The Korean Journal of Pesticide Science (농약과학회지)

The Korean Society of Pesticide Science (한국농약과학회)
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Synthesis of 2-Mercaptobenzoxazoles and 2-Mercaptobenzimidazole

2-Mercaptobenzoxazole 및 2-Mercaptobenzimidazole의 새로운 합성법

  • 정근회 (한국화학연구원 생명화학연구단) ;
  • 이동국 (한국화학연구원 생명화학연구단) ;
  • 고영관 (한국화학연구원 생명화학연구단) ;
  • 류재욱 (한국화학연구원 생명화학연구단) ;
  • 우재춘 (한국화학연구원 생명화학연구단) ;
  • 구동완 (한국화학연구원 생명화학연구단) ;
  • 김대황 (한국화학연구원 생명화학연구단)
  • Published : 2006.03.31
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Abstract

New synthetic method of 2-mercaptobenzoxazoles and 2-mercaptobenzimidazoles was established using elemental sulfur, dichloromethane, inorganic base and catalysts in alcohol solvents. This reaction condition gave products in high yields.

2-아미노페놀(aminophenol) 유도체와 1,2-페닐렌디아민(phenylenediamine) 유도체를 이황화탄소대신 유황(S), 디클로로메탄과, 알칼리금속의 무기염기 및 촉매를 사용하여 알콜용매에서 반응시켜서 고수율 고순도로 2-머캅토벤족사졸 및 벤즈이미다졸 유도체를 합성하였다.

Keywords

References

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