Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Determination of Salicylate by Selective Poly(vinylchloride) Membrane Electrode Based on N,N'-1,4-Butylene Bis(3-methyl salicylidene iminato) Copper(II)

  • Mazloum Ardakani, M. (Department of Chemistry, Faculty of Science, Yazd University) ;
  • Jamshidpoor, M. (Department of Chemistry, Faculty of Science, Kashan University) ;
  • Naeimi, H. (Department of Chemistry, Faculty of Science, Kashan University) ;
  • Heidarnezhad, A. (Department of Chemistry, Faculty of Science, Kashan University)
  • Published : 2006.08.20
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Abstract

A new salicylate-selective electrode based on the complex N,N'-1,4-butylene bis(3-methyl salicylidene iminato) copper(II) as the membrane carrier was developed. The electrode exhibits a good Nernstian slope of 59.1 ${\pm}$ 1.0 mV/decade and a linear range of $1.0\;{\times}\;10^{-6}$-1.0 M for salicylate. The limit of detection was $5.0\;{\times}\;10^{-7}$ M. It has a fast response time 10 s and can be used for more than three months. The selective coefficients were determined by the fixed interference method (FIM) and could be used in the pH range 4.5-10.5. It was employed as an indicator electrode for direct determination of salicylate in pharmaceutical samples.

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