광촉매공정과 초음파를 접목시킨 광촉매공정에 의한 Benomyl의 분해 비교

The Comparison of Photocatalysis and Sonophotocatalysis for Benomyl Degradation

  • 안상우 (서희건설 SOC 환경사업부) ;
  • 박재홍 (국립환경과학원 수질총량관리센터) ;
  • 조일형 (경기지방공사) ;
  • 장순웅 (경기대학교 환경공학과)
  • An, Sang-Woo (SOC Environmental Business Division, Seohee Construction Co. Ltd) ;
  • Park, Jae-Hong (Watershed Management Research Division, National Institute of Environmental Research) ;
  • Cho, Il-Hyoung (New Town Development Division, Gyeonggi Innovation Corporation) ;
  • Chang, Soon-Woong (Department of Environmental Engineering, Kyonggi University)
  • 투고 : 2005.10.31
  • 심사 : 2006.04.27
  • 발행 : 2006.07.30

초록

Comparison between photocatalysis and sonophotocatalysis were performed in lab-scale experiments for the treatment of benomyl. The effect of operational parameters, i.e., initial benomyl concentration, $TiO_2$ concentration, $H_2O_2$ concentration on the degradation rate of aqueous solution of benomyl has been examined. The optimal conditions for photocatalysis and sonophotocatalysis processes were determined: initial Benomyl concentration was 3 mg/L, the concentration of $TiO_2$ was 2 g/L and $H_2O_2$concentration was 1.5 mM. Under the optimal conditions, sonophotocatalysis was effective for inducing faster degradation of the benomyl.

키워드

참고문헌

  1. 박재흥,안상우, 장순웅,$TiO_{2}$ 광촉매를 이용한 Atrazine과 PCP의 분해, 한국물환경학회지, 20(6), pp. 577-582(2004)
  2. 신혜승, 표회수, 박송자, Benomyl의 국내 환경 시료중의 오염실태조사, 한국환경분석학회지, 5(3), pp. 145-151(2002)
  3. Harada, H., Hosoki, C. and Kudo, A., Overall Water Splitting by Sonophotocatalytic Reaction: the Role of Powdered Photocatalyst and an Attempt to Decompose Water using a Visible-Light Sensitive Photocatalyst, J. photochem. Photobiol., A 141, pp. 219-224 (2001)
  4. Kaneko, M. and Okura, I., Photocatalysis Science and Technology, Springer, Japan, p. 203 (2002)
  5. Lindley, J., Sonochemistry, The Royal Society of Chemistry, Cambridge, p. 102 (1997)
  6. Malato, S., Blanco, J., Richter, C., Braun, B. and Maldonado, M. I., Enhancement of the Rate of Solar Photocatalytic Mineralization of Organic Pollutants by Inorganic Oxidizing Species, Environmental, 17, pp. 347-356 (1998)
  7. Mason, T. J., Current Trends and Future Prospects, In: Current Trends in Sonochemistry, The Royal Society of Chemistry, Cambridge, p. 171 (1992)
  8. Morgan, D. P., Recognition and Management of Pesticide Poisonings, 4th ed., 112 EPA 440/988-001 (1989)
  9. Osol, A., Remington's Pharmaceutical Sciences, 16th ed., Mack publishing co. (1980)
  10. Park, J. H., Cho, I. H. and Kim, Y. G., Solar Light Induced Degradation of Reactive Dye Using Photocatalysis, J. Environ. Sci. Heath, A39(1), pp. 159-171 (2004)
  11. Poulios, I. and Aetopoulou, I., Photocatalytic Degradation of the Textile Dye Reactive Orange 16 in the Presence of $TiO_{2}$ Suspension, Environ. Tech., 20, pp. 479-487 (1999) https://doi.org/10.1080/09593332008616843
  12. Stock, N. L., Peller, J., Vinodgopal, K. and Kamat, P. V., Combinative Sonolysis and Photocatalysis for Textile Dye Degradation, Environ. Sci. Tech., 34, pp. 1747-1750 (2000) https://doi.org/10.1021/es991231c
  13. Szewczyk, D. A., The Degradation of 2-chlorophenol by Sonolysis and Photocatalysis on $TiO_{2}$ in Aqueous Solution, American Chemical Society, San Francisco (1997)