth time at a high-temperature, the surface morphology, structural quality, and optical and electrical properties were investigated using atomic force microscopy, high-resolution x-ray diffraction, photoluminescence, and Hall effect measurement, respectively. The root-mean-square roughness showed a drastic decrease after a certain period of surface roughening probably due to the initial island growth. The surface morphology also showed the island coalescence and the subsequent suppression of three-dimensional island nucleation. The structural quality of the GaN epilayer was improved with increasing growth time considering the symmetrical (002) and asymmetrical (102) rocking curves. The variations of room-temperature photoluminescence, background carrier concentration, and Hall mobility were measured and discussed.

Keywords

References

  1. M. O. Manasreh and I. T. Ferguson, 'ill-Nitride Semiconductor Materials: Growth', Taylor & Francis, p. 159, 2003
  2. H. S. Nalwa and L. S. Rohwer, 'Handbook of Luminescence, Display Materials, and Devices, Vol. 2, American Scientific Publishers, p. 46, 2003
  3. J. I. Pankove and T. D. Moustakas, 'Gallium Nitride (GaN) I ', Academic Press, p. 20, 1998
  4. B. Gil, 'Group ill Nitride Semiconductor Compounds', Oxford University Press Inc., p. 87, 1998
  5. J. H. Edgar, S. Strite, I. Akasaki, H. Amano, and C. Wetzel, 'Properties, Processing and Applications of Gallium Nitride and Related Semiconductors', INSPEC, p. 416,1999
  6. H. Amano, N. Sawaki, I. Akasaki, and Y. Toyoda, 'Metalorganic vapor phase epitaxial growth of a high quality GaN film using an AIN buffer layer', Appl. Phys. Lett., Vol. 48, No.5, p. 353, 1986 https://doi.org/10.1063/1.96549
  7. S. Nakamura, 'GaN growth using GaN buffer layer', Jpn. J. Appl. Phys., Vol. 30, No. 10A, p. L1705, 1991 https://doi.org/10.1143/JJAP.30.L1705
  8. X. H. Wu, D. Kapolnek, E. J. Tarsa, B. Heying, S. Keller, B. P. Keller, U. K. Mishra, S. P. DenBaars. and J. S. Speck, 'Nucleation layer evolution in metal-organic chemical vapor deposition grown GaN', Appl. Phys. Lett., Vol. 68, No. 10, p. 1371, 1996 https://doi.org/10.1063/1.116083
  9. J. Chen, S. M. Zhang, B. S. Zhang, J. J. Zhu, X. M. Shen, G. Feng, J. P. Liu, Y. T. Wang, H. Yang, and W. C. Zheng, 'Influences of reacor pressure of GaN buffer layrs on morphological evolution of GaN grown by MOCVD', J. Cryst. Growth, Vol. 256, p. 248,2003 https://doi.org/10.1016/S0022-0248(03)01367-8
  10. J. Han, T.-B. Ng, R. M. Biefeld, M. H. Crawford, and D. M. Follstaedt, 'The effect of $H_{2}$ on morphological evolution during GaN metal organic chemical vapor deposition', Appl. Phys. Lett., Vol. 71, No. 21, p. 3114, 1997
  11. A. P. Grzegorczyk, L. Macht, P. R. Hageman, J. L. Weyher, and P. K. Larsen, 'Influences of the nucleation layer morphology and epilayer structure on the resistivity of GaN films grown on c-plane sapphire by MOCVD', J. Cryst. Growth, Vol. 273, p. 424, 2005 https://doi.org/10.1016/j.jcrysgro.2004.09.100
  12. E. M. Goldys, M. Godlewski, R. Langer, and A. Barski, 'Surface morphology of cubic and wurtzite GaN films', Appl. Surf. Sci., Vol. 153, p. 143,2000 https://doi.org/10.1016/S0169-4332(99)00342-6
  13. J. Zhou, J. E. Reddic, M. Sinha, W. S. Ricker, J. Karlinsey, J.-W. Yang, M. A. Khan, and D.A. Chen, 'Surface morphologies of MOCVD-grown GaN films on sapphire studied by scanning tunneling microscopy', Appl. Surf. Sci., Vol. 202, p. 131,2002 https://doi.org/10.1016/S0169-4332(02)00889-9
  14. D. Kapolnek, X. H. Wu, B. Heying, S. Keller, B. P. Keller, U. K. Mishra, S. P. DenBaars, and J. S. Speck, 'Structural evolution in epitaxial metalorganic chemical vapor deposition grown GaN films on sapphire', Appl. Phys. Lett., Vol. 67, No. 11, p. 1541. 1995 https://doi.org/10.1063/1.114486
  15. S. Figge, T. Bottcher, S. Einfeldt, and D. Hommel, 'In situ and ex situ evaluation of the film coalescence for GaN growth on GaN nucleation layers', J. Cryst. Growth, Vol. 221, p. 262, 2000 https://doi.org/10.1016/S0022-0248(00)00696-5
  16. H. Yuan, D.-C. Lu, X. Liu, Z. Chen, P. Han, X. Wang, and Du Wang, 'Statistical investigation on morphology development of gallium nitride in initial growth stage', J. Cryst. Growth, Vol. 234, p. 77,2002 https://doi.org/10.1016/S0022-0248(01)01655-4
  17. H. Yuan, Z. Chen, D.-C. Lu, X. Liu, P. Han, and X. Wang, 'A geometrical model of GaN morphology in initial growth stage', J. Cryst. Growth, Vol. 234, p. 115, 2002 https://doi.org/10.1016/S0022-0248(01)01668-2
  18. X. H. Wu, P. Fini, E. J. Tarsa, B. Heying, S. Keller, U. K. Mishra, S. P. DenBaars, and J. S. Speck, 'Dislocation generation in GaN heteroepitaxy', J. Cryst. Growth, Vol. 189/190, p. 231, 1998 https://doi.org/10.1016/S0022-0248(98)00240-1
  19. M. S. Kwon and S. I. Cho, 'Effects of total gas velocity during growth of undoped GaN epitaxial layer on sapphire (0001) substrate by horizontal MOCVD', J. Cryst. Growth, Vol. 266, p. 435, 2004 https://doi.org/10.1016/j.jcrysgro.2004.03.003
  20. S. Keller, B. P. Keller, Y.-F. Wu, B. Heying, D. Kapolnek, J. S. Speck, U. K. Mishra, and S. P. DenBaars, 'Influence of sapphire nitridation on properties of gallium nitride grown by metalorganic chemical vapor deposition', Appl. Phys. Lett., Vol. 68, p. 1525, 1996 https://doi.org/10.1063/1.115687
  21. B. Heying, X. H. Wu, S. Keller, Y. Li, D. Kapolnek, B. P. Keller, S. P. DenBaars, and J. S. Speck, 'Role of threading dislocation structure on the x-ray diffraction peak widths in epitaxial GaN films', Appl. Phys. Lett., Vol. 68, No.5, p. 643, 1996 https://doi.org/10.1063/1.116495
  22. A. K. Viswanath, J. I. Lee, S. Yu, D. Kim, Y. Choi, and C.-H. Hong, 'Photoluminescence studies of excitonic transitions in GaN epitaxial layers', J. Appl. Phys., Vol. 84, No.7, p. 3848, 1998 https://doi.org/10.1063/1.368564

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