Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Synthesis of Chiral Azophenolic Pyridino-18-Crown-6 Ether and Its Enantiomeric Recognition toward Chiral Primary Amines

  • Kim, Jae-kon (Department of Chemistry and Center for Plastic Information Systems, Pusan National University) ;
  • Song, Su-Hee (Department of Chemistry and Center for Plastic Information Systems, Pusan National University) ;
  • Kim, Jae-Hong (Department of Chemistry and Center for Plastic Information Systems, Pusan National University) ;
  • Kim, Tae-Hyun (Department of Chemistry and Center for Plastic Information Systems, Pusan National University) ;
  • Kim, Ha-suck (Department of Chemistry and Center for Plastic Information Systems, Pusan National University) ;
  • Suh, Hong-Suk (Department of Chemistry and Center for Plastic Information Systems, Pusan National University)
  • Published : 2006.10.20
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Abstract

The article reports the synthesis and enantiomeric recognition of a new chiral azophenolic pyridino-18-crown-6 ether, (S,S)-6, possessing diphenyl groups as chiral barriers. The association constants for the enantiomeric recognition of chiral primary amines (7-12) using chiral azophenolic pyridino-18-crown-6 ether, (S,S)-6, were determined by UV-visible titration method in acetonitrile at $25{^{\circ}C}$.

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References

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