• Title/Summary/Keyword: Diacylgalactosides

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Two Acylglycerylgalactosides and a New Sesquiterpene Galactoside from the Flowers of Hemisteptia lyrata Bunge

  • Ha, Tae-Joung;Lee, Jin-Hwan;Hwang, Seon-Woo;Lee, Jun;Kang, Nam-Suk;Park, Keum-Yong;Suh, Duck-Yong;Park, Ki-Hun;Yang, Min-Suk
    • Journal of Applied Biological Chemistry
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    • v.49 no.1
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    • pp.16-20
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    • 2006
  • The flowers of Hemisteptia lyrata B. afforded two known acylglycerylgalactosides, 2',3'-di-O-(9Z,12Z,15Z-octadecatrienoyl)glyceryl ${\beta}$-D-galactopyranoside (1) and 2'-O-(9Z,12Z,15Z-octadecatrienoyl)glyceryl ${\beta}$-D-galactopyranoside (2), and a new sesquiterpene galactopyranoside, 7-eudesmene-1${\beta}$,4${\beta}$-diol-1-O-${\beta}$-D-galactopyranoside (3). This is the first time that galactopyranosides (1-3) have been isolated from the genus Hemisteptia. Their structures and stereochemistry were elucidated by 1D and 2D NMR data, including COSY, NOESY and HMBC experiments.