Journal of Applied Biological Chemistry

The Korean Society for Applied Biological Chemistry (한국응용생명화학회)
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Two Acylglycerylgalactosides and a New Sesquiterpene Galactoside from the Flowers of Hemisteptia lyrata Bunge

  • Ha, Tae-Joung (Yeongnam Agricultural Research Institute, National Institute of Crop Science, RDA) ;
  • Lee, Jin-Hwan (Yeongnam Agricultural Research Institute, National Institute of Crop Science, RDA) ;
  • Hwang, Seon-Woo (Division of Applied Life Science (BK21 program), Institute of Agriculture & Life Sciences, Department of Agricultural Chemistry, Gyeongsang National University) ;
  • Lee, Jun (Division of Applied Life Science (BK21 program), Institute of Agriculture & Life Sciences, Department of Agricultural Chemistry, Gyeongsang National University) ;
  • Kang, Nam-Suk (Yeongnam Agricultural Research Institute, National Institute of Crop Science, RDA) ;
  • Park, Keum-Yong (Yeongnam Agricultural Research Institute, National Institute of Crop Science, RDA) ;
  • Suh, Duck-Yong (Yeongnam Agricultural Research Institute, National Institute of Crop Science, RDA) ;
  • Park, Ki-Hun (Division of Applied Life Science (BK21 program), Institute of Agriculture & Life Sciences, Department of Agricultural Chemistry, Gyeongsang National University) ;
  • Yang, Min-Suk (Division of Applied Life Science (BK21 program), Institute of Agriculture & Life Sciences, Department of Agricultural Chemistry, Gyeongsang National University)
  • Published : 2006.03.30
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Abstract

The flowers of Hemisteptia lyrata B. afforded two known acylglycerylgalactosides, 2',3'-di-O-(9Z,12Z,15Z-octadecatrienoyl)glyceryl ${\beta}$-D-galactopyranoside (1) and 2'-O-(9Z,12Z,15Z-octadecatrienoyl)glyceryl ${\beta}$-D-galactopyranoside (2), and a new sesquiterpene galactopyranoside, 7-eudesmene-1${\beta}$,4${\beta}$-diol-1-O-${\beta}$-D-galactopyranoside (3). This is the first time that galactopyranosides (1-3) have been isolated from the genus Hemisteptia. Their structures and stereochemistry were elucidated by 1D and 2D NMR data, including COSY, NOESY and HMBC experiments.

Keywords

References

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