Analytical Science and Technology (분석과학)

The Korean Society of Analytical Sciences (한국분석과학회)
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Self-assembly directed synthesis of tubular conducting polymer inside the channels of MCM-41

  • Showkat, Ali Md. (Department of Chemistry Graduate School, Kyungpook National University) ;
  • Lee, Kwang-Pill (Department of Chemistry Graduate School, Kyungpook National University) ;
  • Gopalan, Anantha Iyengar (Department of Chemistry Graduate School, Kyungpook National University) ;
  • Reddy, K. Raghava (Department of Chemistry Graduate School, Kyungpook National University) ;
  • Kim, Sang-Ho (Department of Chemistry Graduate School, Kyungpook National University) ;
  • Choi, Seong-Ho (Department of Chemistry, Hannam university)
  • Published : 2006.06.27
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Abstract

Diphenyl amine (DPA) was polymerized inside the channels of the mesoporous silica (MCM-41). MCM-41 (C) and MCM-41 (D) were prepared with cetyltrimethyl ammonium bromide (CTAB) and dodecyltrimethyl ammonium bromide (DTAB), respectively and used as hosts. Initially, the self assembly of DPA inside the pores of MCM-41 was made in ${\beta}$-naphthalene sulfonic acid (NSA) medium and subsequently poly (diphenylamine), PDPA was formed by oxidative polymerization. $N_2$ adsorption-desorption measurements of PDPA loaded MCM-41 (C) and MCM-41 (D) show variations in pore volume and surface area between them. A tubular form of poly (diphenylamine), PDPA was envisaged to form in the pores of MCM-41 and supported by high resolution transmission microscopy. The presence of PDPA inside the channel of MCM-41 was further confirmed by FTIR spectroscopy, thermogravimetric analysis (TGA), X-ray diffraction.

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