Deposition of (Ti, Cr, Zr)N-$MoS_{2}$ Thin Films by D.C. Magnetron Sputtering

  • Kim, Sun-Kyu (School of Materials Science and Engineering, University of Ulsan) ;
  • Vinh, Pham-Van (School of Materials Science and Engineering, University of Ulsan)
  • Published : 2006.12.31

Abstract

As technology advances, there is a demand for development of hard solid lubricant coating. (Ti, Cr, Zr)N-$MoS_2$ films were deposited on AISI H13 tool steel substrate by co-deposition of $MoS_2$ with (Ti, Cr, Zr)N using a D.C. magnetron sputtering process. The influence of the $N_2Ar$ gas ratio, the amount of $MoS_2$ in the films and the bias voltage on the mechanical and structural properties of the films were investigated. The highest hardness level was observed at the $N_2/Ar$ gas ratio of 0.3. Hardness of the films did not change much with the increase of the $MoS_2$ content in the films. As the substrate bias potential was increased, hardness level of the film reached maximum at -150 V. Surface morphology of these films indicated that high hardness was attributed to the fine dome structure.

Keywords

References

  1. S. K. Kim, Y. H. Kim, K. H. Kim, Surf. Coat. Technol., 169-170 (2003) 428 https://doi.org/10.1016/S0257-8972(03)00181-6
  2. N. M. Renevier, J. Hampshire, V. C. Fox, J. Witts, T. Allen, D. G. Teer, Surf. Coat. Technol., 142-144 (2001) 69
  3. X. Zhang, W. Lauwerens, J. He, J.-P. Cellis, J. Vac. Sci. Technol., A21 (2) (2003) 416
  4. M. C. Simmons, A. Sayans, E. Pflueger, H. Van Swygenhoven, Surf. Coat. Technol., 126 (2000) 15 https://doi.org/10.1016/S0257-8972(00)00521-1
  5. S. Carrera, O. Salas, J. J. Moore, A. Woolveraton, E. Sutter, Surf. Coat. Technol., 169 (2003) 25
  6. R. Gilmore, M. A. Baker, P. N. Gibson, W. Gissler, M. Stoiber, P. Lobicher, C. Mitterer, Surf. Coat. Technol., 108-109 (1998) 345 https://doi.org/10.1016/S0257-8972(98)00602-1
  7. S. K. Kim, B. C. Cha, Surf. Coat. Technol., 188-189 (2004) 174 https://doi.org/10.1016/j.surfcoat.2004.08.013
  8. S. K. Kim, J. H. Kim, J. Kor. Inst. Surf. Eng. 39, 2 (2006) 70
  9. S. K. Kim, B. C. Cha, J. S. Yoo, Surf. Coat. Technol., 177-178 (2004) 434 https://doi.org/10.1016/j.surfcoat.2003.09.021
  10. S. K. Kim, B. C. Cha, Thin Solid Films, 475 (2005) 202 https://doi.org/10.1016/j.tsf.2004.08.059